Fundamentals of Diffusion in Microfluidic Systems
Synonyms
Self-diffusion
Definition
Brownian motion is defined as the irregular motion of microscopic particles suspended in a fluid due to collisions with the surrounding fluid molecules. The mean square displacement of a particle executing Brownian motion is directly proportional to the temperature of the fluid and inversely proportional to the viscosity of the fluid and the diameter of the particle.
Chemical and Physical Principles
In the latter half of the nineteenth century and the beginning of the twentieth century, Brownian motion played an important role in the debate about the molecular reality of nature. The random movement of microscopic particles suspended in a liquid is named after the botanist Robert Brown, who discovered this phenomenon while observing pollen grain suspended in water. Though Brown himself states that this motion was observed by other researchers before him such as Leeuwenhoek (1632–1723), Buffon (1800s), Spallanzani (1800s), and Bywater (1819), he is...
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