CAS Registry Number: 66559-24-8
Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Monoesters
Biological sources: Ferula tenuisecta Korov. [1, 2]; F. lancerottensis Parl. ex Hartung [3]; F. jaeschkeana Vatke [4]
C22H30O5: 374.2093
Mp: 164–165°C [1]
[α]D +75° (c 1.2, CHCl3) [1]
UV 263 (4.15) [1]
IR: 3550–3200, 1690, 1600, 1580, 1520 [1]; IR (CHCl3): 3600, 3350, 2970, 2890, 1695, 1620, 1590, 1515, 1450, 1385, 1310, 1270, 1170, 1120, 1100, 960, 920, 880, 850 [3]
EI-MS: 331 [M − C3H7]+, 234, 207, 191, 163, 151, 148 [3]
1 H NMR: 0.80 and 0.86 (6H, d, J = 6.5, H-12, H-13), 1.24 (3H, s, H-14), 1.45 (3H, s, H-15), 2.82 (1H, t, J = 6.5, H-9), 5.37(1H, sextet, J = 10.5; 10.5; 2.5, H-6); Op-HOBz: 6.72 (2H, d, J = 9.5, H-3′, H-5′), 7.75 (2H, d, J = 9.5, H-2′, H-6′) [1]
1 H NMR (90 MHz, CDCl3): 0.88 (6H, t, J = 8), 1.26 (3H, s, H-14), 1.48 (3H, s, H-15), 2.93 (1H, t, J = 8), 5.48 (1H, t, J = 11, H-6), 6.90...
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References
A.I. Saidkhodzhaev Terpenoids from plants of the Ferula L. genus, Author’s Abstract of a Doctoral Dissertation in Chemical Sciences, Tashkent (1984)
A.I. Saidkhodzhaev, Chem. Nat. Comp. 14, 55 (1978)
B.M. Fraga, A.G. Gonzalez, P. Gonzalez, M.G. Hernandez, C.L. Larruga, Phytochemistry 24(3), 501 (1985)
T.K. Razdan, B. Qadri, M.A. Qurishi, M.A. Khuroo, P.K. Kachroo, Phytochemistry 28(12), 3389 (1989)
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(2013). 6α-(4′-Hydroxy-benzoyloxy)-8α,9α-epoxy-5α(H)-dauc-4β-ol (p-Oxybenzoyl-epoxy-jaeschkeanadiol; Tenuferidin; Epoxyjaeschkeanadiol p-Hydroxybenzoate; Jaeskeanin). In: Azimova, S.S., Saidkhodzhaev, A.I. (eds) Natural Compounds. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0539-9_900
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