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Enhancements in the properties of porous alumina materials by utilizing multi-sol-impregnated walnut shell

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Abstract

To further improve the properties of the porous alumina materials, which were prepared by using walnut shell as pore former with a multi-layer hierarchical structure, the multiple sol (zirconia sol, alumina sol, and silica sol)–impregnated walnut shell powder was utilized. The hygroscopicity and microstructure of walnut shell, and physical performances, thermal conductivity, and microstructure of porous alumina materials were characterized. The residual structure of walnut shells impregnated with multiple sols was left in the pores, which optimized the pore structure of materials. High-performance porous alumina materials were produced by successively impregnating with silica, alumina, and zirconia sols, which possesses low thermal conductivity of 0.166 W/(m·K) at 200 °C and ultra-high compressive strength of 84.4 MPa. The above excellent properties result in a great advantage for the existing materials. In addition, the feasibility of optimizing the structure and properties of the porous alumina materials, by using the residual structure of pore-forming agent, was further verified.

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References

  1. Li, J.J., Ren, B., Lu, Y.J., Xi, X.Q., Li, Y.J., Liu, K.L., Yang, J.L., Huang, Y.: Novel design of elongated mullite reinforced highly porous alumina ceramics using carbonized rice husk as pore-forming agent. Ceram. Int. 45, 13964–13970 (2019)

    Article  Google Scholar 

  2. Han, M., Yin, X.W., Cheng, L.F., Ren, S., Li, Z.K.: Effect of core-shell microspheres as pore-forming agent on the properties of porous alumina ceramics. Mater Design. 113, 113384–113390 (2017)

    Google Scholar 

  3. Tang, F.Q., Fudouzi, H., Sakka, Y.: Fabrication of macroporous alumina with tailored porosity. J Am. Ceram. Soc. 86, 2050–2054 (2003)

    Article  CAS  Google Scholar 

  4. Giorgio, P., Ludovica, C., Matteo, L., Ulrico, S.: On the elastic deformation properties of porous ceramic materials obtained by pore-forming agent method. Ceram. Int. 41, 11097–11105 (2015)

    Article  Google Scholar 

  5. Chevalier, E., Chulia, D., Pouget, C., Viana, M.: Review: Fabrication of porous substrates: a review of processes using pore forming agents in the biomaterial field. J. Pharm. Sci. 97, 1135–1154 (2010)

    Article  Google Scholar 

  6. Fu, L.P., Gu, H.Z., Huang, A., Zhou, Y.S., Zhang, M.J.: Fabrication of lightweight alumina with nanoscale intracrystalline pores. J. Am. Ceram. Soc. 103, 2262–2271 (2020)

    Article  CAS  Google Scholar 

  7. Dele-Afolabi, T.T., Azmah Hanim, M.A., Norkairunnisa, M., Sobri, S., Calin, R., Ismarrubie, Z.N.: Significant effect of rice husk and sugarcane bagasse pore formers on the microstructure and mechanical properties of porous Al2O3/Ni composites. J Alloys. Compd. 743, 323–331 (2018)

    Article  CAS  Google Scholar 

  8. Luisa, B., Fernanda, A., Isabella, L., Rosa, T.: Management of agricultural biomass wastes: preliminary study on characterization and valorisation in clay matrix bricks. Waste. Manage. 33, 2307–2315 (2013)

    Article  Google Scholar 

  9. Li, X.S., Li, Y.B., Li, S.J., Wei, Z.P., Xiang, R.F.: Preparation of high-strength lightweight alumina with plant-derived pore using corn stalk as pore-forming agent. Int. J. Appl. Ceram. Technol. 17, 2465–2472 (2020)

    Article  CAS  Google Scholar 

  10. Cao, J., Rambo, C.R., Sieber, H.: Preparation of porous Al2O3 ceramics by biotemplating of wood. J. Porous Mater. 11, 163–172 (2005)

    Article  Google Scholar 

  11. Alzukaimi, J., Jabrah, R.: Review: The preparation and characterization of porous alumina ceramics using an eco-friendly pore-forming agent. Int J Appl Ceram. Technol. 16, 820–831 (2018)

    Article  Google Scholar 

  12. Zhang, T., Zhou, Y.M., He, M., Yang, Y.J., Zhang, C.: Templated fabrication of biomorphic alumina-based ceramics with hierarchical structure. J. Eur. Ceram. Soc. 35, 1337–1341 (2015)

    Article  CAS  Google Scholar 

  13. Mohanta, K., Kumar, A., Parkash, O., Kumar, D.: Low cost porous alumina with tailored microstructure and thermal conductivity prepared using rice husk and sucrose. J. Am. Ceram. Soc. 97, 1708–1719 (2014)

    Article  CAS  Google Scholar 

  14. Wei, Z.P., Li, S.J., Li, Y.B., Li, X.S., Xiang, R.F., Xu, N.N.: Porous alumina ceramics with enhanced mechanical and thermal insulation properties based on sol-treated rice husk. Ceram. Int. 44, 22616–22621 (2018)

    Article  CAS  Google Scholar 

  15. Venkatesan, B., Lijina, V.J., Kannan, V., Dhevasenaa, P.R.: Partial replacement of fine aggregate by steel slag and coarse aggregate by walnut shell in concrete. Mater. Today. Chem. (2020)

  16. Czlonka, S., Strakowska, A., Kairyte, A.: Effect of walnut shells and silanized walnut shells on the mechanical and thermal properties of rigid polyurethane foams. Polym. Test. 87, (2020)

  17. Xiang, R.F.: Utilization of waste foundry sand from investment casting in refractories, PhD Dissertation, Wuhan University of Science and Technology. (2017)

  18. Li, N., Gu, H.Z., Zhao, H.Z.: Metallurgical Industry Press. Refractory science. Beijing. (2010)

  19. Mohanta, K., Kumar, A., Parkash, O., Kumar, D.: Processing and properties of low cost macroporous alumina ceramics with tailored porosity and pore size fabricated using rice husk and sucrose. J. Eur. Ceram. Soc. 34, 2401–2412 (2014)

    Article  CAS  Google Scholar 

  20. Feng, Y., Wang, K., Yao, J.F., Webley, P.A., Smart, S.: Effect of the addition of polyvinylpyrrolidone as a pore-former on microstructure and mechanical strength of porous alumina ceramics. Ceram. Int. 39, 7551–7556 (2013)

    Article  CAS  Google Scholar 

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Funding

The research leading to these results received funding from the projects of the National Natural Science Foundation of China under Grant Agreement Nos. 51502213 and 51772221.

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Correspondence to Shujing Li.

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Hu, J., Li, S., Li, Y. et al. Enhancements in the properties of porous alumina materials by utilizing multi-sol-impregnated walnut shell. J Aust Ceram Soc 57, 1553–1562 (2021). https://doi.org/10.1007/s41779-021-00660-8

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  • DOI: https://doi.org/10.1007/s41779-021-00660-8

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