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Wilsonirine (Aducaine)

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Natural Compounds
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CAS Registry Number: 17807-64-6

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Isoquinoline Alkaloids – Aporphine Alkaloids

Biological sources: Corydalis pseudoadunca, C. paniculigera, C. stricta

C19H21NO4: 327.1471

Mp: 211–213°C (dec., Me2CO) [1], 247°C (dec., hydrobromide), 200°C (picrate) [2]

[α]D +55° (CHCl3) [1]

UV: 220, 280, 303(4.50, 4.12, 4.13) [2]

IR: 3400 [2]

1 H NMR: 3.73, 3.80, 3.80(each 3H, s, 3 × OCH3), 6.60, 6.83, 8. 05(each 1H, s, H–Ar [1]

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References

  1. M.S. Yunusov, Author’s Abstract of Candidate’s Dissertation, Tashkent, 1968

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  2. K.L. Stuart, C. Chambers, Tetrahedron Lett. 8, 4135 (1967)

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(2013). Wilsonirine (Aducaine). In: Azimova, S.S., Yunusov, M.S. (eds) Natural Compounds. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0560-3_677

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