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High-Frequency Dynamic Nuclear Polarization NMR for Solids: Part 1 – An Introduction

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Modern Magnetic Resonance

Abstract

Dynamic nuclear polarization (DNP) NMR spectroscopy, a high-polarization method, is rapidly changing the landscape of what is possible in solid-state nuclear magnetic resonance spectroscopy. To date, there have been over 200 publications discussing high-frequency DNP NMR of solids with more than half being released within the past few years. Below we provide for researchers that may be interested in this high-sensitivity technique an introduction to high-frequency DNP NMR spectroscopy, including instrumentation, mechanisms, polarizing agents, and sample preparation. While there are many applications utilizing high-frequency DNP NMR, Part II will deal with recent advances in method development and applications to biomolecular solids and materials science.

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Acknowledgments

VKM acknowledges the Natural Sciences and Engineering Research Council of Canada (NSERC) Discovery Grants program and the University of Alberta for funding. MH is partially supported by the Government of Alberta Queen Elizabeth II Graduate Scholarship.

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  1. Department of Chemistry, University of Alberta, Edmonton, T6G 2G2, Alberta, Canada

    Michelle Ha & Vladimir K. Michaelis

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  1. Michelle Ha
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Correspondence to Vladimir K. Michaelis .

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  1. Royal Society of Chemistry, London, United Kingdom

    Graham A. Webb

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Ha, M., Michaelis, V.K. (2017). High-Frequency Dynamic Nuclear Polarization NMR for Solids: Part 1 – An Introduction. In: Webb, G. (eds) Modern Magnetic Resonance. Springer, Cham. https://doi.org/10.1007/978-3-319-28275-6_140-1

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