Skip to main content

Polyvinyl Resins

  • Living reference work entry
  • First Online:
  • 130 Accesses

Abstract

Polyvinyls are not sensitizers. Some additives of polyvinyl resins are highly sensitizing: phthalates, maleates, benzophenones, epoxy resins, etc.

Diagnostic procedures include patch-testing with vinylic resins and additives used in the polymerization process.

Polyvinyl chloride (PVC) always contains free molecules of vinyl chloride that can induce allergic contact dermatitis, contact urticaria, Raynaud’s syndrome, and systemic sclerosis.

PVC powder has irritating properties.

Incineration of PVC objects releases dioxin and HCl, posing hazard to skin and mucosa.

Polyvinyl resins have multiple uses including medical purposes.

Gheorghe Bucur: deceased.

This is a preview of subscription content, log in via an institution.

References

  • Aalto-Korte K, Alanko K, Henriks-Eckerman ML, Estlander T, Jolanki R (2003) Allergic contact dermatitis from bisphenol a in PVC gloves. Contact Dermatitis 49(4):202–205

    Article  CAS  PubMed  Google Scholar 

  • Aalto-Korte K, Alanko K, Henriks-Eckerman ML, Jolanki R (2006) Antimicrobial allergy from polyvinyl chloride gloves. Arch Dermatol 142(10):1326–1330

    Article  PubMed  Google Scholar 

  • Aalto-Korte K, Ackermann L, Henriks-Eckerman ML, Välimaa J, Reinikka-Railo H, Leppänen E, Jolanki R (2007) 1,2-benzisothiazolin-3-one in disposable polyvinyl chloride gloves for medical use. Contact Dermatitis 57(6):365–370

    Article  CAS  PubMed  Google Scholar 

  • Anavekar NS, Nixon R (2006) Occupational allergic contact dermatitis to cobalt octoate included as an accelerator in a polyester resin. Australas J Dermatol 47(2):143–144

    Article  PubMed  Google Scholar 

  • Arellano-Rodrigo E, Real MI, Muntañola A, Burrel M, Rozman M, Fraire GV, Cervantes F (2004) Successful treatment by selective arterial embolization of severe retroperitoneal hemorrhage secondary to bone marrow biopsy in post-polycythemic myelofibrosis. Ann Hematol 83(1):67–70

    Article  CAS  PubMed  Google Scholar 

  • Artigas J (1955) Staining technic by molybdic hematoxylin for protozoa in stool smears preserved in polivinyl alcohol fixative. Bol Chil Parasitol 10(3):57–58

    PubMed  CAS  Google Scholar 

  • Björkner B (2000) Other plastics. In: Kanerva L, Elsner P, Wahlberg JE, Maibach HI (eds) Handbook of occupational dermatology. Springer, Berlin/Heidelberg, p 607

    Chapter  Google Scholar 

  • Chappell G, Pogribny IP, Guyton KZ, Rusyn I (2016) Epigenetic alterations induced by genotoxic occupational and environmental human chemical carcinogens: a systematic literature review. Mutat Res Rev Mutat Res 768:27–45

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Chevillard C, Rugina M, Bonfils P, Bougara A, Castillo L, Crampette L, Pandraud L, Samardzic M, Peynègre R (2006) Evaluation of calcium alginate nasal packing (Algostéril) versus polyvinyl acetal (Merocel) for nasal packing after inferior turbinate resection. Rhinology 44(1):58–61

    PubMed  Google Scholar 

  • Costner P, Cray C, Martin G, Rice B, Santillo D, Stringeret R (1995) PVC: a primary contributor to the U.S. dioxin burden. Comments submitted to the U.S. EPA dioxin reassessment. Greenpeace, Washington, DC

    Google Scholar 

  • Creech J, Johnson M (1974) Angiosarcoma of liver in the manufacture of polyvinyl chloride. J Occup Med 16(3):150–151

    PubMed  Google Scholar 

  • Di Lernia V, Cameli N, Patrizi A (1989) Irritant dermatitis in a child by the plastic tube of an infusion system. Contact Dermatitis 21(5):339–340

    Article  PubMed  Google Scholar 

  • Durner J, Stojanovic M, Urcan E, Spahl W, Haertel U, Hickel R, Reichl FX (2011) Effect of hydrogen peroxide on the three-dimensional polymer network in composites. Dent Mater 27(6):573–580

    Article  CAS  PubMed  Google Scholar 

  • English JSC, Lovell CR, Rycroft RJG (1985) Contact dermatitis from dibutyl maleate. Contact Dermatitis 13(5):337–338

    Article  CAS  PubMed  Google Scholar 

  • Estlander T, Jolanki R, Kanerva L (1986) Dermatitis and urticaria from rubber and plastic gloves. Contact Dermatitis 14(1):20–25

    Article  CAS  PubMed  Google Scholar 

  • Fregert S, Rorsman H (1963) Hypersensitivity to epoxy resins used as plasticizers and stabilizers in polyvinyl chloride (PVC) resins. Acta Derm Venereol 43:10–13

    PubMed  CAS  Google Scholar 

  • Fregert S, Trulsson L, Zimerson E (1982) Contact allergic reaction to diphenylthiourea and phenylisothiocyanate in PVC adhesive tape. Contact Dermatitis 8(1):38–42

    Article  CAS  PubMed  Google Scholar 

  • Fregert S, Meding B, Trulsson L (1984) Demonstration of epoxy resin in stoma pouch plastic. Contact Dermatitis 10(2):106

    Article  CAS  PubMed  Google Scholar 

  • Fromageau J, Brusseau E, Vray D, Gimenez G, Delachartre P (2003) IEEE transactions on ultrasonics. Ferroelectr Freq Control 50(10):1318–1324

    Article  Google Scholar 

  • Gettens RJ, Stout GL (1966) Painting materials: a short encyclopaedia. Dover, New York, p 331

    Google Scholar 

  • Goh CL, Ho SF (1988) An outbreak of acneiform eruption in a polyvinyl chloride manufacturing factory. Derm Beruf Umwelt 36(2):53–57

    PubMed  CAS  Google Scholar 

  • Haustein UF, Ziegler V (1986) Scleroderma and scleroderma-like diseases caused by environmental pollutants. Derm Beruf Umwelt 34(3):61–67

    PubMed  CAS  Google Scholar 

  • Hayakawa M, Fujisawa S (1963) Occlusive dressing method with plastic films (Saran wrap, KRE wrap and polyethylene) as topical corticosteroid therapy for skin diseases and a peculiar urticoerythema caused by Saran wrap (KRE wrap). Hifuka Kiyo 58:144–157

    PubMed  CAS  Google Scholar 

  • Hills RJ, Ive FA (1993) Allergic contact dermatitis from di-isodecyl phthalate in a polyvinyl chloride identity band. Contact Dermatitis 29(2):94–95

    Article  CAS  PubMed  Google Scholar 

  • Hindson C, Lawlor F (1982) Allergy to glyoxal in a polyvinyl resin emulsion. Contact Dermatitis 8(3):213

    Article  CAS  PubMed  Google Scholar 

  • Jolanki R, Estlander T, Kanerva L (1987) Contact allergy to an epoxy reactive diluent: 1,4-butanediol diglycidyl ether. Contact Dermatitis 16(2):87–92

    Article  CAS  PubMed  Google Scholar 

  • Kanerva L, Estlander T, Jolanki R (1989) Allergic contact dermatitis from dental composite resins due to aromatic epoxy acrylates and aliphatic acrylates. Contact Dermatitis 20(3):201–211

    Article  CAS  PubMed  Google Scholar 

  • Kanerva L, Estlander T, Jolanki R (1994) Occupational allergic contact dermatitis caused by thiourea compounds. Contact Dermatitis 31(4):242–248

    Article  CAS  PubMed  Google Scholar 

  • Kawakami T, Isama K, Ikarashi Y (2014) Analysis of isothiazolinone preservatives in polyvinyl alcohol cooling towels used in Japan. J Environ Sci Health A Tox Hazard Subst Environ Eng 49(11):1209–1217

    Article  CAS  PubMed  Google Scholar 

  • Lee HS, Lin YW (2009) Permeation of hair dye ingredients, p-phenylenediamine and aminophenol isomers, through protective gloves. Ann Occup Hyg 53(3):289–296

    PubMed  CAS  Google Scholar 

  • Lind ML, Johnsson S, Lidén C, Meding B, Boman A (2015) The influence of hydrogen peroxide on the permeability of protective gloves to resorcinol in hairdressing. Contact Dermatitis 72(1):33–39

    Article  CAS  PubMed  Google Scholar 

  • Lithner D, Larsson A, Dave G (2011) Environmental and health hazard ranking and assessment of plastic polymers based on chemical composition. Sci Total Environ 409(18):3309–3324

    Article  CAS  PubMed  Google Scholar 

  • Lopez V, Chamoux A, Tempier M, Thiel H, Ughetto S, Trousselard M, Naughton G, Dutheil F (2013) The long-term effects of occupational exposure to vinyl chloride monomer on microcirculation: a cross-sectional study 15 years after retirement. BMJ Open 3(6)

    Article  PubMed  PubMed Central  Google Scholar 

  • Matsuoka T, Kurohane K, Suzuki W, Ogawa E, Kobayashi K, Imai Y (2016) Dibutyl maleate and Dibutyl fumarate enhance contact sensitization to fluorescein Isothiocyanate in mice. Biol Pharm Bull 39(2):272–277

    Article  CAS  PubMed  Google Scholar 

  • Murray GT (1997) Handbook of materials selection for engineering applications. M. Dekker, New York, p 242

    Google Scholar 

  • Noster U, Hausen BM (1978) Occupational dermatitis due to a yellow quinophthalone dye (solvent yellow 33: C.I. 47 000). Hautarzt 29(3):153–157

    PubMed  CAS  Google Scholar 

  • Osbourn RA (1964) Contact dermatitis caused by Saran wrap. JAMA 188:1159

    Article  CAS  PubMed  Google Scholar 

  • Osmundsen PE (1980) Contact urticaria from nickel and plastic additives (butylhydroxytoluene, oleylamide). Contact Dermatitis 6(7):452–454

    Article  CAS  PubMed  Google Scholar 

  • Pontén A, Dubnika I (2009) Delayed reactions to reusable protective gloves. Contact Dermatitis 60(4):227–229

    Article  PubMed  Google Scholar 

  • Rahman S (2007) PVC pipe & fittings: underground solutions for water and sewer systems in North America. 2nd Brazilian PVC Congress, Sao Paulo, 19–20 June 2007. Available at: http://www.institutodopvc.org/congresso2/ShahRahman.pdf. Accessed 14 June 2011

  • Salles JC, Deschamps FJ (2010) Allergic contact dermatitis due to a PVC table cover. Occup Med (Lond) 60(8):662–664

    Article  CAS  Google Scholar 

  • Sanmartín O, De La Cuadra J (1992) Occupational contact dermatitis from cyclohexanone as a PVC adhesive. Contact Dermatitis 27(3):189–190

    Article  PubMed  Google Scholar 

  • Schulsinger C, Møllgaard K (1980) Polyvinyl chloride dermatitis not caused by phthalates. Contact Dermatitis 6(7):477–480

    Article  CAS  PubMed  Google Scholar 

  • Suuronen K, Pesonen M, Henriks-Eckerman ML, Aalto-Korte K (2013) Triphenyl phosphite, a new allergen in polyvinylchloride gloves. Contact Dermatitis 68(1):42–49

    Article  CAS  PubMed  Google Scholar 

  • Swan SH (2008) Environmental phthalate exposure in relation to reproductive outcomes and other health endpoints in human. Environ Res 108(2):177–184

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Takeo K et al (2002) Formation of PCDDs, PCDFs, and coplanar PCBs from polyvinyl chloride during combustion in an incinerator. Environ Sci Technol 36:1320–1324

    Article  CAS  Google Scholar 

  • Thornton J (2002) Environmental impacts of polyvinyl chloride building materials. Healthy Building Network, Washington, DC

    Google Scholar 

  • Titow WV (1984) PVC technology, 4th edn. Elsevier Applied Science, Essex

    Book  Google Scholar 

  • Van Ketel WG, Van Den Berg WH (1984) The problem of the sensitization to dithiocarbamates in thiuram-allergic patients. Dermatologica 169(2):70–75

    Article  PubMed  Google Scholar 

  • Vidovic R, Kansky A (1985) Contact dermatitis in workers processing polyvinyl chloride plastics. Derm Beruf Umwelt 33(3):104–105

    PubMed  CAS  Google Scholar 

  • Vidović R, Kansky A (1985) Contact dermatitis in workers processing polyvinyl chloride plastics. Derm Beruf Umwelt 33(3):104–105

    PubMed  Google Scholar 

  • Wagner J, Green A (1993) Correlation of chlorinated organic compound emissions from incineration with chlorinated organic input. Chemosphere 26(11):2039–2054

    Article  CAS  Google Scholar 

  • Weimann S, Skudlik C, John SM (2010) Allergic contact dermatitis caused by the blue pigment VINAMON® blue BX FW – a phthalocyanine blue in a vinyl glove. J Dtsch Dermatol Ges 8(10):820–822

    PubMed  Google Scholar 

  • Yamamoto K (1975) Acute toxicity of the combustion products from various kinds of fibers. Z Rechtsmed 76(1):11–26

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to George-Sorin Ţiplica .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer International Publishing AG, part of Springer Nature

About this entry

Check for updates. Verify currency and authenticity via CrossMark

Cite this entry

Sălăvăstru, C.M., Bucur, L., Ţiplica, GS., Bucur, G. (2018). Polyvinyl Resins. In: John, S., Johansen, J., Rustemeyer, T., Elsner, P., Maibach, H. (eds) Kanerva’s Occupational Dermatology. Springer, Cham. https://doi.org/10.1007/978-3-319-40221-5_206-2

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-40221-5_206-2

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-40221-5

  • Online ISBN: 978-3-319-40221-5

  • eBook Packages: Springer Reference MedicineReference Module Medicine

Publish with us

Policies and ethics