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Glicomarine

Reference work entry

CAS Registry Number: 77396-64-6 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Benzylisoquinoline Alkaloids

Biological sources: Papaver arenarium

C24H25NO9: 471.1529

Mp: 205–206°C (MeOH) [1]

[α]D −51° (CHCl3–MeOH) [1]

UV: 239, 290, 313, 327(4.78, 4.01, 3.81, 3.85) [1]

IR: 3515, 3450, 1630, 1605, 1580, 1520, 1100–1000, 940, 925 [1]

MSm/z: 471(M+), 309, 308 [1]

1H NMR(Py-d5): 3.64(3H, s, OCH3), 4.22(2H, s, Ar-CH2-Ar), 4.25–5.65(11H, m), 5.69(2H, s, CH2O2), 6.67(1H, d, J = 8, o–H–Ar), 7.03–7.28(3H, m, H–Ar), 7.44, 8.56(each 1H, d, J = 4.5, o–H–Ar), 8.21(1H, s, H–Ar) [1]

References

  1. 1.
    I.A. Israilov, M.A. Manushakyan, V.A. Mnatsakanyan, M.S. Yunusov, S.Yu. Yunusov, Khim. Prirod. Soedin. 852 (1980)Google Scholar

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© Springer Science+Business Media New York 2013

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