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Cayaponoside D2

Reference work entry

CAS Registry Number: 159653-47-1 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Triterpene Glycosides – Glycosides of Aglycones of Cucurbitane Type – 22,25-Dihydroxy-6-en-fevicordin A

Biological source: Cayaponia tayuya [1]

C35H50O12: 662.330

Mp: 172–175°C [1]

[α]D26 − 106.9° (c 1.38, MeOH) [1]

UV λmaxMeOH nm (log ε): 206 (4.11), 233 (4.36), 274 (3.85), 284 (3.82), 303 (3.47), 315 (3.37) [1]

FAB-MSm/z: 661 [M-H], 499 [M-H-162], 383 [1]

HR-FAB-MSm/z: 685.3198 [M + Na]+ [1]

1H NMR (J/Hz): 6.53 (s, H-1), 6.88 (d, J = 10, H-6), 5.82 (dd, J = 6, 10, H-7), 2.57 (d, J = 6, H-8), 2.67, 2.88 (dd, J = 15, H2-12), 1.47 (d, J = 14), 2.08 (dd, J = 9, 14, H2-15), 4.64 (dd, J = 7, 9, H-16), 2.29 (d, J = 7, H-17), 0.92 (s, CH3-18), 1.22 (s, CH3-19), 1.21 (s, CH3-21), 3.96 (dd, J = 1, 6, H-22), 5.75 (dd, J = 6, 15, H-23), 5.83 (dd, J = 1, 15, H-24), 1.25 (s, CH3-26), 1.25 (s, CH3-27), 2.23 (s, CH3-28), 1.05 (s, CH3-30)

β-D-Glcp: 4.61 (d, J = 7, H-1), 3.40-3.55...

References

  1. 1.
    E. Himeno, T. Nagao, J. Honda, H. Okabe, N. Irino, T. Nakasumi, Chem. Pharm. Bull. 42(11), 2370 (1994)CrossRefGoogle Scholar

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