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Haplaphine

Reference work entry

CAS Registry Number: 54357-78-7 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Quinoline Alkaloids

Biological sources: Haplophyllum perforatum

C14H15NO2: 229.1103

Mp: 159–160°C (Me2CO) [1]

Solubility: very sol. CHCl3 [1]

UV: 215, 225, 229, 238 sh, 267, 277, 317, 328 [1]

IR: 3170, 1665, 1610, 1510, 1442, 1414, 1380, 1368, 1330, 1265, 1230, 1160, 1110, 1040, 980 [2]

MSm/z: 229(M+, 42), 214(11), 186(10), 162(40), 161(100), 133(20), 132(21), 120(20), 119(35), 69(70) [1,2]

1H NMR: 1.73, 1.79(each 3H, 2 × CH3), 4.62(2H, d, J = 6.8, CH2O), 5.50(1H, t, J = 6.8, CH), 5.97(1H, s, H-3), 7.27(3H, m, H–Ar), 7.86(1H, dd, J = 9, 2, H-5), 12.09(1H, br s, NH) [1]

References

  1. 1.
    I.A. Bessonova, S.Yu. Yunusov, Chem. Nat. Comp. 22, 619 (1986)Google Scholar
  2. 2.
    R. Shakirov, M.V. Telezhenetskaya, I.A. Bessonova, S.F. Aripova, I.A. Israilov, M.N. Sultankhodzhaev, V.I. Vinogradova, V.I. Akhmedzhanova, T.S. Tulyaganov, B.T. Salimov, V.A. Tel’nov, Chem. Nat. Comp. 32, 932 (1996)Google Scholar

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© Springer Science+Business Media New York 2013

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