Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

2α,10α-Diacetoxy-6α-anisoyloxy-5α(H)-dauc-8-en-4β-ol (2α,10α-Diacetoxy-6α-p-anisate Jaeschkeanadiol)

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_978

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Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Triesters

Biological sources: Ferula communis L. subsp. communis [1]

C27H36O8: 488.2410

Mp: 155–156°C (hexane–EtOAc, 3:1), colorless tetragonal plates [1]

UV (CHCl3) 263 (ε 8200) [1]

IR (KBr): 3520, 2975, 2940, 2885, 2860, 1739, 1720, 1693, 1650, 1608, 1580, 1465, 1442, 1380, 1320, 1302, 1258, 1172, 1130, 1103, 1080, 1031, 995, 850, 775, 700 [1]

MS: 488 [M]+ (0.4), 471 [M − H2O + H]+ (1.4), 445 [M − iso-Pr]+ (3.3), 385 [M − HOAc − iso-Pr]+ (12.5), 325 [M − 2 x HOAc − iso-Pr]+ (5.5), 293 [M − p-anisic acid − iso-Pr]+ (17.1), 276 [M − p-anisic acid − HOAc]+ (9.3), 261 [M − p-anisic acid − HOAc − Me]+ (4.7) 251 [M − p-anisic acid − acetate − iso-Pr + H]+ (6.2), 233 [M − p-anisic acid − HOAc − iso-Pr]+ (79.8), 216 [M − p-anisic acid − 2 × HOAc]+ (60.9), 201 [M − p-anisic acid − 2 x HOAc − Me]+ (14.2), 191 [M − p-anisic acid...

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References

  1. 1.
    M. Miski, T.J. Mabry, Phytochemistry 24(8), 1735 (1985)CrossRefGoogle Scholar

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