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Radiochemical Separations by Thermochromatography

  • Reference work entry
Handbook of Nuclear Chemistry

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1 Introduction

The increasing interest in studying short-lived radionuclides, including transactinide ones, in the early 1960's created a demand for improved or newly created methods allowing fast and highly selective separation of various radioelements.

The analysis of the trends in development of analytical and radiochemical methods showed that the simplest and most effective way to satisfy this demand was through high-temperaturegas chemistry. The already gained experience in using a variety of gas chromatography versions logically led to the choice of thermochromatography (TC), i.e. stationary non-isothermal gas-solid chromatography based on thermal variation of the interaction between the volatile radioactive species (atoms or molecules) and the adsorbent. In this method a negative temperature gradient is produced in the direction of the carrier gas flow or, alternatively, in vacuum. It is, consequently, this temperature gradient, which retards the transport of...

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© 2003 Kluwer Academic Publishers

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(2003). Radiochemical Separations by Thermochromatography. In: Handbook of Nuclear Chemistry. Springer, Boston, MA. https://doi.org/10.1007/0-387-30682-X_46

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  • DOI: https://doi.org/10.1007/0-387-30682-X_46

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4020-1305-8

  • Online ISBN: 978-0-387-30682-7

  • eBook Packages: Springer Book Archive

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