Abstract
Molecules are aggregates of two or more nuclei bound by at least one electron. The nuclei of most stable molecules can be imagined to be points in a more or less rigid body whose relative positions are constrained by an electronic bonding potential. This potential depends strongly upon the electronic state as described in Chapt. 31. Most of this discussion is about stable molecules in their electronic ground state. In Sect. 32.6 some comments are made about molecules with excited, or “loose”, parts.
Abbreviations
- CES:
-
constant energy surface
- FTIR:
-
Fourier transform infrared spectroscopy
- NMR:
-
nuclear magnetic resonance systems
- RES:
-
rotational energy surface
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Harter, W. (2006). Molecular Symmetry and Dynamics. In: Drake, G. (eds) Springer Handbook of Atomic, Molecular, and Optical Physics. Springer Handbooks. Springer, New York, NY. https://doi.org/10.1007/978-0-387-26308-3_32
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