Definition
Strontium (Sr) isotopes are widely applied tracers in geoscientific applications. One of the four stable isotopes (87Sr) is subject to long-term radiogenic ingrowth by radioactive decay of rubidium (87Rb). Resultant isotope variations in 87Sr/86Sr, but also other stable isotope variations, can be employed to trace mixing of global reservoirs, ranging from high-temperature-pressure processes preserved in solid rock to low-temperature, environmental conditions in surface waters, oceans, chemical sediments, or biogeochemistry. A second, frequent application is the dating of rock-forming processes using the Rb-Sr decay scheme, ranging in age from the infant stages of the solar system to most recent geologic events.
Introduction to Rb-Sr Systematics
Rb-Sr systematics are based on the radioactive decay of the isotope 87Rb (that today accounts for ~27% of all rubidium) to 87Sr (~9% of all strontium) by beta decay with a half-life of approximately 49 billion years, corresponding to...
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References
Armstrong RL (1968) A model for the evolution of strontium and lead isotopes in a dynamic earth. Rev Geophys 6:175–199
Burke WH et al (1982) Variation of seawater 87Sr/86Sr through Phanerozoic time. Geology 10(10):516–519
Caro G, Bourdon B (2010) Non-chondritic Sm/Nd ratio in the terrestrial planets: consequences for the geochemical evolution of the mantle crust system. Geochim Cosmochim Acta 74(11):3333–3349
Charlier BLA et al (2012) High temperature strontium stable isotope behaviour in the early solar system and planetary bodies. Earth Planet Sci Lett 329:31–40
DePaolo DJ (1981) Trace element and isotopic effects of combined wall rock assimilation and fractional crystallization. Earth Planet Sci Lett 53:189–202
DePaolo DJ, Wasserburg GJ (1977) Sources of island arcs as indicated by Nd and Sr isotopic studies. Geophys Res Lett 4(10):465–468
Fietzke J, Eisenhauer A (2006) Determination of temperature-dependent stable strontium isotope (Sr-88/Sr-86) fractionation via bracketing standard MC-ICP-MS. Geochem Geophys Geosyst 7
Font L, Nowell GM, Pearson DG, Ottley CJ, Willis SG (2007) Sr isotope analysis of bird feathers by TIMS: a tool to trace bird migration paths and breeding sites. J Anal At Spectrom 22(5):513–522
Font L et al (2012) Strontium and lead isotope ratios in human hair: investigating a potential tool for determining recent human geographical movements. J Anal At Spectrom 27(5):719–732
Hans U, Kleine T, Bourdon B (2013) Rb-Sr chronology of volatile depletion in differentiated protoplanets: BABI, ADOR and ALL revisited. Earth Planet Sci Lett 374:204–214
Hofmann AW, White WM (1982) Mantle plumes from ancient oceanic crust. Earth Planet Sci Lett 57:421–436
Jackson MG et al (2007) The return of subducted continental crust in Samoan lavas. Nature 448(7154):684–687
Jacobson AD, Wasserburg GJ (2005) Anhydrite and the Sr isotope evolution of groundwater in a carbonate aquifer. Chem Geol 214(3–4):331–350
Muller W, Fricke H, Halliday AN, McCulloch MT, Wartho JA (2003) Origin and migration of the Alpine Iceman. Science 302(5646):862–866
Nebel O, Mezger K (2008) Timing of thermal stabilization of the Zimbabwe Craton deduced from high-precision Rb-Sr chronology, Great Dyke. Precambrian Res 164(3–4):227–232
Nebel O, Mezger K, van Westrenen W (2011a) Rubidium isotopes in primitive chondrites: constraints on Earth’s volatile element depletion and lead isotope evolution. Earth Planet Sci Lett 305(3–4):309–316
Nebel O, Scherer EE, Mezger K (2011b) Evaluation of the Rb-87 decay constant by age comparison against the U-Pb system. Earth Planet Sci Lett 301(1–2):1–8
Palmer MR, Edmond JM (1989) The strontium isotope budget of the modern ocean. Earth Planet Sci Lett 92:11–26
Price TD, Manzanilla L, Middleton WD (2000) Immigration and the ancient city of Teotihuacan in Mexico: a study using strontium isotope ratios in human bone and teeth. J Archaeol Sci 27(10):903–913
Sobolev AV, Hofmann AW, Jochum KP, Kuzmin DV, Stoll B (2011) A young source for the Hawaiian plume. Nature 476(7361):434–437
Stevenson EI et al (2016) Insights into combined radiogenic and stable strontium isotopes as tracers for weathering processes in subglacial environments. Chem Geol 429:33–43
Veizer J, Compston W (1974) 87Sr/86Sr composition of seawater during the Phanerozoic. Geochim Cosmochim Acta 38(9):1461–1484
Veizer J et al (1999) Sr-87/Sr-86, delta C-13 and delta O-18 evolution of Phanerozoic seawater. Chem Geol 161(1–3):59–88
Vollstaedt H et al (2014) The Phanerozoic delta Sr-88/86 record of seawater: new constraints on past changes in oceanic carbonate fluxes. Geochim Cosmochim Acta 128:249–265
Vroon PZ, van der Wagt B, Koornneef JM, Davies GR (2008) Problems in obtaining precise and accurate Sr isotope analysis from geological materials using laser ablation MC-ICPMS. Anal Bioanal Chem 390(2):465–476
Willigers BJA, Mezger K, Baker J (2004) Development of high precision Rb–Sr phlogopite and biotite geochronology; an alternative to 40Ar/39Ar tri-octahedral mica dating. Chem Geol 213(4):339–358
Zack T, Hogmalm KJ (2016) Laser ablation Rb/Sr dating by online chemical separation of Rb and Sr in an oxygen-filled reaction cell. Chem Geol 437:120–133
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Nebel, O., Stammeier, J.A. (2018). Strontium Isotopes. In: White, W.M. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39312-4_137
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