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Abstract

Nearly all materials are dielectrics, and the measurement of their dielectric response is a very common technique for their characterisation. This chapter is intended to guide scientists and engineers through the subject to the point where they can interpret their data in terms of the microscopic and atomistic dynamics responsible for the dielectric response, and hence derive useful information appropriate to their particular needs. The focus is on the physical concepts underlying the observed behaviour and is developed from material understandable by an undergraduate student. Emphasis is placed on the information content in the data, and the limits to be placed on its interpretation are clearly identified.

Generic forms of behaviour are identified using examples typical of different classes of material, rather than an exhaustive review of the literature. Limited-range charge transport is included as a special item. The theoretical concepts are developed from a basic level up to the ideas current in the field, and the points where these are controversial have been noted so that the readers can choose for themselves how far to rely on them.

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Abbreviations

AC:

alternating current

DC:

direct current

References

  1. P. Debye: Polar Molecules (Dover, New York 1945)

    Google Scholar 

  2. C. P. Smyth: Dielectric Behaviour and Structure (McGraw–Hill, New York 1955)

    Google Scholar 

  3. N. G. McCrum, B. E. Read, G. Williams: Anelastic and Dielectric Effects in Polymeric Solids (Wiley, New York 1967)

    Google Scholar 

  4. V. V. Daniels: Dielectric Relaxation (Academic, New York 1967)

    Google Scholar 

  5. C. J. F. Bottcher, P. Bordewijk: Theory of Electric Polarisation, Vol. I,II (Elesvier, Amsterdam 1978)

    Google Scholar 

  6. A. K. Jonscher: Dielectric Relaxation in Solids (Chelsea Dielectric, London 1983)

    Google Scholar 

  7. K. L. Ngai, G. B. Wright (Eds.): Relaxations in Complex Systems. In: Proc. The International Discussion Meeting on Relaxations in Complex Systems (Elsevier, Amsterdam 1991)

    Google Scholar 

  8. R. M. Hill: Electronic Materials from Silicon to Organics. In: Dielectric properties and materials, ed. by L. S. Miller, J. B. Mullin (Plenum, New York 1991) pp. 253–285

    Google Scholar 

  9. T. Furukawa: IEEE Trans. E.I. 24, 375 (1989)

    CAS  Google Scholar 

  10. C. J. F. Bottcher: Theory of Electric Polarisation (Elsevier, Amsterdam 1952) p. 206

    Google Scholar 

  11. M. Born, E. Wolf: Principles of Optics (Pergamon, Oxford 1965)

    Google Scholar 

  12. A. R. von Hippel (ed.): Dielectric Materials and Applications (Wiley, New York 1958)

    Google Scholar 

  13. R. N. Clarke, A. Gregory, D. Connell, M. Patrick, I. Youngs, G. Hill: Guide to the Characterisation of Dielectric Materials at RF and Microwave Frequencies. In: NPL Good Practice Guide (Pub. Inst. Measurement and Control, London 2003)

    Google Scholar 

  14. W. Heitler: The Quantum Theory of Radiation, 3rd edn. (Dover, London 1984)

    Google Scholar 

  15. D. Bohm, D. Pines: Phys. Rev. 82, 625 (1951)

    Article  CAS  Google Scholar 

  16. H. Eyring, J. Walter, G. E. Kimball: Quantum Chemistry (Wiley, New York 1960)

    Google Scholar 

  17. P. Wheatley: The Determination of Molecular Structure (Clarendon, Oxford 1959) Chap. XI

    Google Scholar 

  18. R. Kubo: Rep. Prog. Phys. 29, 255–284 (1966)

    Article  CAS  Google Scholar 

  19. R. Kubo: J. Phys. Soc. Jpn. 12, 570 (1957)

    Article  Google Scholar 

  20. A. K. Jonscher: J. Phys. D Appl. Phys. 32, R57 (1999)

    Article  CAS  Google Scholar 

  21. S. Havriliak, S. Negami: J. Polym. Sci. C 14, 99 (1966)

    Google Scholar 

  22. S. Jr. Havriliak, S. J. Havriliak: Dielectric and Mechanical Relaxation in Materials (Hanser, New York 1997)

    Google Scholar 

  23. L. A. Dissado, R. M. Hill: Proc. R. Soc. London 390(A), 131 (1983)

    CAS  Google Scholar 

  24. L. A. Dissado, R. R. Nigmatullin, R. M. Hill: Dynamical Processes in Condensed Matter. In: Adv. Chem. Phys, Vol. LXIII, ed. by R. Evans M. (Wiley, New York 1985) p. 253

    Chapter  Google Scholar 

  25. M. Abramowitz, I. A. Stegun: Handbook of Mathematical Functions (Dover, New York 1965)

    Google Scholar 

  26. L. A. Dissado, R. M. Hill: Chem. Phys. 111, 193 (1987)

    Article  Google Scholar 

  27. L. A. Dissado, R. M. Hill: Nature (London) 279, 685 (1979)

    Article  CAS  Google Scholar 

  28. G. Williams, D. C. Watt: Trans. Farad. Soc. 66, 80 (1970)

    Article  CAS  Google Scholar 

  29. R. Kohlrausch: Pogg. Ann. Phys. 91, 198 (1854)

    Google Scholar 

  30. A. K. Loidl, J. Knorr, R. Hessinger, I. Fehst, U. T. Hochli: J. Non-Cryst. Solids 269, 131 (1991)

    Google Scholar 

  31. C. Kittel: Introduction to Solid State Physics (Wiley, New York 1966)

    Google Scholar 

  32. J. Joffrin, A. Levelut: J. Phys. (Paris) 36, 811 (1975)

    Google Scholar 

  33. P. C. Hohenberg, B. I. Halperin: Rev. Mod. Phys. 49, 435–479 (1977)

    Article  CAS  Google Scholar 

  34. J. G. Kirkwood: J. Chem. Phys. 7, 911 (1939)

    Article  CAS  Google Scholar 

  35. L. A. Dissado, R. M. Hill: Phil. Mag. B 41, 625–642 (1980)

    Article  CAS  Google Scholar 

  36. L. A. Dissado, M. E. Brown, R. M. Hill: J. Phys. C 16, 4041–4055 (1983)

    Article  CAS  Google Scholar 

  37. L. A. Dissado, R. M. Hill: J. Phys. C 16, 4023–4039 (1983)

    Article  CAS  Google Scholar 

  38. H. A. Kramers: Physica VII(4), 284–304 (1940)

    Article  Google Scholar 

  39. R. F. Grote, J. T. Hynes: J. Chem. Phys. 73, 2715–2732 (1980)

    Article  CAS  Google Scholar 

  40. W. A. Phillips: Proc. R. Soc. London A 319, 535 (1970)

    Google Scholar 

  41. J. le G. Gilchrist: Cryogenics 19, 281 (1979)

    Article  CAS  Google Scholar 

  42. J. le G. Gilchrist: Private communication with R.M. Hill, reported in 10.44, (1978)

    Google Scholar 

  43. H. Eyring: J. Chem. Phys. 4, 283 (1936)

    Article  CAS  Google Scholar 

  44. R. M. Hill, L. A. Dissado: J. Phys. C 15, 5171 (1982)

    Article  CAS  Google Scholar 

  45. S. H. Glarum: J. Chem. Phys. 33, 1371 (1960)

    Article  CAS  Google Scholar 

  46. C. A. Angell: Encyclopedia of Materials. In: Science and Technology, Vol. 4, ed. by K. H. J. Buschow, R. W. Cahn, M. C. Fleming, B. Ilschner, E. J. Kramer, S. Mahajan (Elsevier, New York 2001) pp. 3565–3575

    Google Scholar 

  47. W. Kauzmann: Chem. Rev. 43, 219 (1948)

    Article  CAS  Google Scholar 

  48. G. P. Johari, M. Goldstein: J. Chem. Phys. 53, 2372 (1970)

    Article  CAS  Google Scholar 

  49. M. L. Williams, R. F. Landel, J. D. Ferry: J. Am. Chem. Soc. 77, 3701 (1955)

    Article  CAS  Google Scholar 

  50. M. Goldstein: J. Chem. Phys. 39, 3369 (1963)

    Article  CAS  Google Scholar 

  51. D. Turnbull, M. H. Cohen: J. Chem. Phys. 14, 120 (1961)

    Article  Google Scholar 

  52. R. R. Nigmatullin, S. I. Osokin, G. Smith: J. Phys. Cond. Matter 15, 1 (2003)

    Article  Google Scholar 

  53. R. M. Hill, L. A. Dissado, R. R. Nigmatullin: J. Phys. Cond. Matter 3, 9773 (1991)

    Article  Google Scholar 

  54. M. Shablakh, L. A. Dissado, R. M. Hill: J. Chem. Soc. Faraday Trans. 2 79, 369 (1983)

    Article  CAS  Google Scholar 

  55. R. Pirc, B. Zeks, P. Goshar: Phys. Chem. Solids 27, 1219 (1966)

    Article  CAS  Google Scholar 

  56. K. Pathmanathan, L. A. Dissado, R. M. Hill: Mol. Cryst. Liq. Cryst. 135, 65 (1986)

    Article  CAS  Google Scholar 

  57. K. L. Ngai, A. K. Jonscher, C. T. White: Nature 277, 185 (1979)

    Article  CAS  Google Scholar 

  58. K. L. Ngai, A. K. Rajgopal, S. Tietler: J. Phys. C 17, 6611 (1984)

    Article  Google Scholar 

  59. K. L. Ngai, R. W. Rendell, A. K. Rajgopal, S. Tietler: Ann. Acad. Sci. NY 484, 150 (1986)

    Article  CAS  Google Scholar 

  60. R. G. Palmer, D. Stein, E. S. Abrahams, P. W. Anderson: Phys. Rev. Lett. 53, 958 (1984)

    Article  Google Scholar 

  61. K. Weron: J. Phys. Cond. Matter 4, 10507 (1992)

    Google Scholar 

  62. K. Weron, A. Jurlewicz: J. Phys. A 26, 395 (1993)

    Article  Google Scholar 

  63. E. J. Gumbel: Statistics of Extremes (Columbia University Press, New York 1958)

    Google Scholar 

  64. J. T. Bendler: J. Stat. Phys. 36, 625 (1984)

    Article  Google Scholar 

  65. J. Klafter, M. F. Schlesinger: Proc. Natl. Acad. Sci. 83, 848 (1986)

    Article  CAS  Google Scholar 

  66. D. Stauffer: Introduction to Percolation Theory (Taylor Francis, London 1985)

    Book  Google Scholar 

  67. R. R. Nigmatullin: Theor. Math. Phys. 90, 354 (1992)

    Article  Google Scholar 

  68. R. R. Nigmatullin, A. Le Mehaute: Int. J. Sci. Geores. 8, 2 (2003)

    Google Scholar 

  69. L. A. Dissado, R. M. Hill: J. Appl. Phys. 66, 2511 (1989)

    Article  Google Scholar 

  70. L. A. Dissado, R. M. Hill: J. Chem. Soc. Faraday Trans. 1 80, 325 (1984)

    Article  Google Scholar 

  71. T. Ramdeen, L. A. Dissado, R. M. Hill: J. Chem. Soc. Faraday Trans. 2 80, 325 (1984)

    CAS  Google Scholar 

  72. R. R. Nigmatullin, L. A. Dissado, N. N. Soutougin: J. Phys. D 25, 113 (1992)

    Article  Google Scholar 

  73. A. Puzenko, N. Kozlovich, A. Gutina, Yu. Feldman: Phys. Rev. B 60, 14348 (1999)

    Article  CAS  Google Scholar 

  74. L. A. Dissado: Phys. Med. Biol. 35, 1487 (1990)

    Article  CAS  Google Scholar 

  75. L. A. Dissado, R. M. Hill: Phys. Rev. B 37, 3434 (1988)

    Article  Google Scholar 

  76. D. P. Almond, C. R. Brown: Phys. Rev. Lett. 92, 157601 (2004)

    Article  CAS  Google Scholar 

  77. Yu. Feldman, N. Kozlovich, Yu. Alexandrov, R. Nigmatullin, Ya. Ryabov: Phys. Rev. E 54, 20–28 (1996)

    Article  Google Scholar 

  78. L. A. Dissado, R. M. Hill, C. Pickup, S. H. Zaidi: Appl. Phys. Commun. 5, 13 (1985)

    CAS  Google Scholar 

  79. R. M. Hill, L. A. Dissado, K. Pathmanathan: J. Biol. Phys. 15, 2 (1987)

    Article  Google Scholar 

  80. M. Shablakh, L. A. Dissado, R. M. Hill: J. Biol. Phys. 12, 63 (1984)

    Article  CAS  Google Scholar 

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© 2006 Springer-Verlag

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Dissado, L. (2006). Dielectric Response. In: Kasap, S., Capper, P. (eds) Springer Handbook of Electronic and Photonic Materials. Springer Handbooks. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-29185-7_10

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