Magnetic resonance spectroscopies are methods capable of detecting transitions of spin orientations of electrons or atomic nuclei between states separated energetically under the influence of an external magnetic field. Transitions involving the spin of the nucleus of an atom with a nonzero magnetic moment are studied with nuclear magnetic resonance spectroscopy (NMR), whereas transitions involving the spin of unpaired electrons in paramagnetic samples are investigated with electron spin resonance spectroscopy (ESR) (Frequently this method has been called electron paramagnetic resonance spectroscopy (EPR) because the presence of one or several unpaired electrons being a precondition for this spectroscopy is also closely related to the phenomenon of paramagnetism.) [1]. Both methods are widely employed in analytical chemistry. NMR preferably of protons and 13C-atoms and further selected atoms is presumably the most important method in analytical organic chemistry. ESR is used less...
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Krička, M., Holze, R. (2014). Magnetic Resonance Spectroscopy. In: Kreysa, G., Ota, Ki., Savinell, R.F. (eds) Encyclopedia of Applied Electrochemistry. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-6996-5_227
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