Abstract
In this study, two groups of the cement-matrix nanocomposites (CMNC) were produced. The first group was reinforced with either carbon nanotubes (CNT) or graphene oxide (GO), where the equivalent weight% of cement equaled 0.05, 0.1, and 0.15. The second group was reinforced with the hybrid CNT–GO, where the equivalent weight% of cement equaled 0.05 CNT–0.1 GO and 0.1 CNT–0.05 GO. Before producing nanocomposites, the distribution of the nanoreinforcement in water had been investigated using spectrophotometric analysis, scanning electron microscopy, and transmission electron microscopy. The physical and mechanical behaviors of different samples of the produced nanocomposites were evaluated by electrical resistivity and compressive strength tests. The effects of the types and the percentages of the nanoreinforcements on the electrical and mechanical properties of the produced nanocomposites were measured. The results showed that the electrical resistivity of the produced composites decreased with increasing the percentage of CNT, whereas the compressive strength of the cement paste initially increased and then decreased. Also, with increasing the percentage of GO, the compressive strength of the produced composites increased, while the electrical resistivity decreased. Moreover, in comparison with the composites reinforced with either CNT or GO, by using the hybrid reinforcement (CNT/GO), the compression strength increased, while the electrical resistivity decreased.
Similar content being viewed by others
References
Ubertini F, Materazzi AL, D’Alessandro A, Laflamme S. Natural frequencies identification of a reinforced concrete beam using carbon nanotube cement-based sensors. Eng Struct. 2014;60:265–75.
Konsta-Gdoutos MS, Aza CA. Self-sensing carbon nanotube (CNT) and nanofiber (CNF) cementitious composites for real time damage assessment in smart structures. Cem Concr Compos. 2014;53:162–9.
Raki L, Beaudoin J, Alizadeh R, Makar J, Sato T. Cement and concrete nanoscience and nanotechnology. Materials. 2010;3:918–42.
Lenous M. Carbon nanotubes influence on the compressive strength of cement composites. Tech Trans. 2014;1-B:5–11.
Makar J, Margeson J, Luh J. Carbon nanotube/cement composites-early results and potential applications. In: Third international conference on construction materials. Vancouver: Innovations and Structural Implications; 2005. p. 1–10.
Lu Z, Hou D, Meng L, Sun G, Lu C, Li Z. Mechanism of cement paste reinforced by graphene oxide/carbon nanotubes composites with enhanced mechanical properties. R Soc Chem. 2015;5:100598–605.
Lv S, Ting S, Liu J, Zhou Q. Use of graphene oxide nanosheets to regulate the microstructure of hardened cement paste to increase its strength and toughness. R Soc Chem. 2014;16:8508–16.
Lv S, Ma Y, Qiu C, Zhou Q. Regulation of GO on cement hydration crystals and its toughening effect. Mag Concr Res. 2013;65:1246–54.
Zhou C, Li F, Hu J, Ren M, Wei J, Yu Q. Enhanced mechanical properties of cement paste by hybrid graphene oxide/carbon nanotubes. Constr Build Mater. 2017;134:336–45.
Jiang S, Zhou D, Zhang L, Ouyang J, Yu X, Cui X, Han B. Comparison of compressive strength and electrical resistivity of cementitious composites with different nano-and micro-fillers. Arch Civ Mech Eng. 2018;18:60–8.
Konsta-Gdoutos MS, Metaxa ZS, Shah PS. Highly dispersed carbon nanotube reinforced cement based materials. Cem Concr Res. 2010;40:1052–9.
Sixuan H. Multifunctional graphite nanoplatelets (GNP) reinforced cementitious composites. Master’s thesis. University of Singapore; 2012.
Li GY, Wang PM, Zhao XH. Pressure-sensitive properties and microstructure of carbon nanotube reinforced cement composites. Cem Concr Compos. 2007;29:377–82.
Aghajani D. Investigation of the electrochemical behavior and the use of gold electrode modified by functionalized graphene at the edges. Master’s thesis. University of Iran; 2014.
Han BG, Yu X, Ou JP. Effect of water content on the piezoresistivity of CNTs/cement composites. J Mater Sci. 2010;45:3714–9.
Ou JP, Han BG. Piezoresistive cement-based strain sensors and self-sensing concrete components. J Intell Mater Syst Struct. 2009;20:329–36.
Funding
This study was not funded.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Ethical issues
Authors state that the research was conducted according to ethical standards.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Najafishad, S., Manesh, H.D., Zebarjad, S.M. et al. Production and investigation of mechanical properties and electrical resistivity of cement-matrix nanocomposites with graphene oxide and carbon nanotube reinforcements. Archiv.Civ.Mech.Eng 20, 57 (2020). https://doi.org/10.1007/s43452-020-00059-5
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s43452-020-00059-5