Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

10β-Angeloyloxy-6α-(4″-hydroxy-benzoyloxy)-5α(H)-dauc-8-en-4β-ol (Fertidin)

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_960

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Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Diesters

Biological sources: Ferula tenuisecta Korov. [1]

C27H36O6: 456.2512

Mp: 163–164°C [1]

UV 260 (4.17) [1]

IR: 3450, 3250, 1715, 1690, 1650, 1615, 1590, 1520 [1]

1H NMR: 0.8 and 0.9 (each 3H, d, J = 7, H-12, H-13), 1.16 (3H, s, H-14), 1.74 (3H, br s, H-15), 4.83 (1H, d, J = 8, H-10), 5.36 (1H, sextet, J = 11; 6; 3, H-6), 5.69 (1H, d, J = 8, H-10); OAng: 1.8–1.95 (6H, m, H-4′, H-5′), 6.01 (1H, m, H-3′); Op-HOBz: 6.78 (2H, d, J = 9.5, H-3″, H-5″), 7.81 (2H, d, J = 9.5, H-2″, H-6″), [1]

References

  1. 1.
    L.A. Golovina, A.I. Saidkhodzhaev, V.M. Malikov, Chem. Nat. Comp. 27, 701 (1991)CrossRefGoogle Scholar

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© Springer Science+Business Media New York 2013