Encyclopedia of Polymeric Nanomaterials

2015 Edition
| Editors: Shiro Kobayashi, Klaus Müllen

Halogenated Polymers

Reference work entry
First Online:
DOI: https://doi.org/10.1007/978-3-642-29648-2_141
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Synonyms

Fluorinated oligomers; Nanocomposites; Silica nanoparticle; Titanium oxide nanoparticle

Definition

Fluoroalkyl end-capped oligomers can form the nanometer size-controlled fluorinated oligomeric aggregates through the aggregation of terminal fluoroalkyl groups, and these fluorinated oligomeric aggregates can interact with silica nanoparticles and titanium oxide nanoparticles to afford the corresponding fluorinated oligomers/silica and titanium oxide nanocomposites, respectively.

Introduction

Fluorinated polymers such as poly(tetrafluoroethylene) can afford extraordinary thermal and oxidative stability due to the bond-strengthening effect of fluorine for C–C and C–F bonds in highly fluorinated compounds, compared to that of the corresponding nonfluorinated materials [1]. This property can afford fluorinated polymers with high thermal and oxidative stability and excellent resistance to most chemicals [1]. Therefore, hybridizations of the fluorinated polymers with metal alkoxides...

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Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  1. 1.Department of Frontier Materials Chemistry, Graduate School of Science and TechnologyHirosaki UniversityHirosakiJapan