Glaucine

doi:10.1007/978-1-4614-0560-3_612

68 Accesses

CAS Registry Number: 66396-10-9

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Isoquinoline Alkaloids – Aporphine Alkaloids

Biological sources: Aconitum tokii, Corydalis rosea-purpurea, Berberis densiflora, B. heteropoda, B. integerrima, B. thunbergii, Delphinium ternatum, Eschscholtzia californica, Glaucium corniculatum, G. elegans, G. flavum, G. grandiflorum, G. serpieri, Liriodendron tulipiferum, Thalictrum baikalense, T. collinum, T. filamentosum, T. foetidum, T. longipedunculatum, T. minus, T. sachalinense

C₂₁H₂₅NO₄: 355.1783

Mp: 104–109°C (Et₂O) [1], 116–117°C [2], oil [3]; 219°C (methiodide), 237°C (hydrobromide) [1]

[α]_D +84° (MeOH) [1]; +113° (EtOH) [2]

UV: 282, 304(4.34, 4.24) [3]

IR: 2800, 1600, 1583, 1440, 1318, 1105, 975, 950 [4]

MS m/z: 355(M⁺), 354, 340, 324, 312, 297, 281 [3]

¹ H NMR: 2.49(3H, s, NCH₃), 3.59(3H, s, 1-OCH₃), 3.84(9H, s, 3×OCH₃), 6.54, 6.74, 8.03(each 1H, s, H-3, H-8, H-11) [3]

¹³ C NMR: [5]

Table 1

C-1	143.9	C-5	53.1	C-11	111.4
1a

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Chapter: USD 29.95; Price excludes VAT (USA)

eBook: USD 549.00; Price excludes VAT (USA)

Hardcover Book: USD 549.99; Price excludes VAT (USA)

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

S.Yu. Yunusov, N.N. Progressov, Zh. Obshch. Khim. 22, 1047 (1952)
CAS Google Scholar
L.D. Yakhontova, Trudy VILAR 15, 348 (1969)
Google Scholar
A. Karimov, M.V. Telezhenetskaya, K.L. Lutfullin, S.Yu. Yunusov, Chem. Nat. Comp. 12, 505 (1976)
Google Scholar
M. Shamma, B.S. Dudock, J. Pharm. Sci. 57, 262 (1968)
CAS Google Scholar
H. Guinaudeau, M. Leboeuf, A. Cave, J. Nat. Prod. 42, 325 (1979)
CAS Google Scholar
J.P. Fels, P. Lechat, R. Rispe, W. Cautreels, J. Chromatogr. 308, 273 (1984)
CAS Google Scholar
E.V. Kopantseva, O.N. Tolkachev, Yu.K. Botezat-Belyi, S.A. Kudrin, S.V. Klochkov, O.M. Markova, V.G. Tumbov, A.A. Ladanova, N.L. Molchalova, Khim. Farm. Zh. 23, 1116 (1989)
Google Scholar
F.S. Sadritdinov, A.G. Kurmukov, The Pharmacology of the Plant Alkaloids and Their Use in Medicine [in Russian] (UzSSR, Tashkent, 1980), p. 209
Google Scholar
Kh.S. Shakhabutdinova, I.K. Kamilov, S.F. Fakhrutdinov, The Pharmacology of Alkaloids and Glycosides[in Russian] (Fan, Tashkent, 1967), p. 142
Google Scholar
S.F. Fakhrutdinov, Kh.S. Shakhabutdinova, The Pharmacology of Alkaloids and Cardiac Glycosides [in Russian] (Fan, Tashkent, 1971), p. 137
Google Scholar
E.K. Aronchik, A.Yu. Ivanova-Neznamova, V.I. Kalmykova, R.G. Maksimova, E.E. Aleshinskaya, Trudy VILR 14, 251 (1971). M.Ya. Elova, V.P. Semenova, R.G. Maksimova, Trudy VILR 14, 253 (1971)
Google Scholar
M.D. Mashkovskii, Drugs [in Russian], vol. 1 (Meditsina, Moscow, 1984), p. 205
Google Scholar

Download references

Editor information

Editors and Affiliations

S.Yu. Yunusov Institute of the Chemistry of Plant Substances of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
Shakhnoza S. Azimova
S.Yu. Yunusov Institute of the Chemistry of Plant Substances of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan
Marat S. Yunusov

Rights and permissions

Reprints and permissions

Copyright information

About this entry

Cite this entry

(2013). Glaucine. In: Azimova, S.S., Yunusov, M.S. (eds) Natural Compounds. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0560-3_612

Download citation

DOI: https://doi.org/10.1007/978-1-4614-0560-3_612
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4614-0559-7
Online ISBN: 978-1-4614-0560-3
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics

Publish with us

Policies and ethics