Triacetylglycoperine

Reference work entry

CAS Registry Number: 55740-46-0 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Quinoline Alkaloids

Biological sources: Haplophyllum perforatum

C25H27NO11: 517.1584

Mp: 181–182°C (C6H6-pet. ether.) [1]

[α]D −91° (EtOH) [1]

Solubility: very sol. CHCl3, Me2CO; spar. sol. Et2O, pet. ether.; insol. H2O [1]

UV: 248, 314, 323, 336 (4.94, 3.91, 3.93, 3.83) [1]

IR: 3155, 3130, 1750, 1622, 1582, 1512, 1490, 1450 [1, 2]

MSm/z: 517(M+, 5), 273(41), 245(93), 227(52), 171(30), 153(100), 111(8) [1]

1H NMR: 1.05(3H, d, J = 6.5, CH3), 1.88, 1.92, 2.05(each 3H, s, 3 × Ac), 3.80–4.40(1H, m, H-5′), 4.00, 4.15(each 3H, 2 × OCH3), 5.05(1H, t, J = 10, H-4′), 5.49(3H, m, H-1′, H-2′, H-3′), 6.91, 7.46(each 1H, d, J = 3, H-3, H-2), 7.12, 7.86(each 1H, d, J = 9.5, H-6, H-5) [1]

References

  1. 1.
    Kh.A. Abdullaeva, I.A. Bessonova, S.Yu. Yunusov, Chem. Nat. Comp. 13, 363 (1977)Google Scholar
  2. 2.
    R. Shakirov, M.V. Telezhenetskaya, I.A. Bessonova, S.F. Aripova, I.A. Israilov, M.N. Sultankhodzhaev, V.I. Vinogradova, V.I. Akhmedzhanova, T.S. Tulyaganov, B.T. Salimov, V.A. Tel’nov, Chem. Nat. Comp. 32, 932 (1996)Google Scholar

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