Abstract
In this study, hair waste was converted into active carbon for the first time and its characteristics were analyzed. As chemical activation tool, zinc chloride (ZnCl2) was impregnated and then carbonized under different temperatures (250–300 °C). Scanning Electron Microscope (SEM) images showed an increase in the pore density, radius and volume of pores. X-ray diffraction analysis (XRD) showed that the samples had an amorphous structure. In Fourier-transform infrared (FT-IR) spectroscope analysis, C=C and N–H vibrations observed in 1515–1520 cm−1 wave number of protein molecules were found to disappear with the increase in temperature. With Raman spectroscopy, the behaviors of D peak at 1344 cm−1 wave number and G peak at 1566 cm−1 wave number expressing structure layout in carbonized structures were analyzed depending on the temperatures. Between these intensities, (ID/IG) the rate was found to differ in direct proportion to temperature. XRD spectrums showed that the samples are converted into a more irregular crystal structure. All these results implied that the waste hair mass could be used as an adsorbant material.
Similar content being viewed by others
References
Gupta A (2014) Human hair “waste” and its utilization: gaps and possibilities. J Waste Manage. https://doi.org/10.1155/2014/498018
Ghosh A, Collie S (2014) Keratinous materials as novel absorbent systems for toxic pollutants. Def Sci J 64(3):209–221. https://doi.org/10.14429/dsj.64.7319
Ifelebuegu AO, Nguyen TVA, Ukotije-Ikwut P, Momoh Z (2015) Liquid-phase sorption characteristics of human hair as a natural oil spill sorbent. J Environ Chem Eng 3(2):938–943. https://doi.org/10.1016/j.jece.2015.02.015
Leblond CP (1951) Histological structure of hair, with a brief comparison to other epidermal appendages and epidermis itself. Ann N Y Acad Sci 53:464–475. https://doi.org/10.1111/j.1749-6632.1951.tb31949.x
Banat FA, Al-Asheh S (2001) The use of human hair waste as a phenol biosorbent. Adsorpt Sci Technol 19:599–608. https://doi.org/10.1260/0263617011494420
Srividya K, Mohanty K (2009) Biosorption of hexavalent chromium from aqueous solutions by catla catla scales: equilibrium and kinetics studies. Chem Eng J 155(3):666–673. https://doi.org/10.1016/j.cej.2009.08.024
Nadeem R, Ansari TM, Khalid AM (2008) Fourier transform infrared spectroscopic characterization and optimization of Pb(II) biosorption by fish (Labeo rohita) scales. J Hazard Mater 156(1–3):64–73. https://doi.org/10.1016/j.jhazmat.2007.11.124
Banat F, Al-Asheh S, Al-Rousan D (2002) Comparison between different keratin-composed biosorbents for the removal of heavy metal ions from aqueous solutşons. Adsorpt Sci Technol 20(4):393–416. https://doi.org/10.1260/02636170260295579
Khosa MA, Ullah AA (2013) Sustainable role of keratin biopolymer in green chemistry: a review. J Food Proc Beverages 1(1):8
Tonettia C, Aluigia A, Selminb F, Cilurzob F, Mazzuchetti G (2015) Removal of Cu(II) ions from water using thermally-treated horn-hoof powder as biosorbent. Desalination Water Treat 55(4):1105–1115
Masri MS, Friedman M (1974) Interactions of keratins with metal ions: uptake profiles, mode of binding, and effects on properties of wool. Adv Exp Med Biol 48:551–587
Masri MS, Friedman M (1974) Effect of chemical modification of wool on metal ion binding. J Appl Polym Sci 18(8):2367–2377
Masri MS, Reuter FW, Friedman M (1974) Interactions of wool with metal, cations. Textile Res J 44(4):298–300
Bruce Fraser RD, Parry DAD (2012) The role of disulfide bond formation in the structural transition observed in the intermediate filaments of developing hair. J Struct Biol 180(1):117–124. https://doi.org/10.1016/j.jsb.2012.05.020
Meyer B (1976) Elemental sulfur. Chem Rev 76(3):367–388
Igowsky K, Pangerl E (2013) American society of trace evidence examiners 44:17–27
Leichang C, Iris KMY, Daniel CWT, Shicheng Z, Yong Sik O, Eilhann EK, Hocheol S, Chi Sun P (2018) Phosphoric acid-activated wood biochar for catalytic conversion of starch-rich food waste into glucose and 5-hydroxymethylfurfural. Biores Technol 267:242–248. https://doi.org/10.1016/j.biortech.2018.07.048
Shamsuddin MS, Yusoff NRN, Sulaiman MA (2016) Synthesis and characterization of activated carbon produced from Kenaf core fiber using H3PO4 activation. Proc Chem 19:558–565. https://doi.org/10.1016/j.proche.2016.03.053
Dong X, Fen T, Chuanpan Z, Xiuli J, Zheng C, Heng L, Yanmei Z, Qingbiao L, Yuanpeng W (2016) ZnCl2-activated biochar from biogas residue facilitates aqueous As(III) removal. Appl Surf Sci 377:361–369. https://doi.org/10.1016/j.apsusc.2016.03.109
Xue-Lei D, Chun-Gang Y, Tian-Tian J, Xiao-Dong Y (2019) Removal of elemental mercury using large surface area micro-porous corn cob activated carbon by zinc chloride activation. Fuel 239:830–840. https://doi.org/10.1016/j.fuel.2018.11.017
Kun Y, Lianghong Z, Jingjing Y, Daohui L (2018) Adsorption and correlations of selected aromatic compounds on a KOH-activated carbon with large surface area. Sci Total Environ 618:1677–1684. https://doi.org/10.1016/j.scitotenv.2017.10.018
Qiang A, Yun-Qiu J, Hong-Yan N, Yang Y, Jun-Nan J (2019) Unraveling sorption of nickel from aqueous solution by KMnO4 and KOH-modified peanut shell biochar: implicit mechanism. Chemosphere 214:846–854. https://doi.org/10.1016/j.chemosphere.2018.10.007
Naik R, Wen G, Dharmaprakash MS, Hureau S, Uedono A, Wang X, Liu X, Cookson PG, Smith SV (2010) Metal ion binding properties of novel wool powders. J Appl Polym Sci 115(3):1642–1650. https://doi.org/10.1002/app.31206
Sayğılı H (2017) Studies on structural, morphological and porous properties of carbonaceous material made from a novel precursor. DUMF J Eng 8(1):245–252
Zhonghua H, Vansant EF (1995) A new composite adsorbent produced by chemical activation of elutrilithe with zinc chloride. J Colloid Interface Sci 176:422–431
Yan W, Daniel Charles A, McCreery Richard L (1990) Raman spectroscopy of carbon materials: structural basis of observed spectra. Chem Mater 2:557–563
Tuinstra F, Koenig JL (1970) Raman spectrum of graphite. J Chem Phys 53:1126
Kudin KN, Ozbas B, Schniepp HC, Prud’homme RK, Aksay IA, Car R (2008) Raman spectra of graphite oxide and functionalized graphene sheets. Nano Lett 8(1):36–41. https://doi.org/10.1021/nl071822y
Lucchese MM, Stavale F, Martins Ferreira EH, Vilani C, Moutinho MVO, Capaz RB, Achete CA, Jorio A (2010) Quantifying ion-induced defects and Raman relaxation length in graphene. Carbon 48(5):1592–1597. https://doi.org/10.1016/j.carbon.2009.12.057
Yang H, Hu H, Wang Y, Yu T (2013) Rapid and non-destructive identification of graphene oxide thickness using white light contrast spectroscopy. Carbon. https://doi.org/10.1016/j.carbon.2012.10.005
Budrys RS (1986) Ftir analysis of cationic polymers on human-hair. J Soc Cosmet Chem 37(4):289–290
Shanmugasundaram OL, Ramkumar M (2018) Characterization and study of physical properties and antibacterial activities of human hair keratin-silver nanoparticles and keratin-gold nanoparticles coated cotton gauze fabric. J Ind Text 47(5):798–814. https://doi.org/10.1177/1528083716674904
Sundaramoorthi K, Sethu G, Ethirajulu S, Raja Marthandam P (2017) Efficacy of metformin in human single hair fibre by ATR-FTIR spectroscopy coupled with statistical analysis. J Pharm Biomed Anal 136:10–13. https://doi.org/10.1016/j.jpba.2016.11.057
Trivedi MK, Sethi KK, Panda P, Jana S (2017) A comprehensive physicochemical, thermal, and spectroscopic characterization of zinc (II) chloride using X-ray diffraction, particle size distribution, differential scanning calorimetry, thermogravimetric analysis/differential thermogravimetric analysis, ultraviolet-visible, and Fourier transform-infrared spectroscopy. Int J Pharm Investig 7(1):33–40. https://doi.org/10.4103/jphi.JPHI_2_17
Mohd Abdul M, Zafar MKM (2017) FTIR spectroscopic analysis on human hair. Int J Innov Res Sci Eng Technol 6(5):9327–9332. https://doi.org/10.15680/IJIRSET.2017.0605195
Xu Z, Tian D, Sun Z, Zhang D, Zhou Y, Chen W, Deng H (2019) “Highly porous activated carbon synthesized by pyrolysis of polyester fabric wastes with different iron salts: pore development and adsorption behaviour. Colloids Surf A 565:180–187
Funding
There is no specific funding.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
There are no specific conflicts of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Bal Altuntaş, D., Nevruzoğlu, V., Dokumacı, M. et al. Synthesis and characterization of activated carbon produced from waste human hair mass using chemical activation. Carbon Lett. 30, 307–313 (2020). https://doi.org/10.1007/s42823-019-00099-9
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42823-019-00099-9