Introduction
Salts play an important role in the development of mankind. Probably since more than 10,000 years, man uses sodium chloride to conserve food. It was often called “the white gold,” an expression that highlights the importance and value of this chemical. Workers were in medieval times paid with salt, hence the word “salary” for their income. Many other processes like leather tanning with mineral salts depended and still depend on salts. Acids (vinegar) and bases (soaps) also have played important roles in human culture. And in general, life on earth is not imaginable without electrolytes.
Still, the molecular composition of electrolytes in general and their behavior in solvents is known only since several decades, and still its properties are not fully understood. Man is capable of flying to the moon, but the prediction of activity coefficients of NaCl in water is still a challenge.
History
The history of scientific comprehension of electrolytes begins in the nineteenth...
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Berzelius JJ (1819) Essai sur la théorie des proportions chimiques et sur l’influence chimique de l’électricité. Paris, p 98
Faraday M (1834) On electrochemical decomposition (Reprinted in [4], pp 11–44, Original paper: Faraday M (1834) Experimental researches in electricity. Seventh series. Phil Trans R Soc Lond 124:77–122)
Hittorf W (1853) Über die Wanderung der Ionen während der Elektrolyse. Pogg Ann 89:177–211
Goodwin HM (Ed) (1899) The fundamental laws of electrolytic conduction. Memoirs by Faraday, Hittorf and F Kohlrausch. Harper & brothers, New York/London
Pfeffer W (1877) Osmotische Untersuchungen. Studien zur Zellmechanik, Leipzig, Wilhem Engelmann (Reprint 1921)
Hofmeister F (1888) Ueber die wasserentziehende Wirkung der Salze. Naunyn-Schmiedebergs Archiv für experimentelle Pathologie und Pharmakologie 25:1–30; Citation taken from: Kunz W, Henle J, Ninham BW (2004) Zur Lehre von der Wirkung der Salze (About the science of the effect of salts): Franz Hofmeister’s historical papers. Curr Op Coll Interf Sci 9:37
Hoff JH (1884) Etudes de dynamique chimique, Frederik Muller, Oxford University; Die Rolle des osmotischen Druckes in der Analogie zwischen Lösungen und Gasen (1887) Z phys Chem 1:481–508; see also: Planck M (1887) Ueber die molare Konstitution verdünnter Lösungen. Z phys Chem 1:577–582
Arrhenius S (1887) Über die Dissociation der in Wasser gelösten Stoffe. Z Phys Chem 1:631–648
Ostwald W (1988) Über die Dissociationstheorie der Elektrolyte. Z Phys Chem 2:270–283
Kohlrausch F (1876) On the conductivity of electrolytes dissolved in water in relation to the migration of their compounds in [4], pp 83–92; Kohlrausch FWG, Holborn LFC (1898) Das Leitvermögen der Elektrolyte, insbesondere der Lösungen. Methoden, Resultate und chemische Anwendungen. Teubner BG, Leipzig
Nernst WH (1889) Die elektromotorische Wirksamkeit der Ionen. Z Phys Chem Stöchiom Verwandtschaftslehre 4:129–181
Walden P (1924) Elektrochemie nichtwässeriger Lösungen. Bredigs Handb d angew physikal Chemie, 13. Bd. Barth, Leipzig
Debye P, Hückel E (1923) Zur Theorie der Elektrolyte. Physik Z 24:185–206
Bjerrum N (1926) Untersuchungen über Ionenassoziation. Kgl Danske Vidensk Math-Fysiske Medd VIII 9:1–47
Onsager L, Fuoss RM (1932) Irreversible processes in electrolytes. Diffusion, conductance and viscous flow in arbitrary mixtures of strong electrolytes. J Phys Chem 36:2689–2778
Ornstein LS, Zernike F (1914) Accidental deviations of density and opalescence at the critical point of a single substance. Proc Acad Sci (Amsterdam) 17:793–804
Ramanathan PS, Friedman HL (1971) Study of a refined model for aqueous 1-1- electrolytes. J Chem Phys 54:1086–1099
Pitzer KS (1979) Theory: ion interaction approach. In: Pytkowicz RM (ed) Activity coefficients in electrolyte solutions, vol 1. CRC Press, Boca Raton, pp 158–208
Bernard O, Kunz W, Turq P, Blum L (1992) Self-diffusion in electrolyte solutions using the mean spherical approximation. J Phys Chem 96:398–403; Conductance in electrolyte solutions using the mean spherical approximation. ibid 96:3833–3840
Heinzinger K (1985) Computer simulations of aqueous electrolyte solutions. Physica 131B:196–216
Levesque D, Weis JJ, Hansen JP (1986) In: Binder K (ed) Monte Carlo methods in statistical physics (topics in current physics), 2nd edn. Springer, Berlin
Fyta M, Kalcher I, Dzubiella J, Vrbka L, Netz RR (2010) Ionic force field optimization based on single-ion and ion-pair solvation properties. J Chem Phys 132:024911/1–024911/10
Palinkas G, Kalman E (1981) X-ray diffraction on electrolyte solutions in the low angle range. Z Naturforsch Teil A 36A:1367–1370
Neilson GW, Enderby JE (1979) Neutron and x-ray diffraction studies of concentrated aqueous electrolyte solutions. Annu Rep Prog Chem Sect C Phys Chem 76:185–220
Buchner R, Barthel J (2001) Dielectric relaxation in solutions. Annu Rep Prog Chem Sect C Phys Chem 97:349–382
Tielrooij KJ, Garcia-Araez N, Bonn M, Bakker HJ (2010) Cooperativity in ion hydration. Science 328:1006–1009
Helmholtz H (1853) Ueber einige Gesetze der Vertheilung elektrischer Ströme in körperlichen Leitern mit Anwendung auf die thierisch-elektrischen Versuche. Ann Phys Chem (Leipzig) 165 (ser 2, vol 89, ser 3, vol 29):211–233
Gouy LG (1910) Gouy. Sur la constitution de la charge électrique à la surface d’un électrolyte. J Phys Théor Appl Ser 4 9:457–467
Chapman DL (1913) A contribution to the theory of electrocapillarity. Lond Edinb Dublin Philos Mag J Science Ser 6 25:475–481
Stern O (1924) Zur Theorie der Elektrolytischen Doppelschicht. Z Elektrochem Angew Phys Chem 30:508–516
Motschmann H, Koelsch P (2010) Linear and non-linear optical techniques to probe ion profiles at the air-water interface. In [33], pp 119–147
Padmanabhan V, Girard L, Daillant J, Belloni L (2010) X-ray studies of ion specific effects. In [33], pp 149–169
Jungwirth P, Winter B (2008) Ions at aqueous interfaces: from water surface to hydrated proteins. Annu Rev Phys Chem 59:343–366
Kunz W (ed) (2010) Specific ion effects. World Scientific, Singapore
Krauss D, Eisenberg B, Gillespie D (2011) Selectivity sequences in a model calcium channel: role of electrostatic field strength. Eur Biophys J 40:775–782
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer Science+Business Media New York
About this entry
Cite this entry
Kunz, W. (2014). Electrolytes, History. In: Kreysa, G., Ota, Ki., Savinell, R.F. (eds) Encyclopedia of Applied Electrochemistry. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-6996-5_10
Download citation
DOI: https://doi.org/10.1007/978-1-4419-6996-5_10
Published:
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4419-6995-8
Online ISBN: 978-1-4419-6996-5
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics