Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

2α,10β-Diacetoxy-6α-anisoyloxy-5α(H)-dauc-8-en-4β-ol (2α,10β-Diacetoxy-6α-p-anisate Jaeschkeanadiol)

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_979

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Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Triesters

Biological sources: Ferula communis L. subsp. communis [1]

C27H36O8: 488.2410

Mp: gum [1]

UV (CHCl3) 263 (ε 13150) [1]

IR (KBr): 3450, 2970, 2940, 2880, 2850, 1738, 1712, 1650, 1610, 1580, 1514, 1460, 1380, 1320, 1260, 1174, 1110, 1080, 1038, 970, 950, 852, 778 [1]

MS: 488 [M]+ (0.5), 471 [M − H2O + H]+ (23.7), 445 [M − iso-Pr]+ (14.7), 429 [M − HOAc + H]+ (7.8), 411 [M − HOAc − H2O + H]+ (6.6), 385 [M − HOAc − iso-Pr]+ (19.6), 368 [M − 2 × HOAc]+ (0.4), 337 [M − p-anisic acid + H]+ (0.7), 325 [M − 2 × HOAc−iso-Pr]+ (6.1), 319 [M − p-anisic acid − H2O + H]+ (4.9), 293 [M − p-anisic acid − iso-Pr]+ (24.5), 277 [M − p-anisic acid − HOAc + H]+ (30.8), 259 [M − p-anisic acid − HOAc − H2O + H]+ (35.2), 251 [M − p-anisic acid − acetate − iso-Pr + H]+ (17.3), 233 [M − p-anisic acid − HOAc − iso-Pr]+ (52.7), 217 [M − p-...

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References

  1. 1.
    M. Miski, T.J. Mabry, Phytochemistry 24(8), 1735 (1985)CrossRefGoogle Scholar

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© Springer Science+Business Media New York 2013