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Orientalidine

Reference work entry

CAS Registry Number: 23943-90-0 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Diisoquinoline Alkaloids

Biological sources: Papaver bracteatum, P. orientale, P. pseudo-orientale

C22H23NO6: 397.1525

Mp: 193–194°C (EtOH) [1]

[α]D −236° (CHCl3) [1]

UV: 231 sh, 286 [2]

MSm/z: 397(M+), 367, 366, 198.5(++), 192, 162(100) [1, 2]

1H NMR: 3.80, 4.13(each 1H, d, J = 16), 3.83, 3.95(each 3H, s, 2 × OCH3), 4.61, 4.86(each 1H, d, J = 15), 5.22(2H, s), 5.86(2H, s, CH2O2), 6.32, 6.49(each 1H, s, 2 × H–Ar) [2]

ORD: [2]

HPLC: [3]

References

  1. 1.
    R. Shakirov, M.V. Telezhenetskaya, I.A. Bessonova, S.F. Aripova, I.A. Israilov, M.N. Sultankhodzhaev, V.I. Akhmedzhanova, V.I. Vinogradova, T.S. Tulyaganov, B.T. Salimov, V.A. Tel’nov, Chem. Nat. Comp. 32, 737 (1996)Google Scholar
  2. 2.
    V. Preininger, A.D. Cross, J.W. Murphy, F. Santavy, T. Toube, Collect. Czech. Chem. Commun. 34, 875 (1969)Google Scholar
  3. 3.
    J. Milo, A. Levy, D. Palevitch, G. Ladizinsky, J. Chromatogr. 452, 563 (1988)Google Scholar

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© Springer Science+Business Media New York 2013

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