Nano-functionalized Polycarbonate Coatings for Heat Sink Applications
Abstract
Thermoplastic/thermosetting polymer composites are a category of advanced functional materials having competency to replace many conventional materials due to its lightweight and excellent heat sinking capacity for automotive, aviation, and defense. The heat transfer and dissipation mechanism are basics considered for developing new material with improved heat insulation capacity. Polycarbonate composite comprising nanofiller/-fiber reinforcements fabricated with advanced technique inherits properties such as good mechanical properties, thermal stability, optical clarity, etc. required for thermal insulation. In this chapter, polycarbonate nanocomposites were fabricated though three different methods, i.e., solvent casting, spray coating, and melt mixing with three different reinforced fillers cenosphere, fumed silica (FS), and POSS. Functionalization, effectiveness in surface treatment, changes in surface morphology, and insulation characteristics of composite were affirmed through varied surface, morphology, and thermal characterization tools. Thermal conductivity of composites was also computed theoretically, and steady heat transfer simulation had been carried out to analyze the results numerically using ABAQUS CAE tool. To extend the application field of polycarbonate composites, water contact angle had been measured to check hydrophobic or hydrophilic nature of composites. Finally, the chapter concludes with detailed comparative study of polycarbonate nanocomposites with fillers fabricated by three different techniques with an application in car battery casing. Results displayed enhanced properties of polycarbonate nanocomposites which have a competency to replace the conventional materials used for insulative purpose.
Keywords
High-temperature polymers Heat sink Polycarbonate Nano-fumed silica Polymeric coatings NanomaterialsReferences
- Abbasi S, Carreau PJ, Derdouri A (2010) Flow induced orientation of multiwalled carbon nanotubes in polycarbonate nanocomposites: rheology, conductivity and mechanical properties. Polymer 51:922–935CrossRefGoogle Scholar
- Agrawal A, Satapathy A (2015) Computational, analytical and experimental investigation of heat conduction of particulate filled polymer composite. Universal J Mech Eng 3:1–6CrossRefGoogle Scholar
- Akonda MH, Lawrence CA, Weager BM (2012) Recycled carbon fibre-reinforced polypropylene thermoplastic composites. Compos A: Appl Sci Manuf 43:79–86CrossRefGoogle Scholar
- Armster SQ, Delplanque J-P, Rein M, Lavernia EJ (2002) Thermo–fluid mechanisms controlling droplet based materials processes. Int Mater Rev 47:265–301CrossRefGoogle Scholar
- Ashish J, Swaroop G, Balasubramanian K (2019) Effect of ammonium perchlorate particle size on flow, ballistic, and mechanical properties of composite propellant. In: Yan Q-L, He G-Q, Liu P-J, Gozin M (eds) Nanomaterials in rocket propulsion systems. Elsevier, Amsterdam, pp 299–362CrossRefGoogle Scholar
- Badhe Y, Balasubramanian K (2014) Reticulated three-dimensional network ablative composites for heat shields in thermal protection systems. RSC Adv 4:43708–43719CrossRefGoogle Scholar
- Badhe Y, Balasubramanian K, Gupta R (2015) Cost-effective, low density, carbon soot doped resorcinol formaldehyde composite for ablative applications. RSC Adv 5:23622–23634CrossRefGoogle Scholar
- Baglari S, Kole M, Dey TK (2011) Effective thermal conductivity and coefficient of linear thermal expansion of high-density polyethylene—fly ash composites. Indian J Phys 85:559–573CrossRefGoogle Scholar
- Balasubramanian K (2012) Reinforcement of poly ether sulphones (PES) with exfoliated graphene oxide for aerospace applications. IOP Conf Ser Mater Sci Eng 40:012022CrossRefGoogle Scholar
- Balasubramanian K, Tirumalai M (2013) High temperature polymer nanocomposites. In: Njuguna J (ed) Structural nanocomposites. Springer, Berlin/Heidelberg, pp 165–186CrossRefGoogle Scholar
- Balasubramanian K, Tirumali M, Badhe Y, Mahajan YR (2017) Nano-enabled multifunctional materials for aerospace applications. In: Prasad NE, Wanhill RJH (eds) Aerospace materials and material technologies. Springer, Singapore, pp 439–453CrossRefGoogle Scholar
- Banerjee BS, Balasubramanian K (2015) Nanotexturing of PC/n-HA nanocomposites by innovative and advanced spray system. RSC Adv 5:13653–13659CrossRefGoogle Scholar
- Banerjee BS, Khaira SS, Balasubramanian K (2014) Thin film encapsulation of nano composites of polycarbonate (PC) for thermal management systems. RSC Adv 4:63380–63386CrossRefGoogle Scholar
- Bartuli C, Lusvarghi L, Manfredini T, Valente T (2007) Thermal spraying to coat traditional ceramic substrates: case studies. J Eur Ceram Soc 27:1615–1622CrossRefGoogle Scholar
- Batt RG, Legner HH (1983) A review of roughness-induced Nosetip transition. AIAA J 21:7–22CrossRefGoogle Scholar
- Cai HL, Xu K, Liu H, Liu X, Fu ZE, Chen MC (2011) Influence of polyhedral oligomeric silsesquioxanes on thermal and mechanical properties of polycarbonate/POSS hybrid composites. Polym Compos 32:1343–1351CrossRefGoogle Scholar
- Cao XQ, Vassen R, Stoever D (2004) Ceramic materials for thermal barrier coatings. J Eur Ceram Soc 24:1–10CrossRefGoogle Scholar
- Chen Y, Zhan J, Zhang P, Nie S, Lu H, Song L, Hu Y (2010) Preparation of intumescent flame retardant Poly(butylene succinate) using Fumed silica as synergistic agent. Ind Eng Chem Res 49:8200–8208CrossRefGoogle Scholar
- Chrissafis K, Paraskevopoulos KM, Pavlidou E, Bikiaris D (2009a) Thermal degradation mechanism of HDPE nanocomposites containing fumed silica nanoparticles. Thermochim Acta 485:65–71CrossRefGoogle Scholar
- Chrissafis K, Paraskevopoulos KM, Tsiaoussis I, Bikiaris D (2009b) Comparative study of the effect of different nanoparticles on the mechanical properties, permeability, and thermal degradation mechanism of HDPE. J Appl Polym Sci 114:1606–1618CrossRefGoogle Scholar
- Daniel A, Badhe Y, Srikanth I, Gokhale S, Balasubramanian K (2016) Laser shielding and thermal ablation characteristics of resorcinol formaldehyde/boron nitride composites for thermal protection systems. Ind Eng Chem Res 55:10645–10655CrossRefGoogle Scholar
- Daniel A, Ivaturi S, Kumar A, Kandasubramanian B (2019) Development and characterization of a contoured passive thermal protection system. Int J Appl Ceram Technol 16:170–184CrossRefGoogle Scholar
- Das TK, Prusty S (2013) Graphene-based polymer composites and their applications. Polym-Plast Technol Eng 52:319–331CrossRefGoogle Scholar
- Das A, Satapathy BK (2011) Structural, thermal, mechanical and dynamic mechanical properties of cenosphere filled polypropylene composites. Mater Des 32:1477–1484CrossRefGoogle Scholar
- Dawson DM, Briggs A (1981) Prediction of the thermal conductivity of insulation materials. J Mater Sci 16:3346–3356CrossRefGoogle Scholar
- Deepthi MV, Sharma M, Sailaja RRN, Anantha P, Sampathkumaran P, Seetharamu S (2010) Mechanical and thermal characteristics of high density polyethylene–fly ash Cenospheres composites. Mater Des 31:2051–2060CrossRefGoogle Scholar
- Doyle CD (1961) Estimating thermal stability of experimental polymers by empirical thermogravimetric analysis. Anal Chem 33:77–79CrossRefGoogle Scholar
- Eklund PC, Holden JM, Jishi RA (1995) Vibrational modes of carbon nanotubes; spectroscopy and theory. Carbon 33:959–972CrossRefGoogle Scholar
- Ettlinger M, Ladwig T, Weise A (2000) Surface modified fumed silicas for modern coatings. Prog Org Coat 40:31–34CrossRefGoogle Scholar
- Favis BD, Therrien D (1991) Factors influencing structure formation and phase size in an immiscible polymer blend of polycarbonate and polypropylene prepared by twin-screw extrusion. Polymer 32:1474–1481CrossRefGoogle Scholar
- Feng J, Hao J, Du J, Yang R (2010) Flame retardancy and thermal properties of solid bisphenol A bis(diphenyl phosphate) combined with montmorillonite in polycarbonate. Polym Degrad Stab 95:2041–2048CrossRefGoogle Scholar
- Feng Y, Wang B, Wang F, Zhao Y, Liu C, Chen J, Shen C (2014) Thermal degradation mechanism and kinetics of polycarbonate/silica nanocomposites. Polym Degrad Stab 107:129–138CrossRefGoogle Scholar
- Fomenko EV, Anshits NN, Pankova MV, Solovyov LA, Anshits AG (2011) Fly ash cenospheres: Composition, morphology, structure, and helium permeability. In: World Coal Ash Conf.–May: 9–12, http://www.flyash.info/AshSymposium/AshLibraryAgenda.asp
- Fu BX, Hsiao BS, White H, Rafailovich M, Mather PT, Jeon HG, Phillips S, Lichtenhan J, Schwab J (2000) Nanoscale reinforcement of polyhedral oligomeric silsesquioxane (POSS) in polyurethane elastomer. Polym Int 49:437–440CrossRefGoogle Scholar
- Galvez A, Herlin-Boime N, Reynaud C, Clinard C, Rouzaud J-N (2002) Carbon nanoparticles from laser pyrolysis. Carbon 40:2775–2789CrossRefGoogle Scholar
- Gedler G, Antunes M, Realinho V, Velasco JI (2012) Thermal stability of polycarbonate-graphene nanocomposite foams. Polym Degrad Stab 97:1297–1304CrossRefGoogle Scholar
- Goffreda F, Griff A, Livinghouse L, Walsh T, Scuralli J (1998) Tool and Manufacturing Engineers Handbook Knowledge Base. Society of Manufacturing EngineersGoogle Scholar
- Gonte RR, Shelar G, Balasubramanian K (2014) Polymer–agro-waste composites for removal of Congo red dye from wastewater: adsorption isotherms and kinetics. Desalin Water Treat 52:7797–7811CrossRefGoogle Scholar
- Gore PM, Kandasubramanian B (2018a) Functionalized aramid fibers and composites for protective applications: a review. Ind Eng Chem Res 57:16537–16563CrossRefGoogle Scholar
- Gore PM, Kandasubramanian B (2018b) Heterogeneous wettable cotton based superhydrophobic Janus biofabric engineered with PLA/functionalized-organoclay microfibers for efficient oil–water separation. J Mater Chem A 6:7457–7479CrossRefGoogle Scholar
- Gore PM, Zachariah S, Gupta P, Kandasubramanian B (2016) Multifunctional nano-engineered and bio-mimicking smart superhydrophobic reticulated ABS/fumed silica composite thin films with heat-sinking applications. RSC Adv 6:105180–105191CrossRefGoogle Scholar
- Gore PM, Purushothaman A, Naebe M, Wang X, Kandasubramanian B (2019) Nanotechnology for oil-water separation. In: Prasad R, Karchiyappan T (eds) Advanced research in nanosciences for water technology. Springer International Publishing, Cham, pp 299–339CrossRefGoogle Scholar
- Gun’ko VM, Voronin EF, Pakhlov EM, Zarko VI, Turov VV, Guzenko NV, Leboda R, Chibowski E (2000) Features of fumed silica coverage with silanes having three or two groups reacting with the surface. Colloids Surf A Physicochem Eng Asp 166:187–201CrossRefGoogle Scholar
- Gupta P, Balasubramanian K (2016) Numerical investigation of heat loss in Nano-Fumed silica reinforced styrene acrylonitrile hydrophobic Thermo-sheath for heat inhibition in hydronic boiler. Mater Focus 5:556–564CrossRefGoogle Scholar
- Haddad TS, Lichtenhan JD (1996) Hybrid organic−inorganic thermoplastics: styryl-based polyhedral oligomeric Silsesquioxane polymers. Macromolecules 29:7302–7304CrossRefGoogle Scholar
- Hakimelahi HR, Hu L, Rupp BB, Coleman MR (2010) Synthesis and characterization of transparent alumina reinforced polycarbonate nanocomposite. Polymer 51:2494–2502CrossRefGoogle Scholar
- Han Z, Fina A (2011) Thermal conductivity of carbon nanotubes and their polymer nanocomposites: a review. Prog Polym Sci 36:914–944CrossRefGoogle Scholar
- Hany R, Hartmann R, Böhlen C, Brandenberger S, Kawada J, Löwe C, Zinn M, Witholt B, Marchessault RH (2005) Chemical synthesis and characterization of POSS-functionalized poly[3-hydroxyalkanoates]. Polymer 46:5025–5031CrossRefGoogle Scholar
- Hao N, Böhning M, Schönhals A (2007) Dielectric properties of nanocomposites based on polystyrene and polyhedral oligomeric Phenethyl-Silsesquioxanes. Macromolecules 40:9672–9679CrossRefGoogle Scholar
- Ho CJ, Chen WC (2013) An experimental study on thermal performance of Al2O3/water nanofluid in a minichannel heat sink. Appl Therm Eng 50:516–522CrossRefGoogle Scholar
- Hofmann D, Keinath M, Thomann R, Mülhaupt R (2014) Thermoplastic carbon/polyamide 12 composites containing functionalized graphene, expanded graphite, and carbon nanofillers: thermoplastic carbon/polyamide 12 composites containing functionalized graphene…. Macromol Mater Eng 299:1329–1342CrossRefGoogle Scholar
- Hornbostel B, Pötschke P, Kotz J, Roth S (2006) Single-walled carbon nanotubes/polycarbonate composites: basic electrical and mechanical properties. Phys Status Solidi (b) 243:3445–3451CrossRefGoogle Scholar
- Hussain CM (2018) Handbook of nanomaterials for industrial applications. Elsevier, AmsterdamGoogle Scholar
- Hussain CM, Mishra AK (2018) New polymer nanocomposites for environmental remediation. Elsevier, AmsterdamGoogle Scholar
- Irvine D, Foreman E, Remington CB, Jackson A, Endrizzi S (2015) Designing a heat sink for Lithium-ion battery packs in electric vehicles. US: University of AkronGoogle Scholar
- Ismail KN, Hussin K, Idris MS (2007) Physical, chemical & mineralogical properties of fly ash. Journal of Nuclear and Related Technology 4:47–51Google Scholar
- Jain S, Gupta G, Kshirsagar DR, Khire VH, Kandasubramanian B (2018) Burning rate and other characteristics of strontium titanate (SrTiO3) supplemented AP/HTPB/Al composite propellants. Def Technol. https://doi.org/10.1016/j.dt.2018.10.004CrossRefGoogle Scholar
- Jindal P, Goyal M, Kumar N (2014) Mechanical characterization of multiwalled carbon nanotubes-polycarbonate composites. Mater Des. (1980-2015) 54:864–868CrossRefGoogle Scholar
- Kang H-J, Meesiri W, Blum FD (1990) Nuclear magnetic resonance studies of the hydrolysis and molecular motion of aminopropylsilane. Mater Sci Eng A 126:265–270CrossRefGoogle Scholar
- Karasek L, Sumita M, (1996) Characterization of dispersion state of filler and polymer-filler interactions in rubber-carbon black composites. J Mater Sci 31:281–289. https://doi.org/10.1007/BF01139141
- Kashiwagi T, Du F, Douglas JF, Winey KI, Harris RH, Shields JR (2005) Nanoparticle networks reduce the flammability of polymer nanocomposites. Nat Mater 4:928–933CrossRefGoogle Scholar
- Katiyar N, Balasubramanian K (2014) Thermal modelling of hybrid composites of nano cenosphere and polycarbonate for a thermal protection system. RSC Adv 4:47529–47535CrossRefGoogle Scholar
- Katiyar N, Balasubramanian K (2015) Nano-heat-sink thin film composite of PC/three-dimensional networked nano-fumed silica with exquisite hydrophobicity. RSC Adv 5:4376–4384CrossRefGoogle Scholar
- Kolay PK, Singh DN (2001) Physical, chemical, mineralogical, and thermal properties of cenospheres from an ash lagoon. Cem Concr Res 31:539–542CrossRefGoogle Scholar
- Kumar V, Balasubramanian K (2016) Progress update on failure mechanisms of advanced thermal barrier coatings: a review. Prog Org Coat 90:54–82CrossRefGoogle Scholar
- Kumar V, Kandasubramanian B (2016) Processing and design methodologies for advanced and novel thermal barrier coatings for engineering applications. Particuology 27:1–28CrossRefGoogle Scholar
- Lee ES, Kim JS, Kim KY, Lim DY, Kim DH (2014) Preparation of polypropylene composites reinforced with long carbon fibers and their properties. Fibers Polym 15:2613–2617CrossRefGoogle Scholar
- Leng Y, Liu J, Zhang C, Jiang P (2014) A polyhedral oligomeric silsesquioxane (POSS)-bridged oxo-molybdenum Schiff base complex with enhanced heterogeneous catalytic activity in epoxidation. Cat Sci Technol 4:997–1004CrossRefGoogle Scholar
- Li G, Wang L, Ni H, Pittman CU Jr (2001) Polyhedral oligomeric Silsesquioxane (POSS) polymers and copolymers: a review. J Inorg Organomet Polym 11:123–154CrossRefGoogle Scholar
- Li GZ, Wang L, Toghiani H, Daulton TL, Pittman CU (2002) Viscoelastic and mechanical properties of vinyl ester (VE)/multifunctional polyhedral oligomeric silsesquioxane (POSS) nanocomposites and multifunctional POSS–styrene copolymers. Polymer 43:4167–4176CrossRefGoogle Scholar
- Li ZQ, Lu CJ, Xia ZP, Zhou Y, Luo Z (2007) X-ray diffraction patterns of graphite and turbostratic carbon. Carbon 45:1686–1695CrossRefGoogle Scholar
- Lin-Vien D, Colthup NB, Fateley WG, Grasselli JG (1991) The handbook of infrared and Raman characteristics frequency of organic molecules. AcademicGoogle Scholar
- Ma P-C, Siddiqui NA, Marom G, Kim J-K (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos A: Appl Sci Manuf 41:1345–1367CrossRefGoogle Scholar
- Magisetty R, Kumar P, Gore PM, Ganivada M, Shukla A, Kandasubramanian B, Shunmugam R (2019) Electronic properties of Poly(1,6-heptadiynes) electrospun fibrous non-woven mat. Mater Chem Phys 223:343–352CrossRefGoogle Scholar
- Mishra P, Balasubramanian K (2014) Nanostructured microporous polymer composite imprinted with superhydrophobic camphor soot, for emphatic oil–water separation. RSC Adv 4:53291–53296CrossRefGoogle Scholar
- Moon SC, Kim JY, Oh BT (2014) Mechanical and flame resistant properties of polycarbonate-carbon nanotubes-ochre composites. Polym Eng Sci 54:1289–1299CrossRefGoogle Scholar
- Nakagaito AN, Yano H (2005) Novel high-strength biocomposites based on microfibrillated cellulose having nano-order-unit web-like network structure. Appl Phys A 80:155–159CrossRefGoogle Scholar
- Olmos D, Martínez F, González-Gaitano G, González-Benito J (2011) Effect of the presence of silica nanoparticles in the coefficient of thermal expansion of LDPE. Eur Polym J 47:1495–1502CrossRefGoogle Scholar
- Panwar SS, Patro TU, Balasubramanian K, Venkataraman B (2016) High-temperature stability of yttria-stabilized zirconia thermal barrier coating on niobium alloy—C-103. Bull Mater Sci 39:321–329CrossRefGoogle Scholar
- Parvaiz MR, Mahanwar PA, Mohanty S, Nayak SK (2010) Morphological, mechanical, thermal, electrical and rheological properties of polycarbonate composites reinforced with surfaces modified Mica. J Miner Mater Charact Eng 09:985–996Google Scholar
- Periyasamy T, Asrafali SP, Muthusamy S (2015) New benzoxazines containing polyhedral oligomeric silsesquioxane from eugenol, guaiacol and vanillin. New J Chem 39:1691–1702CrossRefGoogle Scholar
- Phillips SH, Haddad TS, Tomczak SJ (2004) Developments in nanoscience: polyhedral oligomeric silsesquioxane (POSS)-polymers. Curr Opinion Solid State Mater Sci 8:21–29CrossRefGoogle Scholar
- Poręba R, Spírková M, Hrdlicka Z (2011) Mechanical and thermomechanical properties of polycarbonate-based polyurethane-silica nanocomposites. Process Appl Ceram 5:155–159CrossRefGoogle Scholar
- Prasad A, Kandasubramanian B (2019) Fused deposition processing polycaprolactone of composites for biomedical applications. Polym-Plast Technol Mater 58(13):1365–98CrossRefGoogle Scholar
- Puri RG, Khanna AS (2016) Effect of cenospheres on the char formation and fire protective performance of water-based intumescent coatings on structural steel. Prog Org Coat 92:8–15CrossRefGoogle Scholar
- Raask E (1968) Cenospheres in pulverized-fuel ash. J Inst Fuel 41:339Google Scholar
- Raask E (1969) Fusion of silicate particles in coal flames. Fuel 48:366Google Scholar
- Ramdayal BK (2014) Antibacterial application of polyvinylalcohol-nanogold composite membranes. Colloids Surf A Physicochem Eng Asp 455:174–178CrossRefGoogle Scholar
- Reda DC (1981) Correlation of Nosetip boundary-layer transition data measured in ballistics-range experiments. AIAA J 19:329–339CrossRefGoogle Scholar
- Sánchez-Soto M, Schiraldi DA, Illescas S (2009) Study of the morphology and properties of melt-mixed polycarbonate–POSS nanocomposites. Eur Polym J 45:341–352CrossRefGoogle Scholar
- Sanoj P, Kandasubramanian B (2014) Hybrid carbon-carbon ablative composites for thermal protection in aerospace. J Compos 2014:1–15CrossRefGoogle Scholar
- Sengupta R, Bhattacharya M, Bandyopadhyay S, Bhowmick AK (2011) A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites. Prog Polym Sci 36:638–670CrossRefGoogle Scholar
- Sinha Ray S, Okamoto M (2003) Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog Polym Sci 28:1539–1641CrossRefGoogle Scholar
- Song L, He Q, Hu Y, Chen H, Liu L (2008) Study on thermal degradation and combustion behaviors of PC/POSS hybrids. Polym Degrad Stab 93:627–639CrossRefGoogle Scholar
- Striolo A, McCabe C, Cummings PT (2005) Thermodynamic and transport properties of polyhedral oligomeric Silsesquioxanes in Poly(dimethylsiloxane). J Phys Chem B 109:14300–14307CrossRefGoogle Scholar
- Suryanegara L, Nakagaito AN, Yano H (2009) The effect of crystallization of PLA on the thermal and mechanical properties of microfibrillated cellulose-reinforced PLA composites. Compos Sci Technol 69:1187–1192CrossRefGoogle Scholar
- Suryanegara L, Okumura H, Nakagaito AN, Yano H (2011) The synergetic effect of phenylphosphonic acid zinc and microfibrillated cellulose on the injection molding cycle time of PLA composites. Cellulose 18:689–698CrossRefGoogle Scholar
- Sweileh BA, Al-Hiari YM, Kailani MH, Mohammad HA (2010) Synthesis and characterization of polycarbonates by melt phase interchange reactions of Alkylene and Arylene diacetates with Alkylene and Arylene Diphenyl Dicarbonates. Molecules 15:3661–3682CrossRefGoogle Scholar
- Tenjimbayashi M, Shiratori S (2014) Highly durable superhydrophobic coatings with gradient density by movable spray method. J Appl Phys 116:114310CrossRefGoogle Scholar
- Tirumali M, Balasubramanian K, Kumaraswamy A (2017) Functionally layered graphite reinforced epoxy composite sandwiched between epoxy composites: their electrical and flexural properties. Mater Focus 6:691–697CrossRefGoogle Scholar
- Tirumali M, Kandasubramanian B, Kumaraswamy A, Subramani NK, Suresha B (2018) Fabrication, physicochemical characterizations and electrical conductivity studies of modified carbon nanofiber-reinforced epoxy composites: effect of 1-Butyl-3-Methylimidazolium Tetrafluoroborate ionic liquid. Polym-Plast Technol Eng 57:218–228CrossRefGoogle Scholar
- Tong Z, Liu M, Bao H (2016) A numerical investigation on the heat conduction in high filler loading particulate composites. Int J Heat Mass Transf 100:355–361CrossRefGoogle Scholar
- Varadarajan S, Pattanaik AK, Sarin VK (2001) Mullite interfacial coatings for SiC fibers. Surf Coat Technol 139:153–160CrossRefGoogle Scholar
- Wang C, Wang D, Zheng S (2013) Preparation of aluminum silicate/fly ash particles composite and its application in filling polyamide 6. Mater Lett 111:208–210CrossRefGoogle Scholar
- Xu J, Song J (2010) High performance shape memory polymer networks based on rigid nanoparticle cores. Proc Natl Acad Sci 107:7652–7657CrossRefGoogle Scholar
- Yadav R, Zachariah S, Balasubramanian K (2016) Thermally stable transparent hydrophobic bio-mimetic dual scale Spherulites coating by spray deposition. Adv Sci Eng Med 8:181–187CrossRefGoogle Scholar
- Yadav R, Naebe M, Wang X, Kandasubramanian B (2017) Structural and thermal stability of polycarbonate decorated fumed silica nanocomposite via thermomechanical analysis and in-situ temperature assisted SAXS. Sci Rep. https://doi.org/10.1038/s41598-017-08122-7
- Yadav R, Naebe M, Wang X, Kandasubramanian B (2019) Thermomechanical characteristics of h-BN- and POSS-based bisphenol A polycarbonate nanocomposites. Polymer-Plastics Technology and Materials 1–15 https://doi.org/10.1080/25740881.2018.1563143CrossRefGoogle Scholar
- Ye Y-S, Chen W-Y, Wang Y-Z (2006) Synthesis and properties of low-dielectric-constant polyimides with introduced reactive fluorine polyhedral oligomeric silsesquioxanes. J Polym Sci A Polym Chem 44:5391–5402CrossRefGoogle Scholar
- Yoon KH, Polk MB, Park JH, Min BG, Schiraldi DA (2005) Properties of poly(ethylene terephthalate) containing epoxy-functionalized polyhedral oligomeric silsesquioxane. Polym Int 54:47–53CrossRefGoogle Scholar
- Zheng L, Farris RJ, Coughlin EB (2001) Synthesis of polyethylene hybrid copolymers containing polyhedral oligomeric silsesquioxane prepared with ring-opening metathesis copolymerization. J Polym Sci A Polym Chem 39:2920–2928CrossRefGoogle Scholar
- Zheng L, Hong S, Cardoen G, Burgaz E, Gido SP, Coughlin EB (2004) Polymer nanocomposites through controlled self-assembly of cubic Silsesquioxane scaffolds. Macromolecules 37:8606–8611CrossRefGoogle Scholar
- Zou H, Wu S, Shen J (2008) Polymer/silica nanocomposites: preparation, characterization, properties, and applications. Chem Rev 108:3893–3957CrossRefGoogle Scholar