Encyclopedia of Complexity and Systems Science

2009 Edition
| Editors: Robert A. Meyers (Editor-in-Chief)

Carbon Nanotubes, Thermo-mechanical and Transport Properties of

  • H. Rafii-Tabar
Reference work entry
DOI: https://doi.org/10.1007/978-0-387-30440-3_46

Definition of the Subject

Carbon nanotubes form the fourth allotrope of crystalline carbon after graphite , diamond , and a variety of caged‐like fullerene molecules, and were discovered in the early 1990s. Their mechanical properties make them stronger than steel, and their thermal conductivity is faster than copper. They have very exotic electronic‐conduction properties, namely, by changing their geometry, or introducing topological defects into their structure, their electronic conductance can change from metals to semi‐conductors. They can also be used to store gases and transport fluids. Furthermore, nano‐scale robots, machines, and sensors can be constructed from them, and these can be used to deliver drugs to specific locations in the body, or detect individual cancer cells, or be used as molecular filters to separate minute particles from the environment. Carbon nanotubes are referred to as the fabric of nano‐technology, and will play a central role in the future...

This is a preview of subscription content, log in to check access.

Bibliography

  1. 1.
    Ajayan PM, Ebbesen TW (1997) Nanometre‐size tubes of carbon. Rep Prog Phys 60:1025–1062ADSGoogle Scholar
  2. 2.
    Allen MP, Tildesley DJ (1987) Computer simulation of liquids. Clarendon Press, OxfordGoogle Scholar
  3. 3.
    Bekyarova E, Kaneko K, Kasuya D, Murata K, Yudasaka M, Iijima S (2002) Oxidation and porosity evaluation of budlike single‐wall carbon nanohorn aggregates. Langmuir 18:4138–4141Google Scholar
  4. 4.
    Berber S, Kwon YK, Tománek D (2000) Unusually high thermal conductivity of carbon nanotubes. Phys Rev Lett 84:4613–4616Google Scholar
  5. 5.
    Berbholc J, Brenner D, Nardelli MB, Meunier V, Roland C (2002) Mechanical and electrical properties of nanotubes. Annu Rev Mater Res 32:347–75Google Scholar
  6. 6.
    Bethune DS, Kiang CH, de Vries MD, Gorman G, Savoy R, Vazquez J, Beyers R (1993) Cobalt‐catalysed growth of carbon nanotubes with single‐atomic‐layer walls. Nature 363:605–607ADSGoogle Scholar
  7. 7.
    Bhushan B (ed) (2004) Springer handbook of nanotechnology. Springer, BerlinGoogle Scholar
  8. 8.
    Binnig G, Quate CF, Gerber C (1986) Atomic force microscope. Phys Rev Lett 56:930–933ADSGoogle Scholar
  9. 9.
    Binnig G, Rohrer H (1982) Scanning tunnelling microscopy. Helv Phys Acta 55:726–735Google Scholar
  10. 10.
    Buongiorno Nardelli M, Yakobson BI, Bernholc J (1998) Brittle and ductile behaviour in carbon nanotubes. Phys Rev Lett 81:4656–4659ADSGoogle Scholar
  11. 11.
    Buongiorno Nardelli M, Yakobson BI, Bernholc J (1998) Mechanism of strain release in carbon nanotubes. Phys Rev B 57:R4277–R4280ADSGoogle Scholar
  12. 12.
    Calbi MM, Toigo F, Cole MW (2001) Dilation‐induced phases of gases adsorbed within a bundle of carbon nanotubes. Phys Rev Lett 86:5062–5065ADSGoogle Scholar
  13. 13.
    Che J, Cagin T, Goddard WA III (2000) Thermal conductivity of carbon nanotubes. Nanotechnology 11:65–69ADSGoogle Scholar
  14. 14.
    Dai H (2002) Carbon nanotubes: opportunities and challenges. Surf Sci 500:218–241ADSGoogle Scholar
  15. 15.
    Dresselhaus MS, Dresselhaus G, Saito R (1995) Physics of Carbon Nanotubes. Carbon 33:883–891Google Scholar
  16. 16.
    Dresselhaus MS, Dresselhaus G, Saito R, Jorio A (2005) Raman spectroscopy of carbon nanotubes. Phys Rep 409:47–99ADSGoogle Scholar
  17. 17.
    Drexler KE (1992) Nanosystems: Molecular Machinery, Manufacturing and Computation. Wiley, New YorkGoogle Scholar
  18. 18.
    Haile JM (1992) Molecular dynamics simulation: Elementary methods. Wiley, New York Google Scholar
  19. 19.
    Hummer G, Rasaiah JC, Noworyta JP (2001) Water conduction through the hydrophobic channel of a carbon nanotube. Nature 414:188–190ADSGoogle Scholar
  20. 20.
    Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58ADSGoogle Scholar
  21. 21.
    Iijima S (2002) Carbon nanotubes: past, present, and future. Physica B 323:1–5ADSGoogle Scholar
  22. 22.
    Iijima S, Ichihashi T (1993) Single‐shell carbon nanotubes of 1‑nm diameter. Nature 363:603–605 ADSGoogle Scholar
  23. 23.
    Iijima S, Yudasaka M, Yamada R, Bandow S, Suenaga K, Kokai F, Takahashi K (1999) Nano‐aggregates of single‐walled graphitic carbon nano‐horns. Chem Phys Lett 309:165–170ADSGoogle Scholar
  24. 24.
    Jin Y, Yuan G (2003) Simulation of elastic properties of single‐walled carbon nanotubes. Compos Sci Technol 63:1507–1515Google Scholar
  25. 25.
    Kiang CH, Endo M, Ajayan PM, Dresselhaus G, Dresselhaus MS (1998) Size effects in carbon nanotubes. Phys Rev Lett 81:1869–1872ADSGoogle Scholar
  26. 26.
    Lavin JG, Subramoney S, Ruoff RS, Berber S, Tománek D (2002) Scrolls and nested tubes in multiwall carbon nanotubes. Carbon 40:1123–1130Google Scholar
  27. 27.
    Lee SM, An KH, Lee YH, Seifert G, Frauencheim T (2001) A hydrogen storage mechanism in single‐walled carbon nanotubes. J Am Chem Soc 123:5059–5063Google Scholar
  28. 28.
    Lu JP (1997) Elastic properties of carbon nanotubes and nanoropes. Phys Rev Lett 79:1297–1300ADSGoogle Scholar
  29. 29.
    Lu JP (1997) Elastic properties of single and multilayered nanotbes. J Phys Chem Solids 58:1649–1652ADSGoogle Scholar
  30. 30.
    Martí J, Gordillo MC (2001) Effects of confinement on the vibrational spectra of liquid water adsorbed in carbon nanotubes. Phys Rev B 63:165430-1–165430-5Google Scholar
  31. 31.
    Mizel A, Benedict LX, Cohen ML, Louie SG, Zettl A, Budraa NK, Beyermann WP (1999) Analysis of the low‐temperature specific heat of multiwalled carbon nanotubes and carbon nanotube ropes. Phys Rev B 60:3264–3270ADSGoogle Scholar
  32. 32.
    Murata K, Kaneko K, Steele WA, Kokai F, Takahashi K, Kasuya D, Hirahara K, Yudasaka M, Iijima S (2001) Molecular potential structures of heat‐treated single‐wall carbon nanohorn assemblies. J Phys Chem B 105:10210–10216Google Scholar
  33. 33.
    Murata K, Kaneko K, Steele WA, Kokai F, Takahashi K, Kasuya D, Hirahara K, Yudasaka M, Iijima S (2001) Porosity evaluation of intrinsic intraparticle nanopores of single wall carbon nanohorn. Nano Lett 1:197–199ADSGoogle Scholar
  34. 34.
    Nalwa HS (ed) (2004) Encyclopedia of nanoscience and nanotechnology, vol 1–10. American Scientific Publishers, CambridgeGoogle Scholar
  35. 35.
    Ohba T, Murata K, Kaneko K, Steele WA, Kokai F, Takahashi K, Kasuya K, Yudasaka M, Iijima S (2001) N2 adsorption in an internal nanopore space of single‐walled carbon nanohorn: GCMC simulation and experiment. Nano Lett 1:371–373ADSGoogle Scholar
  36. 36.
    Parr RG, Yang W (1989) Density functional theory of atoms and molecules. Oxford University Press, OxfordGoogle Scholar
  37. 37.
    Pathria RK (1972) Statistical mechanics. Pergamon, OxfordGoogle Scholar
  38. 38.
    Pekala K, Pekala M (1995) Low temperature transport properties of nanocrystalline Cu, Fe and Ni. NanoStructured Mater 6:819–822Google Scholar
  39. 39.
    Popov VN (2002) Low‐temperature specific heat of nanotube systems. Phys Rev B 66:153408-1–153408-4ADSGoogle Scholar
  40. 40.
    Popov VN (2004) Carbon nanotubes: properties and applications. Math Sci Eng R 43:61–102Google Scholar
  41. 41.
    Prylutskyy YI, Durov SS, Ogloblya OV, Buzaneva EV, Scharff P (2000) Molecular dynamics simulation of mechanical, vibrational and electronic properties of carbon nanotubes. Comp Math Sci 17:352–355Google Scholar
  42. 42.
    Rafii-Tabar H (2000) Modeling the nano‐scale phenomena in condensed matter physics via computer‐based numerical simulations. Phys Rep 325:239–310ADSGoogle Scholar
  43. 43.
    Rafii-Tabar H (2004) Computational modeling of thermo‐mechanical and transport properties of carbon nanotubes. Phys Rep 390:235–452ADSGoogle Scholar
  44. 44.
    Rafii-Tabar H (2008) Computational physics of carbon nanotubes. Cambridge University Press, CambridgeGoogle Scholar
  45. 45.
    Rao CNR, Satishkumar BC, Govindaraj A, Nath M (2001) Nanotubes. Chem Phys Chem 2:78–105Google Scholar
  46. 46.
    Rapaport DC (1995) The art of molecular dynamics simulation. Cambridge University Press, CambridgeGoogle Scholar
  47. 47.
    Reich S, Thomsen C, Ordejón P (2002) Elastic properties of carbon nanotubes under hydrostatic pressure. Phys Rev B 65:153407-1–153407-4Google Scholar
  48. 48.
    Rieth M, Schommers W (ed) (2007) Handbook of theoretical and computational nanotechnology, vol 1–10. American Scientific Publishers, CambridgeGoogle Scholar
  49. 49.
    Roco MC, Bainbridge WS (2002) Convergent technologies for improving human performance. NSF/DOC‐sponsored Report. WTEC Inc, ArlingtonGoogle Scholar
  50. 50.
    Saito Y, Yoshikawa T, Bandow S, Tomita M, Hayashi T (1993) Interlayer spacings in carbon nanotubes. Phys Rev B 48:1907–1909Google Scholar
  51. 51.
    Schwarz JA, Contescu CI, Putyera K (ed) (2004) Dekker encyclopedia of nanoscience and nanotechnology, vol 1–5. Marcel Dekker Inc, New YorkGoogle Scholar
  52. 52.
    Siber A (2002) Adsorption of He atoms in external grooves of single‐walled carbon nanotube bundles. Phys Rev B 66:205406-1–205406-6ADSGoogle Scholar
  53. 53.
    Simonyan VV, Diep P, Johnson JK (1999) Molecular simulation of hydrogen adsorption in charged single‐walled carbon nanotubes. J Chem Phys 111:9778–9783ADSGoogle Scholar
  54. 54.
    Simonyan VV, Johnson JK, Kuznetsova A, Yates Jr JT (2001) Molecular simulation of xenon adsorption on single‐walled carbon nanotubes. J Chem Phys 114:4180–4185ADSGoogle Scholar
  55. 55.
    Smith BW, Monthoux M, Luzzi DE (1998) Encapsulated C60 in carbon nanotubes. Nature 396:323–324ADSGoogle Scholar
  56. 56.
    Stevens RMD, Frederick NA, Smith BL, Morse DE, Stucky GD, Hansma PK (2000) Carbon nanotubes as probes for atomic force microscopy. Nanotechnology 11:1–5ADSGoogle Scholar
  57. 57.
    Stojkovic D, Zhang P, Crespi VH (2001) Smallest nanotube: breaking the symmetry of sp3 bonds in tubular geometries. Phys Rev Lett 87:125502–125505ADSGoogle Scholar
  58. 58.
    Supple S, Quirke N (2003) Rapid imbibition of fluids in carbon nanotubes. Phys Rev Lett 90:214501-1–214501-4ADSGoogle Scholar
  59. 59.
    Sutton AP, Pethica JB, Rafii-Tabar H, Nieminen JA (1994) Mechanical properties of metals at nanometre scale. In: Pettifor DG, Cottrell AH (eds) Electron theory in alloy design. Institute of Materials, London, pp 191–233Google Scholar
  60. 60.
    Talapatra S, Zambano AZ, Weber SE, Migone AD (2000) Gases do not adsorb on the interstitial channels of closed‐ended single‐walled carbon nanotube bundles. Phys Rev Lett 85:138–141Google Scholar
  61. 61.
    Tuzun RE, Noid DW, Sumpter BG, Merkle RC (1996) Dynamics of fluid flow inside carbon nanotubes. Nanotechnology 7:241–246Google Scholar
  62. 62.
    Wang Q, Johnson JK (1999) Molecular simulation of hydrogen adsorption in single‐walled carbon nanotubes and idealised carbon slit pore. J Chem Phys 110:577–586ADSGoogle Scholar
  63. 63.
    Wang Q, Johnson JK (1999) Optimisation of carbon nanotube arrays for hydrogen adsorption. J Phys Chem B 103:4809–4813Google Scholar
  64. 64.
    Williams KA, Eklund PC (2000) Monte Carlo simulation of H2 physisorption in finite‐diameter carbon nanotube ropes. Chem Phys Lett 320:352–358ADSGoogle Scholar
  65. 65.
    Yakobson BI, Brabec CJ, Bernholc J (1996) Nanomechanics of carbon tubes: instabilities beyond linear response. Phys Rev Lett 76:2511–2514ADSGoogle Scholar
  66. 66.
    Zhao J, Buldum A, Han J, Lu JP (2002) Gas molecule adsorption in carbon nanotubes and nanotube bundles. Nanotechnology 13:195–200ADSGoogle Scholar
  67. 67.
    Zhou LG, Shi SQ (2002) Molecular dynamic simulations on tensile mechanical properties of single‐walled carbon nanotubes with and without hydrogen storage. Comp Math Sci 23:166–174Google Scholar

Copyright information

© Springer-Verlag 2009

Authors and Affiliations

  • H. Rafii-Tabar
    • 1
    • 2
  1. 1.Department of Medical Physics and Biomedical EngineeringShahid Beheshti University of Medical SciencesTehranIran
  2. 2.Department of Nano‐scienceInstitute for Research in Fundamental Sciences (IPM)TehranIran