Abstract
The effect of ignition kinetics and fuel chemistry of conventional jet fuels like JP-8, Jet-A, and JP-5 on the detonation length and time scales was studied and compared for applications in detonation-based combustors. The numerical calculations were carried out over a range of initial conditions to evaluate critical detonation responses of interest of real distillate fuels for their application in detonation-based combustors. The effect of the addition of ignition promoters and inert diluents on the ignition kinetics of real distillate fuels was also computed and compared. Results show that the global detonation properties of the three jet fuels are approximately the same under comparable conditions. Also, the length and time scales of real distillate fuels have very small variations under varying initial conditions. Similarly, the addition of ignition promoters shows similar reductions in the chemical length and times scales. The increase in the detonation length and time scales with the addition of inert diluents is also similar for the three jet fuels. For all the cases tested so far, the detonation chemistry and the critical detonation parameters are found to be very close to each other for JP-8, Jet-A, and JP-5. In so far as the global detonation properties are concerned, the three jet fuels tested exhibit nearly the same chemical behaviors and global combustion properties. Additionally, the three jet fuels tested yield nearly the same composition and amounts of pyrolysis products under comparable conditions. It is found that the pyrolysis product distribution determines the global detonation properties of the original, multicomponent jet fuels.
Similar content being viewed by others
Abbreviations
- Δi :
-
Induction zone length (mm)
- τi :
-
Induction delay time (μs)
- \(\dot{\upsigma }\) :
-
Thermicity
- T 0 :
-
Initial temperature (K)
- P 0 :
-
Initial pressure (atm)
- a 0 :
-
Upstream speed of sound (m/s)
- φ:
-
Equivalence ratio
- P CJ :
-
Post-detonation pressure (atm)
- T CJ :
-
Post-detonation temperature (K)
- M CJ :
-
CJ detonation Mach number
- V CJ :
-
CJ detonation velocity (m/s)
- P VN :
-
Post-shock pressure (atm)
- T VN :
-
Post-shock temperature (K)
- VN:
-
Von Neumann state
- CJ:
-
Chapman–Jouguet state
References
Browne S, Ziegler J, Shepherd JE (2008) Numerical solution methods for shock and detonation jump conditions. Galcit Rep fm2006 6:90
Crane J, Shi X, Singh AV, Tao Y, Wang H (2019) Isolating the effect of induction length on detonation structure: hydrogen-oxygen detonation promoted by ozone. Combust Flame 200:44–52. https://doi.org/10.1016/j.combustflame.2018.11.008
Dahake AP, Singh AV (2021) Numerical study on NOx emissions from a synthetic biofuel for applications in detonation-based combustors. In: AIAA propulsion and energy 2021 forum, p 3678. https://doi.org/10.2514/6.2021-3678
Dahake A, Singh AV (2022a) A comparative study of critical detonation parameters for jet A and an alcohol-to-jet synthetic biofuel. In: 2022a AIAA SciTech forum and exposition, 3–7 January 2022, San Diego, CA, USA. https://doi.org/10.2514/6.2022-0819
Dahake A, Singh AV (2022b) Effect of fuel sensitization on NOx emissions from a synthetic biofuel under detonating conditions. In: 2022b AIAA SciTech forum and exposition, 3–7 January 2022, San Diego, CA, USA. https://doi.org/10.2514/6.2022-0518
Demirbas A (2008) Biofuels sources, biofuel policy, biofuel economy and global biofuel projections. Energy Convers Manage 49(8):2106–2116. https://doi.org/10.1016/j.enconman.2008.02.020
Garikov AI, Efimenko AA, Dorofeev SB (2000) A model for detonation cell size prediction from chemical kinetics. Combust Flame 120(1–2):19–33. https://doi.org/10.1016/S0010-2180(99)00076-0
Goodwin DG, Speth RL, Moffat HK, Weber BW (2018) Cantera: an object-oriented software toolkit for chemical kinetics, thermodynamics, and transport processes, version 2.4.0. https://www.cantera.org
Heiser WH, Pratt DT (2002) Thermodynamic cycle analysis of pulse detonation engines. J Propul Power 18(1):68–76. https://doi.org/10.2514/2.5899
Iyer KM, Singh AV (2021) NOx emissions from Jet A-air detonations. In: AIAA propulsion and energy 2021 forum, p 3679. https://doi.org/10.2514/6.2021-3679
Iyer MSK, Singh AV (2022) Ignition kinetics of real distillate fuels under detonating conditions. In: 2022 AIAA SciTech forum and exposition, 3-7 January 2022, San Diego, CA, USA. https://doi.org/10.2514/6.2022-0816
Kailasanath K (2000) Review of propulsion application of detonation waves. AIAA J 38(9):1698–1708. https://doi.org/10.2514/2.1156
Kao S, Shepherd JE (2008) Numerical solution methods for control volume explosions and ZND detonation structure. Galcit Rep fm2006 7:1–46
Kumar DS, Singh AV (2021) Inhibition of hydrogen-oxygen/air gaseous detonations using CF3I, H2O, and CO2. Fire Saf J 124:103405. https://doi.org/10.1016/j.firesaf.2021.103405
Kumar DS, Ivin K, Singh AV (2021) Sensitizing gaseous detonations for hydrogen/ethylene-air mixtures using ozone and H2O2 as dopants for application in rotating detonation engines. Proc Combust Inst 38(03):3825–3834. https://doi.org/10.1016/j.proci.2020.08.061
Liang W, Wang Y, Law C (2019) Role of ozone doping in the explosion limits of hydrogen-oxygen mixtures: multiplicity and catalyticity. Combust Flame 205:7–10. https://doi.org/10.1016/j.combustflame.2019.03.038
Lu FK, Braun EM (2014) Rotating detonation wave propulsion: experimental challenges, modeling, and engine concepts. J Propul Power 30(5):1125–1142. https://doi.org/10.2514/1.B34802
Mevel R, Lafosse F, Catoire L, Chaumeix N, Dupre G, Paillard CE (2008) Induction delay times and detonation cell size prediction of hydrogen-nitrous oxide-diluent mixtures. Combust Sci Tech 180(10–11):1858–1875. https://doi.org/10.1080/00102200802261340
Nicholls JA, Cullen RE, Ragland KW (1966) Feasibility studies of a rotating detonation wave rocket motor. J Spacecr Rocket 3(6):893–898. https://doi.org/10.2514/3.28557
Peng H, Liu W, Liu S, Zhang H (2018) Experimental investigations on ethylene-air continuous rotating detonation wave in the hollow chamber with Laval nozzle. Acta Astronaut 151:137–145. https://doi.org/10.1016/j.actaastro.2018.06.025
Rodionova MV, Poudyal RS, Tiwari I, Voloshin RA, Zharmukhamedov SK, Nam HG, Zayadan BK, Bruce BD, Hou HJM, Allakhverdiev SI (2017) Biofuel production: challenges and opportunities. Int J Hydrogen Energy 42(12):8450–8461. https://doi.org/10.1016/j.ijhydene.2016.11.125
Stamps DW, Tieszen SR (1991) The influence of initial pressure and temperature on hydrogen-air-diluent detonations. Combust Flame 83(3–4):353–364. https://doi.org/10.1016/0010-2180(91)90082-M
Vasil’ev AA (2006) Cell size as the main geometric parameter of a multifront detonation wave. J Propulsion Power 22(6):1245–1260. https://doi.org/10.2514/1.20348
Wang H, Xu R, Wang K, Bowman CT, Davidson DF, Hanson RK, Brezinsky K, Egolfopoulos FN (2018) A physics-based approach to modeling real-fuel combustion chemistry—I. Evidence from experiments and thermodynamic, chemical kinetics, and statistical considerations. Combust Flame 193(01):502–519. https://doi.org/10.1016/j.combustflame.2018.03.019
Wang H, You X, Joshi AV, Davis SG, Laskin A, Egolfopoulos F, Law CK (2007) USC Mech Version II. High-temperature combustion reaction model of H2/CO/C1-C4 compounds. http://ignis.usc.edu/Mechanisms/USC-Mech%20II/USC_Mech%20II.htm
Westbrook CK (1982) Chemical kinetics of hydrocarbon oxidation in gaseous detonations. Combust Flame 46:191–210. https://doi.org/10.1016/0010-2180(82)90015-3
Wolański P (2013) Detonative propulsion. Proc Combust Inst 34(1):125–158. https://doi.org/10.1016/j.proci.2012.10.005
Zhang B (2019) Detonation limits in methane-hydrogen-oxygen mixtures: dominant effect of induction length. Int J Hydrogen Energy 44(41):23532–23537. https://doi.org/10.1016/j.ijhydene.2019.07.053
Zhao H, Yang X, Ju Y (2016) Kinetic studies of ozone assisted low temperature oxidation of dimethyl ether in a flow reactor using molecular-beam mass spectrometry. Combust Flame 173:187–194
Acknowledgements
The authors acknowledge the financial support for this work from the Aeronautics R&D Board, Ministry of Defence, Govt. of India vide Sanction Letter # ARDB/01/1042000M/I.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Iyer, M.S.K., Dahake, A. & Singh, A.V. Comparative Studies on Ignition Kinetics and Detonation Chemistry of Real Distillate Fuels. Trans Indian Natl. Acad. Eng. 7, 823–834 (2022). https://doi.org/10.1007/s41403-022-00331-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s41403-022-00331-5