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Recent Advancements in Polymer-Based Composite Electrolytes for Rechargeable Lithium Batteries

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Abstract

In recent years, lithium batteries using conventional organic liquid electrolytes have been found to possess a series of safety concerns. Because of this, solid polymer electrolytes, benefiting from shape versatility, flexibility, low-weight and low processing costs, are being investigated as promising candidates to replace currently available organic liquid electrolytes in lithium batteries. However, the inferior ion diffusion and poor mechanical performance of these promising solid polymer electrolytes remain a challenge. To resolve these challenges and improve overall comprehensive performance, polymers are being coordinated with other components, including liquid electrolytes, polymers and inorganic fillers, to form polymer-based composite electrolytes. In this review, recent advancements in polymer-based composite electrolytes including polymer/liquid hybrid electrolytes, polymer/polymer coordinating electrolytes and polymer/inorganic composite electrolytes are reviewed; exploring the benefits, synergistic mechanisms, design methods, and developments and outlooks for each individual composite strategy. This review will also provide discussions aimed toward presenting perspectives for the strategic design of polymer-based composite electrolytes as well as building a foundation for the future research and development of high-performance solid polymer electrolytes.

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Acknowledgements

This work was supported by the Basic Science Center Project of National Natural Science Foundation of China under grant No. 51788104, the National Key R&D Program of China (Gant 2016YFA0202500), the National Natural Science Foundation of China (21773264, 51672281), Beijing Natural Science Foundation (L172023), and the “Transformational Technologies for Clean Energy and Demonstration”, Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA 21070300).

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  1. CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing, 100190, China

    Shuang-Jie Tan & Yu-Guo Guo

  2. College of Science, Hunan Agricultural University, Changsha, 410128, Hunan, China

    Xian-Xiang Zeng, Qiang Ma & Xiong-Wei Wu

  3. University of Chinese Academy of Sciences, Beijing, 100049, China

    Shuang-Jie Tan & Yu-Guo Guo

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Tan, SJ., Zeng, XX., Ma, Q. et al. Recent Advancements in Polymer-Based Composite Electrolytes for Rechargeable Lithium Batteries. Electrochem. Energ. Rev. 1, 113–138 (2018). https://doi.org/10.1007/s41918-018-0011-2

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