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Alpinigenine

Reference work entry

CAS Registry Number: 14028-91-2 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Isoquinoline Alkaloids

Biological sources: Papaver bracteatum, P. orientale

C22H27NO6: 401.1838

Mp: 192–193°C (EtOH) [1], 186.5–187°C [2]

[α]D +290° (CHCl3) [1]; +306° (MeOH) [2]

UV: 230, 284 [2]

IR(CCl4): 3610, 3484 [2]

MSm/z: 401(M+), 222, 208, 206, 179, 164

1H NMR: 2.28(3H, s, NCH3), 2.00–2.40(4H, m), 3.79, 3.87(each 6H, s, 4 × OCH3), 3.95, 5.69(each 1H, d, J = 9), 6.28, 6.55, 7.11(each 1H, s), 6.78, 7.13(each 1H, d, J = 8.5) [2]

HPLC: [3]

References

  1. 1.
    O.N. Denisenko, I.A. Israilov, D.A. Murav’eva, M.S. Yunusov, Chem. Nat. Comp. 13, 456 (1977)Google Scholar
  2. 2.
    A. Guggisberg, M. Hesse, H. Shmid, H. Bohm, H. Ronsch, K. Mothes, Helv. Chim. Acta 50, 621 (1967)Google Scholar
  3. 3.
    J. Milo, A. Levy, D. Palevitch, J. Ladizinsky, J. Chromatogr. 452, 563 (1988)Google Scholar

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© Springer Science+Business Media New York 2013

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