Definition
Calcium (Ca) has the atomic number 20 and is an alkaline earth metal with an atomic mass of 40.978 amu. The important role of Ca in biogeochemical processes is based on its chemical versatility, which is related to its highly adaptable coordination geometry, its divalent charge, modest binding energies, fast reaction kinetics, and its inertness in redox reactions (Williams, 1974). Calcium is a soft grey alkaline earth metal, and is the fifth most abundant element in the Earth’s crust and the seventh most abundant element in the ocean. It is essential for living organisms, particularly in cell physiology, shell formation, and calcification and hence, is usually the most common metal in many animals.
Calcium isotopes and their application in Biogeochemistry
There are seven Ca isotopes present in nature of which three isotopes (42Ca (0.646%), 43Ca (0.135%) through 44Ca (2.086%)) are stable, one isotope (40Ca (69.941%)) is radiogenic, one isotope (41Ca) is cosmogenic, and two...
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Bibliography
Amini, M., Eisenhauer, A., Holmden, C., Boehm, F., Hauff, F., and Jochum, K. P., 2008. d44/40Ca variability in igneous rocks. Geochimica et Cosmochimica Acta 72(12), A19–A19.
Berner, R. A., 2004. A model for calcium, magnesium and sulfate in seawater over Phanerozoic time. American Journal of Science, 304, 438–453.
Berner, E. K., and Berner, R. A., 1996. Global Environment: Water, Air, and Geochemical Cycles. Upper Saddle River: Prentice Hall.
De La Rocha, C. L., and DePaolo, D. J., 2000. Isotopic evidence for variations in the marine calcium cycle over the Cenozoic. Science, 289, 1176–1178.
Demicco, R. V., Lowenstein, T. K., and Hardie, L. A., 2003. Atmospheric pCO2 since 60 Ma from records of seawater pH, calcium, and primary carbonate mineralogy. Geology, 31(9), 793–796.
Fantle, M. S., and DePaolo, D. J., 2005. Variations in the marine Ca cycle over the past 20 million years. Earth and Planetary Science Letters, 237, 102–117.
Farkas, J., Böhm, F., et al. 2007. Calcium isotope record of Phanerozoic oceans: Implications for chemical evolution of seawater and its causative mechanisms. Geochimica et Cosmochimica Acta 71(21), 5117–5134.
Griffith, E. M., Paytan, A., Caldeira, K., Bullen, T. D., and Thomas E., 2008. A dynamic marine calcium cycle during the past 28 million years. Science, 322, 1671–1674.
Gussone, N., Eisenhauer, A., Heuser, A., Dietzel, M., Bock, B., Böhm, F., Spero, H., Lea, D. W., Bijma, J., and Nägler, T. F., 2003. Model for kinetic effects on calcium isotope fractionation (δ44Ca) in inorganic aragonite and cultured planktonic foraminifera. Geochim Cosmochim Acta, 67(7), 1375–1382.
Hart, S. R., and Zindler, A., 1989. Isotope fractionation laws: a test using calcium. International Journal of Mass Spectrometry and Ion Physics, 89, 287–301.
Hippler, D., Eisenhauer, A., and Thomas, F. N., 2006. Tropical Atlantic SST history inferred from Ca isotope thermometry over the last 140 ka. Geochim Cosmochim Acta, 70, 90–100.
Heuser, A., Eisenhauer, A., Böhm, F., Wallmann, K., Gussone, N., Pearson, P. N., Nägler, T. F., and Dullo, W.-C., 2005. Calcium isotope (d44/40Ca) variations of Neogene planktonic foraminifera. Paleoceanography, 20.
Lemarchand, D., Wasserburg, G. J., and Papanastassiou, A., 2004. Rate-controlled calcium isotope fractionation in synthetic calcite. Geochim Cosmochim Acta, 68(22), 4665–4678.
Nägler, T. F., Villa, I. M., 2000. In pursuit of the 40K branching ratios: K-Ca and 39Ar-40Ar dating of gem silicates. Chem Geol 169, 5–16.
Nägler, T., Eisenhauer, A., Müller, A., Hemleben, C., and Kramers, J., 2000. The δ44Ca-isotopes: new powerful tool for reconstruction of past sea surface temperatures. Geochemistry, Geophysics, Geosystems, 1, doi: 2000GC000091.
Thompson, G., 1983. Hydrothermal Fluxes in the Ocean. New York: Academic Press.
Williams, R. J. P., 1974. Calcium ions: their ligands and their function. Biochemical Society Symposia, 39, 133–138.
Zhu, P., and Macdougall, J. D., 1998. Calcium isotopes in the marine environment and the oceanic calcium cycle. Geochim Cosmochim Acta, 62(10), 1691–1698.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2011 Springer Science+Business Media B.V.
About this entry
Cite this entry
Eisenhauer, A. (2011). Calcium Biogeochemistry. In: Reitner, J., Thiel, V. (eds) Encyclopedia of Geobiology. Encyclopedia of Earth Sciences Series. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-9212-1_40
Download citation
DOI: https://doi.org/10.1007/978-1-4020-9212-1_40
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-9211-4
Online ISBN: 978-1-4020-9212-1
eBook Packages: Earth and Environmental ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences