Fluorination

Living Edition
| Editors: Jinbo Hu, Teruo Umemoto

SelectFluor and Its Analogs Fluorination for Preparing Aryl Fluorides

  • Jingyu Hu
  • Jinbo HuEmail author
Living reference work entry
DOI: https://doi.org/10.1007/978-981-10-1855-8_51-1

Introduction

Selectfluor (Fig. 1) is a mild, reliable, effective, and stable source of electrophilic fluorine, which lends itself to large-scale synthesis and is commercially available [ 1]. In 1992, Banks et al. first reported its preparation and application as a competent reagent for the direct synthesis of organofluorides, including aryl fluorides [ 2]. Since then, a variety of aryl fluorides have been synthesized by using Selectfluor as the fluorine source under transition metal-free conditions.
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© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  1. 1.Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular SynthesisShanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of SciencesShanghaiChina