Synonyms
Electron paramagnetic resonance (EPR) dating
Introduction
Electron spin resonance (ESR) dating is a chronometric dating method, but depending on the author, it may also be classified as a radiation exposure, a trapped charge, a paleodosimetric, or a radiometric method. Like other methods that use luminescence phenomena, ESR is based on an evaluation of the exposure of some materials to natural radioactivity. This expsoure is expressed as an absorbed radiation dose, which corresponds to the energy deposited in the matter by ionizing radiation. Such materials can acquire or develop a paramagnetic behavior under the effect of natural radioactivity, which can be later detected and quantified by means of ESR spectroscopy.
Use of this technique for dating purposes was first suggested by Ikeya (1975) based on the study of stalactites from caves in Japan. Since then, numerous applications to a wide range of materials have been to varying degrees successfully attempted (see the...
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Bibliography
Aitken, M. J., 1985. Thermoluminescence Dating. London: Academic.
Ankjærgaard, C., and Murray, A. S., 2007. Total beta and gamma dose rates in trapped charge dating based on beta counting. Radiation Measurements, 42(3), 352–359.
Arnold, L. J., Duval, M., Falguères, C., Bahain, J.-J., and Demuro, M., 2012. Portable gamma spectrometry with cerium-doped lanthanum bromide scintillators: suitability assessments for luminescence and electron spin resonance dating applications. Radiation Measurements, 47(1), 6–18.
Bartoll, J., and Ikeya, M., 1997. ESR dating of pottery: a trial. Applied Radiation and Isotopes, 48(7), 981–984.
Bassiakos, Y., 2001. Assessment of the lower ESR dating range in Greek speleothems. Journal of Radioanalytical and Nuclear Chemistry, 247(3), 629–633.
Beerten, K., and Stesmans, A., 2005. Single quartz grain electron spin resonance (ESR) dating of a contemporary desert surface deposit, Eastern Desert, Egypt. Quaternary Science Reviews, 24(1–2): 223–231.
Beerten, K., Pierreux, D., and Stesmans, A., 2003. Towards single grain ESR dating of sedimentary quartz: first results. Quaternary Science Reviews, 22(10–13), 1329–1334.
Blackwell, B. A. B., Skinner, A. R., Mashriqi, F., Deely, A. E., Long, R. A., Gong, J. J. J., Kleindienst, M. R., and Smith, J. R., 2012. Challenges in constraining pluvial events and hominin activity: examples of ESR dating molluscs from the Western Desert, Egypt. Quaternary Geochronology, 10, 430–435.
Brennan, B. J., Rink, W. J., Rule, E. M., Schwarcz, H. P., and Prestwich, W. V., 1999. The ROSY ESR dating program. Ancient TL, 17(2), 45–53.
Duval, M., and Arnold, L. J., 2013. Field gamma dose-rate assessment in natural sedimentary contexts using LaBr3(Ce) and NaI(Tl) probes: a comparison between the “threshold” and “windows” techniques. Applied Radiation and Isotopes, 74, 36–45.
Duval, M., Grün, R., Falguères, C., Bahain, J.-J., and Dolo, J.-M., 2009. ESR dating of lower Pleistocene fossil teeth: limits of the single saturating exponential (SSE) function for the equivalent dose determination. Radiation Measurements, 44(5–6), 477–482.
Duval, M., Falguères, C., and Bahain, J.-J., 2012. Age of the oldest hominin settlements in Spain: contribution of the combined U-series/ESR dating method applied to fossil teeth. Quaternary Geochronology, 10, 412–417.
Duval, M., Bahain, J. -J., Falguères, C., Garcia, J., Guilarte, V., Grün, R., Martínez, K., Moreno, D., Shao, Q., and Voinchet, P., 2015. Revisiting the ESR chronology of the early pleistocene hominin occupation at Vallparadís (Barcelona, Spain). Quaternary International. doi:10.1016/j.quaint.2014.08.054
Falguères, C., 2003. ESR dating and the human evolution: contribution to the chronology of the earliest humans in Europe. Quaternary Science Reviews, 22(10–13), 1345–1351.
Falguères, C., Bahain, J.-J., Duval, M., Shao, Q., Han, F., Lebon, M., Mercier, N., Perez-Gonzalez, A., Dolo, J.-M., and Garcia, T., 2010. A 300–600 ka ESR/U-series chronology of Acheulian sites in Western Europe. Quaternary International, 223–224, 293–298.
Fattibene, P., and Callens, F., 2010. EPR dosimetry with tooth enamel: a review. Applied Radiation and Isotopes, 68(11), 2033–2116.
Goldstein, S. J., and Stirling, C. H., 2003. Techniques for measuring Uranium-series nuclides: 1992–2002. In. Bourdon, B., Henderson, G. M., Lundstrom, C. C., and Turner, S. P. (eds.), Uranium-Series Geochemistry. Reviews in Mineralogy and Geochemistry.Washington:Mineralogical Society of America, 52(1): 23–58.
Grün, R., 1989. Electron spin resonance (ESR) dating. Quaternary International, 1, 65–109.
Grün, R., 1992. Suggestions for minimum requirements for reporting ESR age estimates. Ancient TL, 10(3), 37–41.
Grün, R., 2007. Electron spin resonance dating. In Elias, S. A. (ed.), Encyclopedia of Quaternary Science. Amsterdam: Elsevier, pp. 1505–1516.
Grün, R., 2009a. The relevance of parametric U-uptake models in ESR age calculations. Radiation Measurements, 44(5–6), 472–476.
Grün, R., 2009b. The DATA program for the calculation of ESR age estimates on tooth enamel. Quaternary Geochronology, 4(3), 231–232.
Grün, R., Maroto, J., Eggins, S., Stringer, C., Robertson, S., Taylor, L., Mortimer, G., and McCulloch, M., 2006. ESR and U-series analyses of enamel and dentine fragments of the Banyoles mandible. Journal of Human Evolution, 50(3), 347–358.
Grün, R., Aubert, M., Hellstrom, J., and Duval, M., 2010. The challenge of direct dating old human fossils. Quaternary International, 223–224, 87–93.
Guérin, G., Mercier, N., and Adamiec, G., 2011. Dose-rate conversion factors: update. Ancient TL, 29(1), 5–8.
Ikeya, M., 1975. Dating a stalactite by electron paramagnetic resonance. Nature, 255(5503), 48–50.
Ikeya, M., 1993. New Applications of Electron Spin Resonance: Dating, Dosimetry and Microscopy. Singapore: World Scientific Publishing.
Laurent, M., Falguères, C., Bahain, J.-J., Rousseau, L., and Van Vliet Lanoé, B., 1998. ESR dating of quartz extracted from quaternary and neogene sediments: method, potential and actual limits. Quaternary Geochronology, 17(11), 1057–1062.
Lin, M., Yin, G., Ding, Y., Cui, Y., Chen, K., Wu, C., and Xu, L., 2006. Reliability study on ESR dating of the aluminum center in quartz. Radiation Measurements, 41(7–8), 1045–1049.
Ludwig, K. R., and Renne, P. R., 2000. Geochronology on the paleoanthropological time scale. Evolutionary Anthropology: Issues, News, and Reviews, 9(2), 101–110.
Miallier, D., Guérin, G., Mercier, N., Pilleyre, T., and Sanzelle, S., 2009. The Clermont radiometric reference rocks: a convenient tool for dosimetric purposes. Ancient TL, 27(2), 37–43.
Mishra, S., White, M. J., Beaumont, P., Antoine, P., Bridgland, D. R., Limondin-Lozouet, N., Santisteban, J. I., Schreve, D. C., Shaw, A. D., Wenban-Smith, F. F., Westaway, R. W. C., and White, T. S., 2007. Fluvial deposits as an archive of early human activity. Quaternary Science Reviews, 26(22–24), 2996–3016.
Molodkov, A., 2001. ESR dating evidence for early man at a Lower Palaeolithic cave-site in the Northern Caucasus as derived from terrestrial mollusc shells. Quaternary Science Reviews, 20(5–9), 1051–1055.
Monnier, J.-L., Hallégouët, B., Hinguant, S., Laurent, M., Auguste, P., Bahain, J.-J., Falguères, C., Gebhardt, A., Marguerie, D., Molines, N., Morzadec, H., and Yokoyama, Y., 1994. A new regional group of the Lower Palaeolithic in Brittany (France), recently dated by Electron Spin Resonance. Comptes Rendus de lAcadémie des sciences de Paris, 319, 155–160.
Olley, J. M., Murray, A., and Roberts, R. G., 1996. The effects of disequilibria in the uranium and thorium decay chains on burial dose rates in fluvial sediments. Quaternary Science Reviews, 15(7), 751–760.
Porat, N., and Schwarcz, H. P., 1991. Use of signal subtraction methods in ESR dating of burned flint. International Journal of Radiation Applications and Instrumentation. Part D. Nuclear Tracks and Radiation Measurements, 18(1–2), 203–212.
Prescott, J. R., and Hutton, J. T., 1994. Cosmic ray contributions to dose rates for luminescence and ESR dating: large depths and long-term time variations. Radiation Measurements, 23(2–3), 497–500.
Regulla, D. F., 2005. ESR spectrometry: a future-oriented tool for dosimetry and dating. Applied Radiation and Isotopes, 62(2), 117–127.
Rink, W. J., 1997. Electron spin resonance (ESR) dating and ESR applications in quaternary science and archaeometry. Radiation Measurements, 27(5–6), 975–1025.
Rink, W. J., Bartoll, J., Goldberg, P., and Ronen, A., 2003. ESR dating of archaeologically relevant authigenic terrestrial apatite veins from Tabun Cave, Israel. Journal of Archaeological Science, 30(9), 1127–1138.
Romanyukha, A. A., Schauer, D. A., Thomas, J. A., and Regulla, D. F., 2005. Parameters affecting EPR dose reconstruction in teeth. Applied Radiation and Isotopes, 62(2), 147–154.
Schwarcz, H. P., 1985. ESR studies of tooth enamel. Nuclear Tracks and Radiation Measurements (1982), 10(4–6), 865–867.
Shao, Q., Bahain, J.-J., Dolo, J.-M. and Falguères, C. (2014). Monte Carlo approach to calculate US-ESR age and age uncertainty for tooth enamel. Quaternary Geochronology, 22, 99–106.
Torres, T. de, Ortiz, J. E., Grün, R., Eggins, S., Valladas, H., Mercier, N., Tisnérat-Laborde, N., Juliá, R., Soler, V., Martínez, E., Sánchez-Moral, S., Cañaveras, J. C., Lario, J., Badal, E., Lalueza-Fox, C., Rosas, A., Santamaría, D., de la Rasilla, M., and Fortea, J., 2010. Dating of the hominid (Homo neanderthalensis) remains accumulation from el Sidrón cave (Piloña, Asturias, North Spain): an example of a multi-methodological approach to the dating of upper Pleistocene sites. Archaeometry, 52(4), 680–705.
Toyoda, S., and Ikeya, M., 1991. Thermal stabilities of paramagnetic defect and impurity centers in quartz: basis for ESR dating of thermal history. Geochemical Journal, 25(6), 437–445.
Valladas, H., Mercier, N., Ayliffe, L. K., Falguères, C., Bahain, J.-J., Dolo, J.-M., Froget, L., Joron, J.-L., Masaoudi, H., Reyss, J.-L., and Moncel, M.-H., 2008. Radiometric dates for the Middle Palaeolithic sequence of Payre (Ardèche, France). Quaternary Geochronology, 3(4), 377–389.
Voinchet, P., Falguères, C., Tissoux, H., Bahain, J.-J., Despriée, J., and Pirouelle, F., 2007. ESR dating of fluvial quartz: estimate of the minimal distance transport required for getting a maximum optical bleaching. Quaternary Geochronology, 2(1–4), 363–366.
Voinchet, P., Despriée, J., Tissoux, H., Falguères, C., Bahain, J.-J., Gageonnet, R., Dépont, J., and Dolo, J.-M., 2010. ESR chronology of alluvial deposits and first human settlements of the Middle Loire Basin (Region Centre, France). Quaternary Geochronology, 5(2–3), 381–384.
Yokoyama, Y., Bibron, R., and Falguères, C., 1988. Datation absolue des planchers stalagmitiques de la grotte du Vallonnet à Roquebrune-Cap-Martin (Alpes-Maritimes) France, par la Résonance de Spin Électronique (ESR). L’Anthropologie, 92(2), 429–436.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2017 Springer Science+Business Media Dordrecht
About this entry
Cite this entry
Duval, M. (2017). Electron Spin Resonance (ESR) in Archaeological Context. In: Gilbert, A.S. (eds) Encyclopedia of Geoarchaeology. Encyclopedia of Earth Sciences Series. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-4409-0_42
Download citation
DOI: https://doi.org/10.1007/978-1-4020-4409-0_42
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-4827-9
Online ISBN: 978-1-4020-4409-0
eBook Packages: Earth and Environmental ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences