Colloids play an essential role in, and are an integral part of, many biogeochemical processes occurring in soils and natural waters and may determine the ultimate fate of environmental contaminants in all natural reservoirs. There is presently no clear definition of the word colloid within the literature. Broadly, colloids are considered as ‘particles’, macromolecules or aggregates having a least diameter in the range of about 0.001–1.0 μm.
Solid, inorganic colloids are dispersed phases, classically referred to as hydrophobic colloids. These colloids generally owe their stability to an electric double layer which causes repulsion between particles if they approach each other. In addition to the hydrophobic colloids, there are also hydrophilic colloids which are hydrated macromolecules whose colloidal properties arise from their large individual size. They are stable in solution either because the electrostatic repulsion of their ionic groups (i.e. −COO− or −NH+ 3or the solvation of...
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Bibliography
Bird, R.P., Stewart, W.E. and Lightfoot, E.N. (1960) Transport Phenomena. New York: Wiley, 780 pp.
Buffle, J. and van Leeuwen, H.P. (ed.) (1992) Environmental Particles, Vol. 1. IUPAC Environmental Analytical and Physical Chemistry Series. Chelsea, MI: Lewis Publishers, 554 pp.
Buffle, J. and van Leeuwen, H.P. (ed.) (1993) Environmental Particles, Vol. 2. IUPAC Environmental Analytical and Physical Chemistry Series. Chelsea, MI: Lewis Publishers, 426 pp.
Everett, D.H. (1972) Definitions, terminology and symbols in colloid and surface chemistry, part I, Pure Appl. Chem., 31, 579–638.
Gregory, J. (1989) Fundamentals of flocculation. CRC Crit. Rev. Environ. Cont., 19, 185–230.
Hirtzel, C.S. and Rajagopalan R. (1985) Colloidal Phenomena. Advanced Topics. Park Ridge: Noyes, 318 pp.
Hochella, M.F. and White, A.F. (eds) (1990) Mineral-Water Interface Geochemistry. Reviews in Mineralogy, Vol. 23. Washington, DC: Mineralogical Society of America, 603 pp.
Ives, K.J. (1978) The Scientific Basis of Flocculation. Alphen aan den Rijn: Sijthoff and Noordhoff., 369 pp.
Lyklema, J. (1991) Fundamentals of Colloid and Interface Science, Vol. I: Fundamentals. London: Academic Press, 612 pp.
Meakin, P. (1988) Fractal aggregates. Adv. Colloid. Interface Sci., 28, 249–331.
Stumm, W. (1992) Chemistry of the Solid-Water Interface. Processes at the Mineral-Water and Particle-Water Interface in Natural Systems. New York: Wiley, 428 pp.
Tanford, C. (1961) Physical Chemistry of Macromolecules. New York: Wiley, 710 pp.
Van de Ven, T.G.M. (1989) Colloidal Hydrodynamics. New York: Academic Press, 582 pp.
Vold, M.J. and Vold, R.D. (1964) Colloid Chemistry. The Science of Large Molecules, Small Particles, and Surfaces. New York: Reinhold, 118 pp.
Cross-references
Rights and permissions
Copyright information
© 1998 Kluwer Academic Publishers
About this entry
Cite this entry
Filella, M., Buffle, J. (1998). Colloids . In: Geochemistry. Encyclopedia of Earth Science. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4496-8_62
Download citation
DOI: https://doi.org/10.1007/1-4020-4496-8_62
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-412-75500-2
Online ISBN: 978-1-4020-4496-0
eBook Packages: Springer Book Archive