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Handbook of Nuclear Chemistry pp 2429–2458Cite as

Radiochemical Separations by Thermochromatography

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Abstract

The history, theoretical fundamentals, and practical application of thermochromatography are briefly reviewed. The main advantages of the method – the speed and selectivity of chemical separation of complex mixtures of short-lived radionuclides, including transactinide ones – are analyzed. Prospects of thermochromatography in production of radionuclides widely used in science and technology are considered on the basis of the performed systematic investigations of the thermochromatographic behavior of volatile compounds of the elements of the periodic table.

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Acknowledgments

The authors are grateful to Dr. A. B. Yakushev and Dr. S. N. Timokhin for providing information and important comments that helped to complete this review. The authors acknowledge to contribution by Dr. Ch. Düllmann concerning the recent developments related to the transactinide elements.

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Authors and Affiliations

  1. Joint Institute of Nuclear Research, Dubna, Russian Federation

    A. F. Novgorodov & N. A. Korolev

  2. Johannes Gutenberg-University of Mainz, Mainz, Germany

    F. Rösch

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  1. A. F. Novgorodov
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  2. F. Rösch
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  3. N. A. Korolev
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Editors and Affiliations

  1. Institute of Chemistry, Eötvös Loránd University, 32, Budapest, 1518, Hungary

    Attila Vértes (Professor Emeritus) & Sándor Nagy (Professor) (Professor Emeritus) &  (Professor)

  2. Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, Budapest, 1025, Hungary

    Zoltán Klencsár (Dr.) (Dr.)

  3. Institute of Nuclear Research (ATOMKI), Hungarian Academy of Sciences, 51, Debrecen, 4001, Hungary

    Rezső G. Lovas (Professor) (Professor)

  4. Institute of Nuclear Chemistry, Johannes Gutenberg University Mainz, Fritz-Strassmann-Weg 2, 55128, Mainz, Germany

    Frank Rösch (Professor) (Professor)

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Novgorodov, A.F., Rösch, F., Korolev, N.A. (2011). Radiochemical Separations by Thermochromatography. In: Vértes, A., Nagy, S., Klencsár, Z., Lovas, R.G., Rösch, F. (eds) Handbook of Nuclear Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-0720-2_53

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