Abstract
The study focuses on the assessment of coastal aquifers in the selected part of Port Harcourt, Nigeria for drinking, industrial, and irrigation use. For this study, a total of 18 groundwater samples were collected from the borehole for physicochemical analysis following the APHA set standard. Results obtained from physicochemical analysis were compared to the WHO and USEPA set limits to determine the suitability of groundwater for domestic use. Collin’s Ratio and Corrosivity Ratio was used to determine the suitability of groundwater for industrial use, while irrigation indices were used to determine the suitability of groundwater for irrigation use. Findings from the study revealed that pH, TDS, EC, Mg2+, Na+, NO3¯, Ca2+, Cl¯, and SO42¯ were below the WHO and USEPA set limits. The values of K+ at some sample locations were above the permissible limit set by WHO. Hence, groundwater at such sampling points was considered unsafe for domestic use. Findings obtained from the assessment of groundwater for industrial use revealed that 91% of groundwater is considered suitable for industrial use, while 9% is considered to be fairly suitable for industrial use. Further findings from Collin’s ratio revealed that 4% of groundwater was considered suitable for drinking, while 3% is considered to show a trace of saline water intrusion, and about 97% is considered to be injurious to human health. According to the irrigation indices estimated values, 72% of groundwater is suitable for irrigation, while 28% is considered to be fair to unsuitable. The plot of TDS against TH revealed that groundwater within the study area fell within the very hard, freshwater category. Results from this study suggest that groundwater is considered to be good for domestic, industrial, and irrigation purposes at various sampling points. It is advised that frequent monitoring of groundwater quality should be carried out from time to time to avoid a decline in groundwater quality.
Similar content being viewed by others
Data availability
The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
Adimalla, N., & Venkatayogi, S. (2018). Geochemical characterization and evaluation of groundwater suitability for domestic and agricultural utility in semi-arid region of Basara, Telangna State, South India. Applied Water Science, 8, 44. https://doi.org/10.1007/s13201-018-0682-1
Akakuru, O. C., & Akudinobi, B. E. B. (2018). Determination of water quality index and irrigation suitability of groundwater sources in parts of coastal aquifers of Eastern Niger Delta, Nigeria. International Journal of Applied and Natural Science, 7(1), 1–6.
Akakuru, O. C., Akudinobi, B. E. B., & Aniwetalu, E. U. (2015). Qualitative evaluation and hydrogeochemical attributes of groundwater in Owerri Capital Territory, Southeastern Nigeria. IOSR Journal of Applied Geology and Geophysics, 3(2), 12-18
Akakuru, O., Akudinobi, B. E. B., & Maduka, E. (2017). Application of geographic information system in the hydrochemical evaluation of groundwater in parts of Eastern Niger Delta Nigeria. American Journal of Environmental Policy and Management, 3(6), 39–45.
Akakuru, O. C., Akudinobi, B. E., Nwankwoala, H. O., Akakuru, O. Z., & Onyekuru, S. O. (2021a). Compendious evaluation of groundwater in parts of Asaba, Nigeria for agricultural sustainability. Geoscience Journal. https://doi.org/10.1007/s12303-021-0010-x
Akakuru, O.C., Akudinobi, B., Opara, A.I., Onyekuru, S.O. & Akakuru, O.U. (2021b). Hydrogeochemical facies and pollution status of groundwater resources of Owerri and environs, Southeastern Nigeria. Environmental Monitoring and Assessment 193, 623. https://doi.org/10.1007/s10661-021-09364-9
Akakuru, O. C., Eze, C. U., Okeke, O. C., Opara, A. I., Usman, A. O., Iheme, O. K., Ibeneme, S. I., & Iwuoha, P. O. (2022). Hydrogeochemical evolution, water quality indices, irrigation suitability and pollution index of groundwater (PIG) around Eastern Niger Delta, Nigeria. International Journal of Energy and Water Resources. https://doi.org/10.1007/s42108-021-00162-0
Ahmed, F. Y. (2020). Criteria for identifying groundwater in rifting basins in arid and semi-arid zones: A case study Sharm El Bahary in Egypt. Environmental Earth Science. https://doi.org/10.1007/s12665-020-09232-8
Amadi, P. A., Ofoegbu, C. O., & Morrison, T. (1989). Hydrogeochemical assessment of groundwater quality in parts of the Niger Delta, Nigeria. Environmental Geology Water Science, 14(3), 195–202.
Andre, L., Franceschi, M., Pouchan, P., & Atteia, O. (2005). Using geochemical data and modelling to enhance the understanding of groundwater flow in a regional deep aquifer, Aquitaine Basin, south west of France. Journal of Hydrology, 305, 40–62.
Badrinath, S. D., Raman, A., Gadkari, S. K., Mhaisalkar, V. A., & Despande, V. P. (1984). Evaluation of carbonate stability indices for Sabarmati river water. Indian Water Assessment, 16, 163–168.
Brindha, K., & Kavitha, R. (2014). Hydrochemical assessment of surface water and groundwater quality along Uyyakondan channel, South India. Environmental Earth Science, 73, 5383–5393. https://doi.org/10.1007/s12665-014-3793-5
Davies, O. A., Ugwumba, A. A. A., & Abolunde, D. S. (2008). Physico-chemistry quality of Trans-Amadi (Woji) creek, Port Harcourt, Niger Delta, Nigeria. Journal of Fishery International, 3(3), 91–97.
Del María, P. A., Daniela, F., Cristina, D., & Pablo, J. B. (2020). Origin and hydrochemical characteristics of groundwater in the Northeastern Patagonia, Argentina: The relationship with geomorphology and soils. Environmental Earth Sciences. https://doi.org/10.1007/s12665-020-09202-0
Devi, O. J., Belagali, S. L., Balasubramanian, A., Bose, S., Senthilkumar, G., Ramaswamy, S. N., & Ramanathan, A. L. (2009). Evaluation of Groundwater quality for irrigation and drinking purposes in selected taluks of Dakshina Kannada district in Karnataka, India (pp. 301–318). International Society of Groundwater for Sustainable Development. Special Publication.
Domenico, P. A., & Schwartz, F. W. (1990). Physical and chemical hydrology (p. 410). John Wiley and sons.
Doneen, L. D. (1961). The influence of crop and soil on percolating waters. Proceeding of Ground Water Recharge Conference, California, USA
Doneen, L.D. (1964). Water quality for agriculture. Department of irrigation, University of California. Davis. 48
Durfor, C. N., Becker, E. (1964). Public water supplies of the 100 largest cities in the United States. Geological survey water supply, vol. 1812. U.S. Government Printing Office, Washington, p 364
Eaton, E. M. (1950). Significance of carbonate in irrigation water. Soil Science, 69, 123–133.
Ebong, E. D., Akpan, A. E., Emeka, C. N., & Urang, J. G. (2017). Groundwater quality assessment using geoelectrical and geochemical approaches: Case study of Abi area, southeastern Nigeria. Applied Water Science, 7(5), 2463–2478. https://doi.org/10.1007/s13201-016-0439-7
Efe, S. I., & Mogborukor, J. O. A. (2012). Acid rain in Niger Delta region: Implication on water resources quality and crisis. International Journal Science Technology, 1(1), 17–26.
Etu-Efeotor, J. O., & Akpokodje, E. G. (1990). Aquifer systems of the Niger Delta. Journal of Mining and Geology, 26(2), 279–284.
EPA (U.S. Environmental Protection Agency). (2003). Drinking water advisory: consumer acceptability advice and health effects analysis on sodium. www.epa.gov/safewater/ccl/pdf/sodium.pdf. EPA 822-R-03-006, Washington DC: EPA Office of Water. Accessed 14 Aug 2021
Eyankware, M. O., Nnajieze, V. S., & Aleke, C. G. (2018). Geochemical assessment of water quality for irrigation in abandoned limestone quarry pits at Nkalagu area, southern Benue trough Nigeria. Environmental Earth Science, 77, 66. https://doi.org/10.1007/s12665-0187232-x
Eyankware, M. O., Ogwah, C., & Ulakpa, R. O. E. (2020a). The study of sea water intrusion in coastal aquifer of Niger Delta Region, Nigeria. Middle-East Journal of Science Research, 28(4), 369–379.
Eyankware, M. O., Aleke, C. G., Selemo, A. O. I., & Nnabo, P. N. (2020b). Hydrogeochemical studies and suitability assessment of groundwater quality for irrigation at Warri and Environs. Niger delta basin, Nigeria. Groundwater for Sustainable Development. https://doi.org/10.1016/j.gsd.2019.100293
Eyankware, M. O., Selemo, A. O. I., Obasi, P. N., & Nweke, O. M. (2020c). Evaluation of groundwater vulnerability in fractured aquifer using geoelectric layer susceptibility index at Oju, Southern Benue Trough Nigeria. Geological Behavior, 4(2), 63-67.
Eyankware, M. O., Nnabo, P. N., & Ogwah, C. (2020d). Impact of past mining activities on water resources around active and abandoned mines and quarries in Ebonyi State, South-Eastern Nigeria—A mini review. Hydro Science and Marine Engineering. https://doi.org/10.30564/hsme.v2i2.2412
Eyankware, M. O., Obasi, P. N., Omo-Irabor, O. O., & Akakuru, O. C. (2020e). Hydrochemical characterization of abandoned quarry and mine water for domestic and irrigation uses in Abakaliki, southeast Nigeria. Modeling Earth Systems and Environment. https://doi.org/10.1007/s40808-020-00827-5
Eyankware, M. O., & Ephraim, B. E. (2021). A comprehensive review of water quality monitoring and assessment in Delta State, Southern Part of Nigeria. Journal of Environmental & Earth Science, 3(1), 16–28. https://doi.org/10.30564/jees.v3i1.2900
Eyankware, M. O., Igwe, E. O., & Onwe, M. O. (2021a). Geochemical study using geochemical modelling approach in Ojekwe region of southern Benue Trough, Nigeria. International Journal of Energy and Water Resources. https://doi.org/10.1007/s42108-021-00163-z
Eyankware, M. O., Ogwah, C., & Umayah, O. S. (2021b). Integrated geophysical and hydrogeochemical characterization and assessment of groundwater studies in Adum West Area of Benue State, Nigeria. Journal of Geological Research, 65, 65881289. https://doi.org/10.30564/jgr.v3i3.3197
Eyankware, M. O., Akakuru, C. O., & Eyankware, E. O. (2022a). Hydrogeophysicaldelineation of aquifer vulnerability in parts of Nkalagu areas of Abakaliki, SE, Nigeria. Sustainable Water Resources Management. https://doi.org/10.1007/s40899-022-00603-6
Eyankware, M. O., Akakuru, C. O., & Eyankware, E. O. (2022b). Interpretation of hydrochemical data using various geochemical models: a case study of Enyigba mining district of Abakaliki, Ebonyi state, SE, Nigeria. Sustainable Water Resources Management. https://doi.org/10.1007/s40899-022-00613-4
Ezeh, V. O., Eyankware, M. O., Irabor, O. O., & Nnabo, P. N. (2016). Hydrochemical evaluation of water resources in Umuoghara and its environs, near Abakaliki, south eastern Nigeria. International Journal of Science and Healthcare Research., 1(2), 23–31.
Gouri, S. B., Ali, K., Pravat, K. S., El-Sayed, E. O., & Ali, B. (2018). Evaluation of groundwater quality and its suitability for drinking and irrigation using GIS and geostatistics techniques in semiarid region of Neyshabur, Iran. Applied Water Science. https://doi.org/10.1007/s13201-018-0795-6
Hem, J. D. (1985). Study and interpretation of the chemical characteristics of natural water. Geological Survey Water-Supply Paper, 1473. http://www.nativefshlab.net/library/textpdf/16621.pdf. Accessed 14 Aug 2021
Huzefa, S., Himanshu, G., Ajaykumar, K., & Bhavana, U. (2020). Hydrogeochemical characterization of groundwater from semiarid region of western India for drinking and agricultural purposes with special reference to water quality index and potential health risks assessment. Applied Water Science. https://doi.org/10.1007/s13201-020-01287-z
Kelly, W. P. (1963). Use of saline irrigation water. Soil Science, 95(4), 355–391.
Ketata, M., Gueddari, M., & Bouhlila, R. (2011). Suitability assessment of shallow and deep groundwaters for drinking and irrigation use in the El Khairat aquifer (Enfdha, Tunisian Sahel). Environmental Earth Science. https://doi.org/10.1007/s12665-011-1091-z
Kunfu, P., Yanxin, W., Xianjun, X., Yaqing, L., Teng, M., & Chunli, S. (2016). Multilevel hydrogeochemical monitoring of spatial distribution of arsenic: A case study at Datong Basin, northern China. Journal of Geochemical Exploration. https://doi.org/10.1016/j.gexplo.2015.09.002
Lima, T. B., Silva, O. N., Oliveira, J. T. A., Vasconcelos, I. M., Scalabrin, F. B., Rocha, T. L., & Castro, C. F. S. (2010). Identification of E. dysenteric laxative peptide: A novel strategy in the treatment of chronic constipation and irritable bowel syndrome. Peptides, 31(8), 1426–1433.
Li, P., Wu, J., & Qian, H. (2016). Hydrochemical appraisal of groundwater quality for drinking and irrigation purposes and the major influencing factors: A case study in and around Hua County, China. Arab Journal of Geoscience, 9, 15. https://doi.org/10.1007/s12517-015-2059-1
Mohammed, M. M., Murad, A., & Chowdhury, R. (2017). Evaluation of groundwater quality in the Eastern District of Abu Dhabi Emirate, UAE. Bulletin of Environmental Contamination and Toxicology, 98, 1–7.
Mohammad, M. A. K., Kishan, R. P. M., Aina, M., Zakiyah, A. K., & Hafzan, E. M. (2018). Evaluating the suitability of shallow aquifer for irrigational purposes in some parts of Kelantan, Malaysia. Bulletin of Geological Society Malaysia, 66, 57–64.
Mohammed-Aslam, M. A., & Syed, S. R. (2020). Hydrogeochemical characterization and appraisal of groundwater suitability for domestic and irrigational purposes in a semi-arid region Karnataka state, India. Applied Water Science. https://doi.org/10.1007/s13201-020-01320-1
Nandini, T., Madhuri, R., Tirumalesh, K., & Anoubam, D. S. (2020). Suitability of spring water from the Upper Beas River Basin in Kullu Valley (Western Himalaya, India) for drinking and irrigation purposes. Arabian Journal of Geosciences. https://doi.org/10.1007/s12517-020-06143-7
Nwankwor, G. I., Ahiarakwem, C. A., Okeke, O. C., & Dikeogu, T. C. (2016). Using hydrologic characteristics of aquifers in evaluating the groundwater resources of Port Harcourt and its environs, South-East, Nigeria. International Journal of Advanced Academic Research Sciences, Technology & Engineering, 2(12), 8–21.
Nwankwoala, H. O., Ngah, S. A., Ushie, F. A., & Amadi, A. N. (2014). Statistical characterization of groundwater quality I Port Harcourt, Southern Nigeria. Science Africian Journal of Scientific Issues, Research and Essays, 2(8), 338–341.
Obasi, P. N., Eyankware, M. O., & Akudinobi, B. E. B. (2021). Characterization and evaluation of the effects of mine discharges on surface water resources for irrigation: A case study of the Enyigba Mining District, Southeast Nigeria. Applied Water Science, 11, 112. https://doi.org/10.1007/s13201-021-01400-w
Ohwoghere, A. O., & Adaikpoh, E. O. (2013). Assessment of shallow aquifers contamination by failure of on site sewage disposal system in Ughelli, Western Niger Delta, Nigeria. Journal of Environmental Earth Science, 5(9), 208–216.
Omo-Irabor, O. O., Eyankware, M. O., & Ogwah, C. (2018). Integration of hydrogeochemical analytical methods and irrigation parameters in the evaluation of groundwater quality at Ibinta, Southern Benue Trough Nigeria. FUPRE Journal of Scientific and Industrial Research, 2(1), 38–49.
Olobaniyi, S. B., & Owoyemi, F. B. (2006). Characterization by factor analysis of the chemical facies of groundwater in the Deltaic Plain Sands aquifers of Warri, Western Niger Delta, Nigeria. African Journal of Science and Technology Science and Engineering Series, 7(1), 73–81.
Oteri, A. U. (1990). Delineation of sea water intrusion in a coastal beach ridge of Forcados. Journal of Mining and Geology, 26(2), 225–229.
Oteri, A. U., Atolagbe, F. P. (2003). Saltwater intrusion into coastal aquifers in Nigeria. The Second International Conference on Saltwater Intrusion and Coastal Aquifers
Onyeagocha, A. C. (1980). Petrography and depositional environment of the Benin Formation, Nigeria. Journal of Mining and Geology, 17, 147-151
Oyeyemi, K. D., Aizebeokhai, A. P., & Oladunjoye, M. A. (2015). Integrated Geophysical and Geochemical Investigations of Saline Water Intrusion in a Coastal Alluvial Terrain, Southwestern Nigeria. International Journal of Applied Environmental Sciences, 10(4), 1275–1288.
Ravindra, K., & Garg, V. K. (2007). Hydro-chemical survey of groundwater of Hisar city and assessment of defuorination methods used in India. Environmental Monitoring and Assessment, 132(1–3), 33–43.
Raghunath, I. I. M. (1987). Groundwater (2nd ed., pp. 344–369). Wiley.
Richards, L. A. (1969). Diagnosis and improvement of saline and alkali soils. In: United States salinity Laboratory Staff Agricultural Handbook No. 60. The United States Government Printing Office, Washington DC
SAI, (Spectrum Analytical Inc). (2010). Guide to Interpreting Irrigation Water Analysis, 1087 Janison Road. Washington CH, Ohio 43160 (Available: spectrumanalytic.com).
Sawyer, C. N., & McCarty, P. L. (1967). Chemistry for sanitary engineers (2nd ed., p. 518). McGraw-Hill.
Sheikh, M. A., Dar, I. Y., Yaseen, S., Pal, A., & Pandit, A. K. (2013). A study of physicochemical characteristics of three fresh water springs of Kashmir Himalaya, India. International Journal of Water Resources and Environmental Engineering, 5, 328–331. https://doi.org/10.5897/IJWREE12.088
Short, K. C., Stauble, A. J. (1967) Outline of Geology of Niger Delta. Bull AAPG 51(5), 761-779
Suneetha, N., Gupta, G. (2018). Evaluation of groundwater potential and saline water intrusion using secondary geophysical parameters: A case study from western Maharashtra, India. E3S Web of Conferences 54, 00033. https://doi.org/10.1051/e3sconf/20185400033
Stumm, W., & Morgan, J. J. (1996). Aquatic chemistry, chemical equilibria and rates in natural waters (3rd ed.). John Wiley & Sons Inc.
Subba, R. N., & Krishna, R. G. (1991). Groundwater quality in Vishakhapatnam urban area, Andhra Pradesh. Indian Journal of Environmental Health, 33(1), 25–30.
Simpson, T. R. (1946). Saline Basin Investigation Bull Calif. Div. Water Resource, Sacramento, 52:230
Ugbena, K. G., Tse, A. C., & Akpokodje, E. G. (2020). Modeling soluble contaminant migration by advection process in subsurface water in the Eastern Niger Delta, Nigeria. World Scientific News, 139(2), 102–114.
Vasanthavigar, M., Srinivasamoorthy, K., Vijayaragavan, K., Rajiv, G. R., Chidambaram, S., Anandhan, P., Manivannan, R., & Vasudevan, S. (2010). Application of water quality index for groundwater quality assessment: Thirumanimuttar sub-basin, Tamilnadu, India. Environmental Monitoring Assessment, 171, 595–609. https://doi.org/10.1007/s10661-009-1302-1
WHO. (2011). Guidelines for drinking-water quality (4th ed.). World Health Organization.
Weber, K., Daukoru, J., E. (1975). Petroleum geology of the Niger Delta: 9th World Petroleum Congress Proceedings 2, 209–221
Wilcox, L. V. (1955). Classification and use of irrigation water (p. 96). USDA, Circular.
Yohannes, M., & Abraham, M. (2020). Hydrochemical characterization and quality assessment of groundwater in Meki River Basin, Ethiopian Rift. Sustainable Water Resources Management. https://doi.org/10.1007/s40899-020-00471-y
Acknowledgements
The authors are thankful to anonymous reviewers for their constructive comments and suggestions towards improving the quality of the manuscript. We are thankful to the owners of the borehole who permitted us to fetch water for sampling. The first author is grateful to Professor A.O.I. Selemo for his encouragement and mentorship.
Author information
Authors and Affiliations
Contributions
All the authors contributed to the study’s conception and design. Material preparation, data collection, and analysis were performed by MOE, OC, RO EU, and EOE. The first draft of the manuscript was written by MOE and all the authors commented on previous versions of the manuscript. All the authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Ethical approval
As per the literature review, this is neither a repetition of any work nor copied key data from other’s work. The methodology, findings, and conclusions made here belong to original research work as per our knowledge and belief.
Research involving human and animal participants
This research work is carried out in compliance with transparency, moral values, honesty, and hard work. No human participation or animals are involved in this research work.
Informed consent
Every step of processing for publication informed to all co-authors of this paper at the earliest, and everything is carried out with collective decision and consent.
Rights and permissions
About this article
Cite this article
Eyankware, M.O., Akakuru, O.C., Ulakpa, R.O.E. et al. Hydrogeochemical approach in the assessment of coastal aquifer for domestic, industrial, and agricultural utilities in Port Harcourt urban, Southern Nigeria. Int J Energ Water Res 7, 401–419 (2023). https://doi.org/10.1007/s42108-022-00184-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42108-022-00184-2