Natural Compounds

2013 Edition
| Editors: Shakhnoza S. Azimova, Ashraf I. Saidkhodzhaev

9α-(3′-Hydroxy-3′-methyl-4′-pentenoloxy)-8α-hydroxy-7α,10βH-eremophil-11(12)-en-2-one

Reference work entry
DOI: https://doi.org/10.1007/978-1-4614-0539-9_1037

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Taxonomy: Physicochemical and Pharmacological Properties of Sesquiterpene Esters – The Bicyclic Sesquiterpene Esters – Eremophilanes – Eremophilanes – Monoesters

Biological sources: Euryops algoensis DC. [1]

C21H32O5: 364.2250

IR (CCl4): [1]

1H NMR (400 MHz, CDCl3): 0.88 (3H, d, J = 7, H-15), 1.04 (3H, s, H-14), 1.29 (1H, dd, J = 13; 13; H-6β), 1.74 (3H, br s, H-13), 1.86 (1H, dd, J = 13; 3; H-6α), 2.03 (1H, ddd, J = 7; 3, H-10β), 2.14 (1H, br d, J = 15; H-1α), 2.18 (1H, ddd, J = 15; 12.5; H-3β), 2.30 (1H, ddd, J = 15; 5; H-3α), 2.49 (1H, ddd, J = 3; 13; 13; H-7α), 2.61 (1H, dd, J = 15; 7; H-1β), 2.71 (1H, ddq, J = 5; 12.5; 7, H-4), 3.60 (1H, ddd, J = 13; 3.5; 2, H-8), 4.83 (1H, br s, H-12b), 4.87 (1H, br s, H-12a), 5.30 (1H, dd, J = 3.5; 3, H-9); acyl group: 1.35 (3H, s, H-6′), 2.50 (2H, s, H-2′), 5.28 and 5.08 (each 1H, dd, J = 16; 10; 1, H-5′), 6.01 (1H, J = 16; 10, dd, H-4′) [1]

References

  1. 1.
    P. Gonser, J. Jakupovic, G.M. Mungali, Phytochemistry 30(3), 899 (1991)CrossRefGoogle Scholar

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