Encyclopedia of Geochemistry

Living Edition
| Editors: William M. White

Phosphorus

  • Karl B. Föllmi
Living reference work entry
DOI: https://doi.org/10.1007/978-3-319-39193-9_189-1

Element Data

  • Atomic Symbol: P

  • Atomic Number: 15

  • Atomic Weight: 30.97 g/mol

  • Isotopes and Abundances: 31P (stable, 100%), radioactive isotopes from 24P to 46P, with 32P (short-lived; half-life = 14.3 days) and 33P (short-lived; half-life = 25.4 days) being the longest-lived ones

  • 1 Atm Melting Point: 44.1 °C

  • 1 Atm Boiling Point: 280 °C

  • Common Valences: +5, +3, +2, +1, −2, −3

  • Ionic Radii: 2.12 Å (−3) and 0.29 Å (+5)

  • Pauling Electronegativity: 2.19

  • First Ionization Energy: 1012 kJ/mol

  • Chondritic (CI) Abundance: 926 ppm

  • Silicate Earth Abundance: 90 ppm

  • Crustal Abundance: 1120 ppm

  • Seawater Abundance: 0.06 ppm

  • Core Abundance: 2000 ppm

Properties, Origin, and Behavior

Elemental phosphorus is known in four allotropic varieties – white or yellow, red, violet, and black P, with different specific densities (1.82 g/cm3, 2.34 g/cm3, 2.36 g/cm3, and 2.69 g/cm3, respectively). Elemental phosphorus is highly reactive in the presence of oxygen, ignites and starts to luminescence (“phosphorescence”:...

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References

  1. Berner RA, Ruttenberg KC, Ingall ED, Rao JL (1993) The nature of phosphorus burial in modern marine sediments. In: Wollast R, Mackenzie FT, Chou L (eds) Interactions of C, N, P and S biochemical cycles and global change, NATO ASI series, vol 14. Springer, Berlin, pp 365–378CrossRefGoogle Scholar
  2. Childers DL, Corman J, Edwards M, Elser JJ (2011) Sustainability challenges of phosphorus and food: solutions from closing the human phosphorus cycle. Bioscience 61:117–124CrossRefGoogle Scholar
  3. Cook PJ, McElhinny MW (1979) A re-evaluation of the spatial and temporal distribution of sedimentary phosphate deposits in the light of plate tectonics. Econ Geol 74:315–330CrossRefGoogle Scholar
  4. Diaz RJ, Rosenberg R (2008) Spreading dead zones and consequences for marine ecosystems. Science 321:926–928CrossRefGoogle Scholar
  5. Filippelli GM (2008) The global phosphorus cycle: past, present, and future. Elements 4:89–95CrossRefGoogle Scholar
  6. Föllmi KB (1996) The phosphorus cycle, phosphogenesis and marine phosphate-rich deposits. Earth-Sci Rev 40:55–124CrossRefGoogle Scholar
  7. Föllmi KB (2011) Phosphorus, phosphorites. In: Reitner J, Thiel V (eds) Encyclopedia of geobiology, Encyclopedia of earth sciences series, vol 15. Springer, Berlin, pp 732–736CrossRefGoogle Scholar
  8. Harrison JA, Seitzinger SP, Bouwman AF, Caraco NF, Beusen AHW, Vörösmarty CJ (2005) Dissolved inorganic phosphorus export to the coastal zone: results from a spatially explicit, global model. Glob Biogeochem Cycles 19, GB4S03Google Scholar
  9. Jarvis I., Burnett WC, Nathan Y et al (1994) Phosphorite geochemistry- state-of-the-arts and environmental concerns. In: Föllmi KB (ed) Concepts and controversies in phosphogenesis, Eclogae geologicae Helvetiae, vol 87. Birkhäuser Verlag, Basel, pp 643–700Google Scholar
  10. Koo BC, Lee YH, Moon DS, Yoon SC, Raymond JC (2013) Phosphorus in the young supernova remnant Cassiopeia a. Science 342:1346–1348CrossRefGoogle Scholar
  11. Pufahl PK, Groat LA (2017) Sedimentary and igneous phosphate deposits: formation and exploration: an invited paper. Econ Geol 112:483–516CrossRefGoogle Scholar
  12. Redfield AC (1958) The biological control of chemical factors in the environment. Am Scient 46:205–221Google Scholar
  13. Toplis MJ, Libourel G, Carroll MR (1994) The role of phosphorus in crystallization processes of basalt: an experimental study. Geochim Cosmochim Acta 58:797–810CrossRefGoogle Scholar
  14. Tyrrell T (1999) The relative influences of nitrogen and phosphorus on oceanic primary productivity. Nature 400:525–531CrossRefGoogle Scholar
  15. USGS (2016) USGS mineral commodity summaries: phosphate rock. https://minerals.usgs.gov/minerals/pubs/commodity/phosphate_rock/mcs-2016-phosp.pdf
  16. Wolf D, Palme H (2001) The solar system abundances of phosphorus and the nebular volatility of phosphorus. Meteor Planet Sci 36:559–571CrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG 2017

Authors and Affiliations

  1. 1.Institute of Earth SciencesUniversity of LausanneLausanneSwitzerland