Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

10α-Angeloyloxy-6β-anisoyloxy-5α(H)-dauc-8-en-4β-ol (10α-Angeloyloxy-6α-anisate of Jaeschkeanadiol)

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_957

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Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Diesters

Biological sources: Ferula communis L. subsp. communis [1]

C28H38O6: 470.2668

Mp: gum [1]

UV (CHCl3) 261 (ε 17750) [1]

IR (CHCl3): 3510, 2980, 2940, 2882, 1710, 1660, 1610, 1583, 1516, 1464, 1445, 1428, 1380, 1320, 1305, 1263, 1172, 1120, 1108, 1040, 960, 936, 853 [1]

MS: 470 [M]+ (0.1), 427 [M − C3H7]+ (0.51), 327 [M − angelic acid – C3H7]+ (18.9), 275 [M − p-anisic acid − C3H7]+ (12.5), 257 [M − p-anisic acid − C3H7 − H2O]+ (3.93), 235 [M − p-anisic acid − angelate]+ (28.9), 218 [M − p-anisic acid − angelic acid]+ (57.6), 203 [M − p-anisic acid − angelic acid − CH3]+ (22.2), 201 [M − p-anisic acid − angelic acid − H2O]+ (26.5), 175 [M − p-anisic acid − angelic acid − C3H7]+ (91.5), 157 [M − p-anisic acid − angelic acid − C3H7 − H2O]+ (51.3), 152 [p-anisic acid]+ (66.8), 147 (53.2), 135 [p-anisate]+(100), 83...

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References

  1. 1.
    M. Miski, T.J. Mabry, Phytochemistry 24(8), 1735 (1985)CrossRefGoogle Scholar

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