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Macrostomine cis-N-Oxide

Reference work entry

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Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Benzylisoquinoline Alkaloids

Biological sources: Papaver arenarium

C24H26N2O5: 422.1842

Mp: amorph. [1, 2]

[α]D +35° (MeOH) [1, 2]

UV: 248, 292, 320, 335(4.49, 3.78, 3.57, 3.57) [1, 2]

IR: 1620, 1570, 1520, 1040, 930 [1, 2]

MSm/z: 422(M+), 406, 405, 404, 363(100), 348, 84, 60, 43 [1, 2]

1H NMR: 2.25–3.70(6H, m), 2.79(3H, s, NCH3), 3.86, 4.06(each 3H, s, 2 × OCH3), 4.45(2H, s, CH2), 5.54(1H, t, J = 7), 5.82(2H, s, CH2O2), 6.65(1H, H–Ar), 6.70(2H, H–Ar), 7.33, 8.00, 8.33(each 1H, s, H–Ar) [1, 2]

References

  1. 1.
    I.A. Israilov, M.A. Manushakyan, V.A. Mnatsakanyan, M.S. Yunusov, Chem. Nat. Comp. 20, 71 (1984)Google Scholar
  2. 2.
    R. Shakirov, M.V. Telezhenetskaya, I.A. Bessonova, S.F. Aripova, I.A. Israilov, M.N. Sultankhodzhaev, V.I. Akhmedzhanova, V.I. Vinogradova, T.S. Tulyaganov, B.T. Salimov, V.A. Tel’nov, Chem. Nat. comp. 32, 596 (1996)Google Scholar

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