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Mecambridine (Oreofilline)

Reference work entry

CAS Registry Number: 31098-60-9 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Diisoquinoline Alkaloids

Biological sources: Papaver bracteatum, P. lisae, P. oreophilum, P. orientale, P. pseudoorientale

C22H25NO6: 399.1682

Mp: 176–177°C (EtOH) [1]

[α]D −260° (CHCl3) [1]

UV: 229, 288 [2]

IR: 3605 [3]

MSm/z: 399(M+), 368, 206, 204, 195, 194, 179 [3]

1H NMR: 2.10–3.80(10H, m), 3.84(6H, s, 2 × OCH3), 3.98(3H, s, OCH3), 4.65(2H, s, Ar–CH2OH), 5.85(2H, s, CH2O2), 6.33, 6.58(each 1H, s, 2 × H–Ar) [3]

References

  1. 1.
    O.N. Denisenko, I.A. Israilov, D.A. Murav’eva, M.S. Yunusov, Chem. Nat. Comp. 13, 456 (1977)Google Scholar
  2. 2.
    F. Veznik, I.A. Israilov, E. Taborska, J. Slavik, Collect. Czech. Chem. Commun. 50, 1745 (1985)Google Scholar
  3. 3.
    V.A. Chelombit’ko, V.A. Mnatsakanyan, L.V. Sal’nikova, Chem. Nat. Comp. 14, 228 (1978)Google Scholar

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© Springer Science+Business Media New York 2013

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