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Polymer Surface Treatment and Coating Technologies

  • Mary GilliamEmail author
Reference work entry

Abstract

An overview of surface modification and coating techniques for plastics is presented for changing the surface properties to meet the performance requirements in a variety of applications. Surface modification and coatings are utilized for purposes of adhesion, wettability, biocompatibility, scratch and abrasion resistance, chemical resistance, barrier properties, and more. Methods for modification include physical processes, such as surface roughening and abrading; liquid chemical processes, such as acid etching; and reactive gas chemical processes. The reactive gas chemical processes covered include corona, flame, and low-temperature plasma. Surface degradation from reactive gas exposure is presented with respect to the sources, chemical mechanisms, and methods for characterization. Coatings for plastics, including paints, functional coatings, and metallization, are summarized.

Keywords

Surface Treatment Plasma Treatment Polymer Surface Abrasion Resistance Surface Functional Group 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. Althaus J, Urwyler P, Padeste C, Heuberger R, Deyhle H, Schift H, Gobrecht J, Peiles U, Scharnweber D, Peters K, Muller B (2012) Micro- and nanostructured polymer substrates for biomedical applications. In: Bioinspiration, biomimetics, and bioreplication proceedings, San Diego, CAGoogle Scholar
  2. Athey RD (2006) Metal coatings. In: Tracton A (ed) Coatings technology handbook, 3rd edn. Taylor & Francis, Boca Raton, p 101-1Google Scholar
  3. Bardos L, Barankova H (2010) Cold atmospheric plasma: sources, processes, and applications. Thin Solid Films 518:6705–6713CrossRefGoogle Scholar
  4. Bernheim EA (2006) Silicone hard coatings. In: Tracton A (ed) Coatings technology handbook, 3rd edn. Taylor & Francis, Boca Raton, p 93-1Google Scholar
  5. Brewis D, Mathieson I (1999) Flame treatment of polymers to improve adhesion. In: Mittal KL (ed) Adhesion promotion techniques: technological applications. Marcel Dekker, New York, pp 175–190Google Scholar
  6. Brynolf J. ATmaP™ Implementation at Venture Industries. http://www.ftstechnologies.com/case_studies/FTSCS001.PDF. Accessed 12 July 2013
  7. IHS Chemical Report (2011) Radiation curable coatings, Englewood, COGoogle Scholar
  8. Fozza AC, Kemberg-Sapieha JE, Wertheimer MR (1999) Vacuum ultraviolet irradiation of polymers. Plasma Polym 4(2/3):183–206CrossRefGoogle Scholar
  9. France RM, Short RD (1998) Plasma treatment of polymers: the effects of energy transfer from an argon plasma on the surface chemistry of polystyrene and polypropylene. Langmuir 14:4827–4835CrossRefGoogle Scholar
  10. Fried JR (1995) Polymer science and technology. Prentice Hall PTR, Englewood CliffsGoogle Scholar
  11. Garrido L, Jimenez I, Ellis G, Cano P, Garcia-Martinez JM, Lopez L, de la Pena E (2010) Characterization of surface-modified polyalkanoate films for biomedical applications. J Appl Polym Sci 119:3286–3296CrossRefGoogle Scholar
  12. Gilliam M, Yu Q (2008) Low-temperature plasma processes for polymeric surface modification. In: Lee S (ed) Encyclopedia of chemical processing. Taylor & Francis, London, pp 1–10Google Scholar
  13. Guimond S, Wertheimer MR (2004) Surface degradation and hydrophobic recovery of polyolefins treated by air corona and nitrogen atmospheric pressure glow discharge. J Appl Polym Sci 94:1291–1303CrossRefGoogle Scholar
  14. Hart A (1996) Electroplating of plastics. Mater World 4:265–267Google Scholar
  15. Henkel Corporation (2011) Design guide for bonding plastics, vol 6, Englewood, COGoogle Scholar
  16. Huber HF, Stoye D (2006) Polyesters. In: Tracton A (ed) Coatings technology handbook, 3rd edn. Taylor & Francis, Boca Raton, pp 50–51Google Scholar
  17. Izzo CP (2000) Coatings and finishes. In: Harper C (ed) Modern plastics handbook. McGraw-Hill, New York, pp 10.1–10.59Google Scholar
  18. Jacobs T, Morent R, De Geyter N, Dubruel P, Leys C (2012) Plasma surface modification of biomedical polymers: influence on cell-material interaction. Plasma Chem Plasma Process 32:1039–1073CrossRefGoogle Scholar
  19. Jama C et al (1999) Characterization of polyethylene surface heated after plasma fluorination. Surf Interface Anal 27:653–658CrossRefGoogle Scholar
  20. Klemberg-Sapieha JE et al (1991) Dual-frequency N2 and NH3 plasma modification of polyethylene and polyimide. J Vac Sci Technol A 9:2975–2981CrossRefGoogle Scholar
  21. Koleske JV (2006) Radiation-cured coatings. In: Tracton A (ed) Coatings technology handbook, 3rd edn. Taylor & Francis, Boca Raton, p 97-1Google Scholar
  22. Landgraf R, Kaiser MK, Posseckardt J, Adolphi B, Fischer WJ (2009) Functionalization of polymer sensor surfaces by oxygen plasma treatment. Proc Chem 1:1015–1018CrossRefGoogle Scholar
  23. Langmuir I (1938) Overturning and anchoring of monolayers. Science 87(2266):493–500CrossRefGoogle Scholar
  24. Liepins R (2006) Conductive coatings. In: Tracton A (ed) Coatings technology handbook, 3rd edn. Taylor & Francis, Boca Raton, p 91-1Google Scholar
  25. Markgraf D (2004) Analysis of new flame treatment technology for surface modification and adhesion promotion. In: TAPPI PLACE conference proceedings, Indianapolis, INGoogle Scholar
  26. Markgraf D Corona Treatment: An Overview. Enercon Industries Corporation. http://www.enerconind.com/mediaLib/stml/techPaper/Enercon-corona-treating-overview.pdf?ext=.pdf. Accessed 2 September 2012
  27. MIELE: Quality assurance on tumble dryers through plasma. http://www.sabic-ip.com/gep/en/NewsRoom/PressReleaseDetail/october_11_2012_sabicandulvacannounce.html. Accessed 12 July 2013
  28. Momose Y, Tamura Y, Ogino M, Okazaki S (1992) Chemical reactivity between teflon surfaces subjected to argon plasma treatment and atmospheric oxygen. J Vac Sci Technol A 10:229–238CrossRefGoogle Scholar
  29. Moss SJ et al (1986) Plasma oxidation of polymers. Plasma Chem Plasma Process 6(4):401–416CrossRefMathSciNetGoogle Scholar
  30. Nagao T et al (2006) Challenge to chromium-free plastic plating method. Galvanotechnik 97(9):2124–2130Google Scholar
  31. Nordstrom JD (2003) Polymers for coatings for plastics. In: Ryntz RA, Yaneff PV (eds) Coatings of polymers and plastics. Marcel Dekker, New York, pp 121–155Google Scholar
  32. Ogino A, Noguchi S, Nagatsu M (2011) Low temperature plasma treatment for immobilization of biomaterials on polymer surface. Adv Mat Res 222:297–300CrossRefGoogle Scholar
  33. Proell. Pad printing – theory and practice. http://www.proell.de/_files/pdf/Pad%20Printing%20Theory%20and%20Practice.pdf. Accessed 21 Oct 2012
  34. Rangel EC et al (2003) Enhancement of polymer hydrophobicity by SF6 plasma treatment and argon plasma immersion ion implantation. Surf Interface Anal 35:179–183CrossRefGoogle Scholar
  35. Regis S et al (2012) Altering surface characteristics of polypropylene mesh via sodium hydroxide treatment. J Biomed Mater Res A 100A(5):1160–1167CrossRefGoogle Scholar
  36. Ryntz RA, Yaneff PV (2003) Coatings of polymers and plastics. Marcel Dekker, New YorkCrossRefGoogle Scholar
  37. SABIC and ULVAC announce availability of new ULGLAZE system for high-volume plasma coating of automotive PC glazing components. http://www.sabic-ip.com/gep/en/NewsRoom/PressReleaseDetail/october_11_2012_sabicandulvacannounce.html. Accessed 12 July 2013
  38. Schlechter M (2010) Medical plastics market. BCC Research, Wellesley, MAGoogle Scholar
  39. Schonhorn H, Hansen RH (1967) Surface treatment of polymers for adhesive bonding. J Appl Polym Sci 11:1461–1474CrossRefGoogle Scholar
  40. Sheng E et al (1995) Effects of the chromic acid etching on propylene polymer surfaces. J Adhes Sci Technol 9(1):47–60CrossRefGoogle Scholar
  41. SmartAdhesives. Surface prep guide for adhesives. http://www.adhesive.com/instructions_detail_surfaceprep__adhesives_application.html. Accessed 2 Sept 2012
  42. Stay KE (2012) InnoVoc Solutions™ technology enables powder coating for plastics, composites and other non-metallic substrates. http://www.innovocsolutions.com/pressreleases.html. Accessed 15 Mar 2014
  43. Strobel M et al (1996) Flame surface modification of polypropylene film. J Adhes Sci Technol 10(6):515–539CrossRefGoogle Scholar
  44. Strobel M, Jones V, Lyons CS, Ulsh M, Kushner MJ, Dorai R, Branch MC (2003) A comparison of corona-treated and flame-treated polypropylene films. Plasma Polym 8(1):61–95CrossRefGoogle Scholar
  45. Tatoulian M et al (2004) Plasma surface modification of organic materials: comparison between polyethylene films and octadecyltrichlorosilane self-assembled monolayers. Langmuir 20:10481–10489CrossRefGoogle Scholar
  46. Tolinski M (2009) Coating alternatives for plastics: optical coatings and VOC-free technologies are becoming clearer options. Plast Eng 65(5):6–8Google Scholar
  47. Tracton A (2006a) Coatings technology handbook, 3rd edn. Taylor & Francis, Boca RatonCrossRefGoogle Scholar
  48. Tracton A (2006b) Coatings technology handbook, 3rd edn. Marcel Dekker, New YorkCrossRefGoogle Scholar
  49. Vaskelis A (2006) Electroless plating. In: Tracton A (ed) Coatings technology handbook, 3rd edn. Taylor & Francis, Boca Raton, p 27-1Google Scholar
  50. Vetaphone. http://www.vetaphone.com/?page=History&id=7. Accessed 2 Sept 2012
  51. Weikart CM, Yasuda HK (2000) Modification, degradation, and stability of polymeric surface treated with reactive plasmas. J Polym Sci A 38:3028–3042CrossRefGoogle Scholar
  52. Wertheimer MR, Martinu L, Liston EM (2002) Plasma sources for polymer surface treatment. In: Glocker DA (ed) Handbook of thin film process technology, vol 2. Institute of Physics Publishing, Bristol, pp E3.0:1–E3.0:38Google Scholar
  53. Wicks ZW, Jones FN, Pappas SP (2007) Organic coatings: science and technology, 3rd edn. Wiley, HobokenCrossRefGoogle Scholar
  54. Wolf RA (2010) Plastic surface modification. Hanser, MunichCrossRefGoogle Scholar
  55. Yasuda H (2005) Luminous chemical vapor deposition and interface engineering. Marcel Dekker, New YorkGoogle Scholar

Copyright information

© Springer-Verlag London 2015

Authors and Affiliations

  1. 1.Department of Chemical EngineeringKettering UniversityFlintUSA

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