Skip to main content

pH Electrodes - Industrial, Medical, and Other Applications

  • Reference work entry
  • First Online:
Encyclopedia of Applied Electrochemistry
  • 136 Accesses

Introduction

The pH value of a solution is a measure of the activity of hydronium ions (H 3 O + ⇌ H + + H 2 O) in the solution and as such it is a measure of the acidity or basicity of that medium. On the one hand pH stands for power of hydrogen (H); on the other hand, the term pH is derived from p, the mathematical symbol of the negative logarithm. The pH value is often simply referred to as concentration of hydrogen ions. Acids and bases are connected with free hydronium and hydroxyl ions, respectively. The relationship between hydronium and hydroxyl ions in a given solution is constant for a given set of conditions and one can be determined by knowing the other. The usual range of pH values encountered is between 0 and 14, with 0 being the value for concentrated acids, 7 being the value for pure water, and 14 being the value for concentrated lyes. It is possible to get pH values <0 (e.g., 10 M HCl) and >14 (e.g., 10 M NaOH). In Fig. 1examples of pH values of a selection of...

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 999.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 549.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Shipman J, Wilson J (1990) An introduction to physical science. D. C. Heath, Boston

    Google Scholar 

  2. Schwabe K (1969) pH-Fibel. Deutscher Verlag für Grundstoffindustrie, Leipzig

    Google Scholar 

  3. Vonau W, Oelßner W, Schwarz J, Hörig A, Kohnke HJ, Heller G, Kurzenknabe (2011) German Patent DE 10 2011 113 941

    Google Scholar 

  4. Cremer M (1906) Über die Ursachen der elektromagnetischen Eigenschaften der Gewebe, zugleich ein Beitrag zur Lehre von den polyphasischen Elektrolytketten. Z Biol 46:562–608

    Google Scholar 

  5. Solokow AI, Passinski AH (1932) Über Glaselektroden. Z Phys Chem A 160:366–377

    Google Scholar 

  6. Ross JW (1982) Potentiometrische Elektrode. German Patent, DE 146 066

    Google Scholar 

  7. Kratz L (1950) Die Glaselektrode und ihre Anwendungen. Dietrich Steinkopff, Frankfurt

    Google Scholar 

  8. Vonau W, Guth U (2006) pH monitoring: a review. J Solid State Electrochem 10(9):746–752

    CAS  Google Scholar 

  9. Emmerich B (1978) Die Emailelektrode, eine neue Lösung zur pH-Messung im Betrieb. Regelungstechn. Praxis 20:313

    Google Scholar 

  10. Bergveld P (1972) Development, operation and application of the ion-selective field-effect transistor as a tool for electrophysiology. IEEE Trans Biomed Eng 19:340–351

    Google Scholar 

  11. Brischwein M, Motrescu ER, Otto AM, Cabala E, Grothe H, Wolf B (2003) Functional cellular assays with multiparametric silicon sensor chips. Lab Chip 3(4):234–240

    CAS  Google Scholar 

  12. Vandenplas Y, Badriul H, Verghote M, Hauser B, Kaufman L (2004) Glass and antimony electrodes for oesophageal pH monitoring in distressed infants: how different are they? Eur J Gastroenterol Hepatol 16:1325–1330

    Google Scholar 

  13. Biilmann ME (1921) Sur I′hydrogenation des quinhydrones. Ann Chim 15:109–157

    Google Scholar 

  14. Kahlert H, Pörksen JR, Behnert J, Scholz F (2005) FIA acid-base titration with a new flow-through PH detector. Anal Bioanal Chem 382:1981–1986

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Winfried Vonau .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer Science+Business Media New York

About this entry

Cite this entry

Vonau, W. (2014). pH Electrodes - Industrial, Medical, and Other Applications. In: Kreysa, G., Ota, Ki., Savinell, R.F. (eds) Encyclopedia of Applied Electrochemistry. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-6996-5_229

Download citation

Publish with us

Policies and ethics