Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

2α-Acetoxy-6α-anisoyloxy-8α,9α-epoxy-5α(H)-dauc-4β-ol (Ferkuchinin)

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_942

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Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Diesters

Biological sources: Ferula kuhistanica Korov. [1]

C25H34O7: 446.2306

Mp: 118–119°C [1]

[α]D +105° (c 1.0, CHCl3) [1]

UV 262 (4.1) [1]

IR: 3540, 1730, 1710, 1590, 1520 [1]

1H NMR: 0.81 and 0.93 (each 3H, d, J = 7, H-12, H-13), 1.3 (3H, s, H-14), 1.4 (3H, s, H-15), 2.40 (1H, d, J = 10, H-5), 2.73 (1H, t, J = 7, H-9), 4.78 (1H, d, J = 5, H-2), 5.32 (1H, sextet, J = 10; 10;2, H-6), 2.05 (3H, s, OAc); OAnis: 3.86 (3H, s, OCH3), 6.80 (2H, d, J = 8, H-3′, H-5′), 7.80 (2H, d, J = 8, H-2′, H-6′) [1]

References

  1. 1.
    A.I. Babekov, A.I. Saidkhodzhaev, B.M. Murzubraimov, B.M. Keneshov, Chem. Nat. Comp. 37, 247 (2001)Google Scholar

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