Abstract
The problems of electrochemical synthesis of complex compounds of lanthanides with organic acids are discussed. It was shown that the resulting complex compounds are thermally stable and can be used as effective luminophores.
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References
Meshkova SB, Rusakova NV, Topilova ZM, Lozinsky MO (1992) Correlation of optical characteristics of different-ligand β-diketonate complexes of neodymium and europium with beta-diketone properties. Russ J Coord Chem 18(2):210–217. (in Russian)
Kharisov BI (2006) Direct low-temperature synthesis of coordination compounds of phthalocyanines and azomethines: DrSci. Dissertation, Rostov State University, Rostov-on-Don. 347 pp. (in Russian)
Kharisov BI, Ortiz Mendez U, Almaraz Garza JL (2005) Use of UV-irradiation for phthalocyanine preparation at low temperature. Influence of solvent nature. New J Chem 29(5):686–692
Kharisov BI, Kharissova OV, Méndez UO, Garnovskii AD, Tsivadze AYu (2007) Direct electrochemical synthesis of metal complexes of phthalocyanines and azomethines as model compounds: advantages and problems of this method versus traditional synthetic techniques. J Coord Chem 60(13):1435–1455
Kharisov BI, Blanco LM, Garcia-Luna A (1999) Direct electrochemical synthesis of metal complexes. Lanthanide phthalocyanines: optimization of the synthesis. Rev Soc Quim Мех 43(2):50–53
Frolov VY, Bolotin SN, Panyshkin VT (2005) Electrochemical synthesis of complex compounds of transition elements with carboxyl-and carbonyl-containing ligands. Russ J Appl Chem 78(6):897–902
Kryukova NP, Frolov VY, Kolokolov FA, Bolotin SN, Panyushkin VT (2005) Synthesis and Study of Copper(II) Complexes with Aspartic Acid, Serine, and Valine. Russ J Gen Chem 75(4):503–506
Panyushkin VT, Zelenov VI, Tyukhteneva ZI, Frolov VY (1995) Synthesis of new carboxylate complexes of rare earths. Russ J Gen Chem 65(3):517–519
Bogdashev NN, Garnovsky AD, Osipov OA, Grigoriev VP, Gontmakher NM (1976) Complex metal compounds with some nitrogen-containing ligands. Russ J Gen Chem 46(3):675. (in Russian)
Frolov VY, Panyushkin VT, Zelenov VI. Method for the preparation of rare earth acetylacetonates. Russian Patent 2191190, priority 29.01.2001, registered 20.10.2002
Korshunov VN (1990) Amalgam systems. M.: Nauka. 201 pp. (in Russian)
Bonnier E, Desre PS (1963) Calculation of the thermodynamic parameters of amalgams. C R Acad Sci 237:3404–3406
Mathien JC, Durand F, Bonnier E (1965) Thermodynamics of binary amalgam systems. J Chim Phys Phys-Chim Biol 62:1289–1296
Lesnik AG (1962) Models of interatomic interaction in the statistical theory of alloys. M. 278 pp. (in Russian)
Smirnov VА (1970) The reduction by amalgams. L.: Khimiya. 230 pp. (in Russian)
Davis S, James A (1979) Electrochemical dictionary. М.: Mir. 288 pp
Weissberger AD, Prskauer ES, Riddick JA, Toops EE Jr (1955) Organic solvents. Wiley (Interscience), New York, p 435
Coetzee JF, Cunningham GP, McGuire DK, Padmanabhan GR (1962) Purification of Acetonitrile as a Solvent for Exact Measurements. Anal Chem 34:1139
Kostyuk NN, Dik TA, Trebnikov AG, Shirokii VL (2003) Anodic dissolution of samarium in an acetonitrile solution in acetylacetone. Russ J Electrochem 39(11):1228–1232
Kostyuk NN, Dik TA, Tereshko NV, Trebnikov AG (2004) Electrochemical synthesis and physico-chemical study of lanthanum (III) acetylacetonate complexes. Radiochemistry 46(6):552–555
Kostyuk NN, Dik TA, Tereshko NV, Trebnikov AG (2003) Electrochemical synthesis of β-diketonates of La(III) in ethanol. Russ J Electrochem 39:1233–1235
Kostyuk NN, Dik TA, Trebnikov AG (2005) Cathodic electrolysis of samarium(III), europium(III), and ytterbium(III) chlorides in the presence of acetylacetone. Russ J Inorg Chem 50(9):1558–1561
Nazarenko MA, Oflidi AI, Kolokolov FA, Panyushkin VT (2017) Electrochemical Synthesis of Anhydrous Luminescent Tb3+ Complexes with Aromatic and Heterocyclic Carboxylic Acids. Russ J Gen Chem 87(5):1022–1025
Pikula AA, Kolechko DV, Panyushkin VT, Oflidi AI, Nazarenko MA (2013) Coordination compounds of europium(III), terbium(III), dysprosium(III), samarium(III), and gadolinium(III) with 2-acetylbenzoic acid. Russ J Inorg Chem 58(7):773–776
Pashchevskaya NV, Nazarenko MA, Bolotin SN, Oflidi AI, Panyushkin VT (2010) Effect of the condition of synthesis on the composition and structure of copper(II) complexes with benzimidazole. Russ J Inorg Chem 55(9):1425
Shuvaev S, Utochnikova V, Marciniak Ł et al (2014) Lanthanide complexes with aromatic ophosphorylated ligands: synthesis, structure elucidation and photophysical properties. Dalton Trans 43(8):3121
Monteiro JHSK, Formiga ALB, Sigoli F (2014) The influence of carboxilate, phosphinate and seleninate groups on luminescent properties of lanthanides complexes. J Lumin 154:22
Kalyakina AS, Sokolova EY, Vaschenko AA et al (2013) High efficiency organic light-emitting diode based on uv stable terbium aromatic carboxylates. Proceedings to SID Mid-Europe Chapter Spring Meeting, vol 2013, p 19
Trivedi ER, Eliseeva SV, Jankolovits J et al (2014) Highly emitting near-infrared lanthanide “encapsulated sandwich” metallacrown complexes with excitation shifted toward lower energy. J Am Chem Soc 136(4):1526
Solodukhin NN, Utochnikova VV, Lepnev LS, Kuzmina NP (2014) Mixed-ligand terbium hydroxyaromatic carboxylates with o-phenanthroline: luminescence quenching at 300 and 77 K. Mendeleev Commun 24(2):91
Utochnikova VV, Kuzmina NP (2016) Photoluminescence of lanthanide aromatic carboxylates. Russ J Coord Chem 42(10):679
Kolechko DV, Kolokolov FA, Oflidi AI, Pikula AA, Panyushkin VT, Mikhailov IE, Dushenko GA (2011) Novel luminescent lanthanides complexes with 1,10-phenanthroline-2,9-dicarboxylic acid. Dokl Phys Chem 441:374
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Panyushkin, V., Kolokolov, F.A., Oflidi, A.I., Nazarenko, M.A. (2019). Electrochemical Synthesis of Coordination Compounds of Lanthanides: Effective Luminophores. In: Martínez, L., Kharissova, O., Kharisov, B. (eds) Handbook of Ecomaterials. Springer, Cham. https://doi.org/10.1007/978-3-319-68255-6_42
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DOI: https://doi.org/10.1007/978-3-319-68255-6_42
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