Encyclopedic Dictionary of Polymers

2007 Edition
| Editors: Jan W. Gooch

Rheometer, foam

Reference work entry
DOI: https://doi.org/10.1007/978-0-387-30160-0_9844

n. A special type of capillary rheometer developed by W. Kostyrzewski to measure the density and viscosity of foaming polyurethane immediately after mixing. Creaming time is also measured. It consists of a three-section vertical acrylic tube, adapted at the bottom to a reaction–injection-molding mixer (RIM machine). The bottom chamber is large enough to contain the mix charge delivered by the RIM machine, and the mixture rises through an instrumented and temperature-controlled “capillary” as the foam forms and expands. The instruments are connected to an analog-to-digital converter and computer. The foam passes up through the capillary into a larger-diameter collection chamber and raises a floating disk that can be weighted to adjust the pressure on the foam as it rises. Flow rate is inferred from foam density; rate of change of density, and shear rate at the capillary wall are computed from flow rate. Shear stress is inferred from the pressure-transducer readings.

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© Springer-Verlag 2007