(−) – Adlumidine

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Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Isoquinoline Alkaloids

Biological sources: Corydalis alpestris, C. caucasica, C. emanuelii, C. gigantea, C. gortschakovii, C. ledebouriana, C. marschalliana, C. paniculigera, C. pseudoadunca, C. remota, C. rosea, C. stricta, C. vaginans, Fumaria capreolata, F. officinalis, F. parviflora, F. schleicheri, F. vaillantii, Glaucium corniculatum

C20H17NO6: 367.1056

Mp: 220–221°C (MeOH–CHCl3) [1]

[α]D −100° (CHCl3) [1]

UV: 225, 295, 325 [1]

IR: 1750, 1615, 1505, 1040, 1030, 935 [1]

MSm/z: 190 [1]

1H NMR: 2.45(3H, s, NCH3), 5.76, 6.00 (each 2H, s, 2 × CH2O2), 6.31, 6.58 (1H, s, p–H–Ar), 6.84, 7.06 (1H, d, J = 8, o–H–Ar) [1]

Abs. conf.: 1R, 9R [2]

References

  1. 1.
    M.U. Ibragimova, M.S. Yunusov, S.Yu. Yunusov, Chem. Nat. Comp. 6, 447 (1970)Google Scholar
  2. 2.
    G.P. Moiseeva, I.A. Israilov, M.S. Yunusov, S.Yu. Yunusov, Chem. Nat. Comp. 14, 82 (1978)Google Scholar

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© Springer Science+Business Media New York 2013

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