Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

6α-Anisoyloxy-8α,9α-epoxy-5α(H)-dauc-4β-ol (p-Methoxybenzoyl of Epoxy-Jaeschkeanadiol)

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_869

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Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Daucanes (Carotanes) – Monoesters

Biological sources: Ferula linkii Webb et Berthel. [1]; F. rigidula DC. [2]

C23H32O5: 388.2250

MP: 145–148°C [1]

IR: 3460, 3000, 2960, 2850, 1700, 1600, 1505, 1455, 1380, 1310, 1255, 1160, 1100, 1030, 955, 875, 845 [1]

MS: 388 [M]+ (0.2), 345 (5), 327 (0.3), 236 (1), 193 (10), 175 (5), 152 (23), 135 (100) [1]

1H NMR (90 MHz, CDCl3): 0.90 (6H, t, J = 8), 1.30 and 1.51 (6H, s), 2.90 (1H, t), 5.48 (1H, t, J = 11); OAnis: 3.91 (3H, s, OCH3), 6.96 (2H, d, J = 9, H-3′, H-5′), 7.98 (2H, d, J = 9, H-2′, H-6′) [1]

References

  1. 1.
    B.M. Fraga, A.G. Gonzalez, P. Gonzalez, M.G. Hernandez, J.G. Diaz, Phytochemistry 23(11), 2541 (1984)CrossRefGoogle Scholar
  2. 2.
    M. Miski, J. Jakupovic, Phytochemistry 29(1), 173 (1990)CrossRefGoogle Scholar

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