Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

2α-Acetoxy-6α-anisoyloxy-5α(H)-dauc-8-ene-4β,10β-diol (2α-Acetoxy-10-hydroxy-6α-p-anisate-jaeschkeanadiol)

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_940

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Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Diesters

Biological sources: Ferula communis L. subsp. communis [1]

C25H34O7: 446.2305

Mp: 152–154°C (hexane – EtOAc, 3:1), white prisms [1]

UV (CHCl3) 263 (ε 11720) [1]

IR (KBr): 3460, 2965, 2930, 2875, 1703, 1672, 1603, 1580, 1510, 1468, 1440, 1420, 1380, 1315, 1275, 1258, 1170, 1128, 1100, 1085, 1033, 970, 932, 900, 850, 830, 770, 700 [1]

MS: 446 [M]+ (0.25), 403 [M − iso-Pr]+ (14.5), 386 [M − HOAc]+ (0.6), 343 [M − HOAc − iso-Pr]+ (16.9), 251 [M − p-anisic acid − iso-Pr]+ (14.3), 234 [M − p-anisic acid − HOAc]+ (34.8), 216 [M − p-anisic acid − HOAc − H2O]+ (37.5), 201 [M − p-anisic acid − HOAc − H2O − CH3]+ (9.2), 191 [M − p-anisic acid − HOAc − iso-Pr]+ (68.7), 173 [M − p-anisic acid − HOAc − H2O]+ (48.3), 163 (44.5), 152 [p-anisic acid]+ (64.5), 148 (63.2), 135 [p-anisate]+(100), 120 (68.5), 105 (59.7), 92 (51),...

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References

  1. 1.
    M. Miski, T.J. Mabry, Phytochemistry 24(8), 1735 (1985)CrossRefGoogle Scholar

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