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Echinatine

  • Reference work entry
Natural Compounds

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CAS Registry Number: 480-82-0

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Pyrrolizidine Alkaloids

Biological sources: Cynoglossum amabile, C. pictum, Lindelofia macrostyla, L. stylosa, L. tschmganica, Paracynoglossum imeretinum, Rindera austroechinata, R. baldshuanica, R. cyclodonta, R. echinata, R. oblongifolia, Solenanthus circinnatus, S. coronatus, S. hirsutus, S. karateginus, Suchtelenia calycina, Symphytum asperum, S. caucasicum, S. officinale

C15H25NO5: 299.1733

Mp: 111–112°C (Me2CO) [1]; oil, 97°C (hydrochloride), 140°C (methiodide), 206°C (picrolonate) [2]

[α]D +12° (MeOH) [1]

UV: 266, 272 [3]*

IR: 3360, 3340, 3230, 3120, 2965, 2745, 2130, 1738, 1650, 1470, 1430, 1420, 1250, 880 [3]

MS m/z: 299(M+, 3), 255(6), 138(100), 93(89) [4]

1 H NMR: 0.82, 0.88(each 3H, d, CH3-7′, CH3-6′), 1.25(3H, d, CH3-4′), 1.77, 1.87(2H, m, H-6), 2.13(1H, m, H-5′), 2.55, 3.18(2H, m, H-5), 3.24, 3.89(2H, d, H-3), 3.91(1H, q, H-3′), 3.94(1H, br s, H-8), 4.08(1H, m, H-7),...

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References

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Editor information

Editors and Affiliations

  1. S.Yu. Yunusov Institute of the Chemistry of Plant Substances of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan

    Shakhnoza S. Azimova

  2. S.Yu. Yunusov Institute of the Chemistry of Plant Substances of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan

    Marat S. Yunusov

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(2013). Echinatine. In: Azimova, S.S., Yunusov, M.S. (eds) Natural Compounds. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0560-3_1033

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