Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

6α-(3′-Methoxy-4′,5′-methylidenoxy-benzoyloxy)-4β-hydroxy-5α(H)-dauc-8-en-10-one (Palliferinin)

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_918

CAS Registry Number: 80535-88-2 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Monoesters

Biological sources: Ferula pallida Korov. [1]

C24H30O7: 430.1992

[α]D +185° (c 0.3, CHCl3) [1]

UV: 244 (4.05), 270 (4.12) [1]

IR: 3600–3350, 1700, 1640–1670, 1600, 1520 [1]

1H NMR: 0.85 (6H, d, J = 6.0, H-12, H-13), 1.35 (3H, s, H-14), 1.93 (3H, s, H-15), 5.93 (1H, m, H-9), 5.80 (1H, m, H-6); acyl group: 3.87 (3H, s, OCH3), 5.98 (2H, s, H-1″), 7.05 and 7.20 (2H, d, J = 2, H-2′, H-6′) [1]

References

  1. 1.
    A.Y. Kushmuradov, A.I. Saidkhodzhaev, A.Sh. Qadirov, Khim. Prir. Soedin. 523 (1981)Google Scholar

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© Springer Science+Business Media New York 2013